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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3,4-dimethylphenylthiomethyl)glutaronitrile —— C14H16N2S
    2-(3,4-dimethylphenylthiomethyl)glutaronitrile
    —— 3-((3,4-dimethylphenyl)thio)-2,2-dimethylpropanoic acid —— C13H18O2S
    3-((3,4-dimethylphenyl)thio)-2,2-dimethylpropanoic acid
    —— 3,5-Dichloro-4-(3,4-dimethyl-phenylsulfanyl)-nitrobenzene —— C14H11Cl2NO2S
    3,5-Dichloro-4-(3,4-dimethyl-phenylsulfanyl)-nitrobenzene
    —— 2-{3-[(3,4-dimethylphenyl)thio]prop-1-yn-1-yl}-6-methylpyridine —— C17H17NS
    2-{3-[(3,4-dimethylphenyl)thio]prop-1-yn-1-yl}-6-methylpyridine
    —— 2-((3,4-dimethylphenyl)thio)acetonitrile —— C10H11NS
    2-((3,4-dimethylphenyl)thio)acetonitrile
    —— 2-(4-chlorophenyl)-4-(4-ethylphenylthio)-6-[3-(morpholino)propylamino]-pyrimidine —— C25H29ClN4OS
    2-(4-chlorophenyl)-4-(4-ethylphenylthio)-6-[3-(morpholino)propylamino]-pyrimidine
    —— 1-(2-methylthio 5-methylphenyl)ethanol —— C10H14OS
    1-(2-methylthio 5-methylphenyl)ethanol
    —— (E)-1,2-difluorovinyl p-tolyl sulfide —— C9H8F2S
    (E)-1,2-difluorovinyl p-tolyl sulfide
    —— 4-(Methylthio)benzenebutanenitrile —— C11H13NS
    4-(Methylthio)benzenebutanenitrile
    —— bis(4-methoxybutyl) disulfide —— C10H22O2S2
    bis(4-methoxybutyl) disulfide
    —— N-{[5-(2-methoxyethylthio)-1,3,4-oxadiazol-2-ylmethyl]-5-(pyridine-3-yl)}-1,3,4-thiadiazol-2-amine —— C13H14N6O2S2
    N-{[5-(2-methoxyethylthio)-1,3,4-oxadiazol-2-ylmethyl]-5-(pyridine-3-yl)}-1,3,4-thiadiazol-2-amine
    —— 3-Cyclopentylthio-6,6-dimethyl-1-(pyrazol-3-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one —— C18H22N2OS2
    3-Cyclopentylthio-6,6-dimethyl-1-(pyrazol-3-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— 2-(4-fluorophenylthio)-N-(5-(2-phenylthiazol-4-yl)pentyl)acetamide —— C22H23FN2OS2
    2-(4-fluorophenylthio)-N-(5-(2-phenylthiazol-4-yl)pentyl)acetamide
    —— 1-(2-((5-chloro-1,6-dihydro-1-isopropyl-2-(methylthio)-6-oxopyrimidin-4-yloxy)methyl)-5-fluorobenzyl)-3-isopropylurea —— C20H26ClFN4O3S
    1-(2-((5-chloro-1,6-dihydro-1-isopropyl-2-(methylthio)-6-oxopyrimidin-4-yloxy)methyl)-5-fluorobenzyl)-3-isopropylurea
    —— 1-(2-((5-bromo-1,6-dihydro-1-isopropyl-2-(methylthio)-6-oxopyrimidin-4-yloxy)methyl)-5-fluorobenzyl)-3-isopropylurea —— C20H26BrFN4O3S
    1-(2-((5-bromo-1,6-dihydro-1-isopropyl-2-(methylthio)-6-oxopyrimidin-4-yloxy)methyl)-5-fluorobenzyl)-3-isopropylurea
    —— isopropyl-propyl sulfone —— C6H14O2S
    isopropyl-propyl sulfone
    —— (2R)-2-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-butanol —— C16H17F2N5OS2
    (2R)-2-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-butanol
    —— 1-(3,4-dichlorophenyl)-3-(4-((6,7-dimethoxy-2-methylquinolin-3-yl)thio)phenyl)urea —— C25H21Cl2N3O3S
    1-(3,4-dichlorophenyl)-3-(4-((6,7-dimethoxy-2-methylquinolin-3-yl)thio)phenyl)urea
    —— 7-isopropoxy-7-oxo-4,4-bis(phenylthio)heptanoic acid —— C20H22O4S2
    7-isopropoxy-7-oxo-4,4-bis(phenylthio)heptanoic acid
    —— tributyl(3-(7-methoxy-7-oxo-4,4-bis(phenylthio)heptanamido)propyl)phosphonium bromide —— Br*C35H55NO3PS2
    tributyl(3-(7-methoxy-7-oxo-4,4-bis(phenylthio)heptanamido)propyl)phosphonium bromide
    —— 1-(isothiuroniummethyl)cyclopropaneacetonitrile hydrobromide —— BrH*C7H11N3S
    1-(isothiuroniummethyl)cyclopropaneacetonitrile hydrobromide
    —— ethyl 3-methyl-5-(methylthio)isoxazole-4-carboxylate —— C8H11NO3S
    ethyl 3-methyl-5-(methylthio)isoxazole-4-carboxylate
    —— ethyl 3-(methylthio)-pyrrole-2,4-dicarboxylate —— C11H15NO4S
    ethyl 3-(methylthio)-pyrrole-2,4-dicarboxylate
    —— 3-(prop-2-en-1-ylsulfanyl)-1,2,4-thiadiazol-5-amine —— C5H7N3S2
    3-(prop-2-en-1-ylsulfanyl)-1,2,4-thiadiazol-5-amine
    —— 6-[3-[3-(4-chlorophenyl)thioureido]phenylthio]-N-methylpyridine-3-formamide —— C20H17ClN4OS2
    6-[3-[3-(4-chlorophenyl)thioureido]phenylthio]-N-methylpyridine-3-formamide
    —— 6-{4-[3-(4-chlorophenyl)thioureido]phenylsulfanyl}-N-methylnicotinamide —— C20H17ClN4OS2
    6-{4-[3-(4-chlorophenyl)thioureido]phenylsulfanyl}-N-methylnicotinamide
    —— methyldiphenyl<(phenylthio)methyl>silane —— C20H20SSi
    methyldiphenyl<(phenylthio)methyl>silane
    —— 1-bis(phenylthio)methyl-2-methylenecyclohexane —— C20H22S2
    1-bis(phenylthio)methyl-2-methylenecyclohexane
    —— (phenylthio)methyl phenylacetate —— C15H14O2S
    (phenylthio)methyl phenylacetate
    —— 4-<<(phenylthio)methyl>oxy>-4-phenyl-1-butene —— C17H18OS
    4-<<(phenylthio)methyl>oxy>-4-phenyl-1-butene
    —— phenylsulfanyl-methanesulfonic acid —— C7H8O3S2
    phenylsulfanyl-methanesulfonic acid
    —— (R)-N-[2-chloro-4-(pyrimid-2-yl-thio)phenyl]-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide —— C14H11ClF3N3O2S
    (R)-N-[2-chloro-4-(pyrimid-2-yl-thio)phenyl]-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide
    —— 5-chloro-1-(chloromethyl)-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one —— C9H6Cl2N4OS
    5-chloro-1-(chloromethyl)-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one
    —— 5-chloro-1-(pyrimidin-2-ylsulfanylmethyl)-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one —— C13H9ClN6OS2
    5-chloro-1-(pyrimidin-2-ylsulfanylmethyl)-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one
    —— 5-(pyrimidine-2-sulfanyl)-thiazolidine-2,4-dione —— C7H5N3O2S2
    5-(pyrimidine-2-sulfanyl)-thiazolidine-2,4-dione
    —— 2-<3-(trifluoromethyl)pyridin-2-ylsulfanyl>pyrimidine —— C10H6F3N3S
    2-<3-(trifluoromethyl)pyridin-2-ylsulfanyl>pyrimidine
    —— 2-<5-(trifluoromethyl)pyridin-2-ylsulfanyl>pyrimidine —— C10H6F3N3S
    2-<5-(trifluoromethyl)pyridin-2-ylsulfanyl>pyrimidine
    —— 2-(5-chloropentylmercapto)pyrimidine —— C9H13ClN2S
    2-(5-chloropentylmercapto)pyrimidine
    —— 4-trifluoromethyl-2-trifluoromethylthiopyrimidine —— C6H2F6N2S
    4-trifluoromethyl-2-trifluoromethylthiopyrimidine
    —— 4,5-bis(trifluoromethyl)-2-trifluoromethylthiopyrimidine —— C7HF9N2S
    4,5-bis(trifluoromethyl)-2-trifluoromethylthiopyrimidine
    —— dimethyl 2-phenyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate —— C18H15N3O5S2
    dimethyl 2-phenyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate
    —— N-((5S)-3-(4-(2-{pyrimid-2-ylthio}methyl-3,6-dihydropyran-4-yl)phenyl)-2-oxooxazolidin-5-ylmethyl)acetamide —— C22H24N4O4S
    N-((5S)-3-(4-(2-{pyrimid-2-ylthio}methyl-3,6-dihydropyran-4-yl)phenyl)-2-oxooxazolidin-5-ylmethyl)acetamide
    —— 5-chloro-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one —— C8H5ClN4OS
    5-chloro-4-(pyrimidin-2-ylsulfanyl)pyridazin-6-one
    —— diethyl 2-phenyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate —— C20H19N3O5S2
    diethyl 2-phenyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate
    —— diethyl 2-methyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate —— C15H17N3O5S2
    diethyl 2-methyl-6-(pyrimidin-2-ylthio)-4-thioxo-5,6-dihydro-4H-1,3-oxazine-5,6-dicarboxylate
    —— N<sup>1</sup>-(1,3-dimnethylbutyl)-N'<sup>4</sup>-phenyl-2-(2-pyrimidinylsulfanyl)-1,4-phenylenediamine —— C22H26N4S
    N<sup>1</sup>-(1,3-dimnethylbutyl)-N'<sup>4</sup>-phenyl-2-(2-pyrimidinylsulfanyl)-1,4-phenylenediamine
    —— 2-(adamantan-1-ylmethylsulfanyl)-pyrimidine —— C15H20N2S
    2-(adamantan-1-ylmethylsulfanyl)-pyrimidine
    —— 2-(propylthio)pyrimidine —— C7H10N2S
    2-(propylthio)pyrimidine
    —— (2-Chloroethyl)-[3-chloro-2-(pyrimidin-2-yl-sulfanylmethyl)pyridin-4-yl]methylamine hydrochloride —— C13H14Cl2N4S*ClH
    (2-Chloroethyl)-[3-chloro-2-(pyrimidin-2-yl-sulfanylmethyl)pyridin-4-yl]methylamine hydrochloride
    —— 2-<2-(pyridin-2-ylthio)phenylthio>pyrimidine —— C15H11N3S2
    2-<2-(pyridin-2-ylthio)phenylthio>pyrimidine