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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-3-(5-methylfuran-2-yl)-N-(3-phenylsulfanylpropyl)prop-2-enamide —— C17H19NO2S
    (Z)-3-(5-methylfuran-2-yl)-N-(3-phenylsulfanylpropyl)prop-2-enamide
    —— (Z)-N-(3-phenylsulfanylpropyl)-3-thiophen-2-ylprop-2-enamide —— C16H17NOS2
    (Z)-N-(3-phenylsulfanylpropyl)-3-thiophen-2-ylprop-2-enamide
    —— (7E)-3-[chloro(difluoro)methyl]-7-[(5-methylthiophen-2-yl)methylidene]-6-phenyl-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H11ClF2N4S2
    (7E)-3-[chloro(difluoro)methyl]-7-[(5-methylthiophen-2-yl)methylidene]-6-phenyl-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— methyl (2R)-3-[1-(benzenesulfonyl)-3-phenylsulfanylindol-2-yl]-2-cyanopropanoate —— C25H20N2O4S2
    methyl (2R)-3-[1-(benzenesulfonyl)-3-phenylsulfanylindol-2-yl]-2-cyanopropanoate
    —— 4-(4-Methylphenyl)-2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3-thiazole —— C17H14N2O4S3
    4-(4-Methylphenyl)-2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3-thiazole
    —— methyl (2S)-3-[1-(benzenesulfonyl)-3-phenylsulfanylindol-2-yl]-2-cyanopropanoate —— C25H20N2O4S2
    methyl (2S)-3-[1-(benzenesulfonyl)-3-phenylsulfanylindol-2-yl]-2-cyanopropanoate
    —— 11-Methyl-10-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C19H18N4OS3
    11-Methyl-10-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 10-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-11-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C18H16N4OS3
    10-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-11-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 5-Nitro-2-(4-oxo-3-phenylthieno[2,3-d]pyrimidin-2-yl)sulfanylbenzonitrile —— C19H10N4O3S2
    5-Nitro-2-(4-oxo-3-phenylthieno[2,3-d]pyrimidin-2-yl)sulfanylbenzonitrile
    —— 2-[(11-Methyl-12-oxo-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-10-yl)sulfanyl]-5-nitrobenzonitrile —— C17H12N4O3S2
    2-[(11-Methyl-12-oxo-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-10-yl)sulfanyl]-5-nitrobenzonitrile
    —— 3-(2-Methoxyethyl)-5,6-dimethyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanylthieno[2,3-d]pyrimidin-4-one —— C17H16N4O2S3
    3-(2-Methoxyethyl)-5,6-dimethyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanylthieno[2,3-d]pyrimidin-4-one
    —— 10-(2-Chloro-4-nitrophenyl)sulfanyl-11-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C16H12ClN3O3S2
    10-(2-Chloro-4-nitrophenyl)sulfanyl-11-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 3-Methyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one —— C17H14N4OS3
    3-Methyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-3-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one —— C19H18N4OS3
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-3-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one
    —— 11-Propyl-10-thieno[2,3-d]pyrimidin-4-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C18H16N4OS3
    11-Propyl-10-thieno[2,3-d]pyrimidin-4-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 2-[(3-Ethyl-4-oxo-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl)sulfanyl]-5-nitrobenzonitrile —— C19H16N4O3S2
    2-[(3-Ethyl-4-oxo-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl)sulfanyl]-5-nitrobenzonitrile
    —— N-[2-[(5E)-5-[(3-bromophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-phenylsulfanylacetamide —— C20H17BrN2O3S2
    N-[2-[(5E)-5-[(3-bromophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-phenylsulfanylacetamide
    —— N-[(S)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-3-(4-fluorophenyl)sulfanylpropanamide —— C20H19ClFN3OS
    N-[(S)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-3-(4-fluorophenyl)sulfanylpropanamide
    —— N-[(S)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-2-(2-methylphenyl)sulfanylacetamide —— C20H20ClN3OS
    N-[(S)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-2-(2-methylphenyl)sulfanylacetamide
    —— ethyl (4S)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylmethyl]-4H-thiopyran-3-carboxylate —— C24H21ClN4O2S2
    ethyl (4S)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylmethyl]-4H-thiopyran-3-carboxylate
    —— N,N'-dimethyl-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]ethane-1,2-diamine —— C20H26N4S2
    N,N'-dimethyl-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]ethane-1,2-diamine
    —— ethyl (4R)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylmethyl]-4H-thiopyran-3-carboxylate —— C24H21ClN4O2S2
    ethyl (4R)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylmethyl]-4H-thiopyran-3-carboxylate
    —— ethyl (7S,8S)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate —— C20H19N3O4S
    ethyl (7S,8S)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate
    —— ethyl (7R,8R)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate —— C20H19N3O4S
    ethyl (7R,8R)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate
    —— ethyl (7R,8S)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate —— C20H19N3O4S
    ethyl (7R,8S)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate
    —— (Z)-N-[3-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine —— C15H16N6S
    (Z)-N-[3-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine
    —— 4-nitro-N-[(Z)-(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylideneamino]aniline —— C22H15N5O4S
    4-nitro-N-[(Z)-(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylideneamino]aniline
    —— ethyl (7S,8R)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate —— C20H19N3O4S
    ethyl (7S,8R)-4-methoxy-9-oxo-8-phenyl-5,6,7,8-tetrahydropyrimido[4,5-b][1,4]benzothiazine-7-carboxylate
    —— 2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-3-ylmethylideneamino]acetamide —— C19H20BrN7OS
    2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-3-ylmethylideneamino]acetamide
    —— (Z)-N-[2-(4-chlorophenyl)sulfanylphenyl]-3-(1-ethyl-5-methylpyrazol-4-yl)prop-2-enamide —— C21H20ClN3OS
    (Z)-N-[2-(4-chlorophenyl)sulfanylphenyl]-3-(1-ethyl-5-methylpyrazol-4-yl)prop-2-enamide
    —— 2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-3-ylmethylideneamino]acetamide —— C19H20BrN7OS
    2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-3-ylmethylideneamino]acetamide
    —— (2R)-2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]propanamide —— C19H20BrN7OS
    (2R)-2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]propanamide
    —— (2S)-2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]propanamide —— C19H20BrN7OS
    (2S)-2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]propanamide
    —— 2-[[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]sulfanyl]-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile —— C21H20N4OS
    2-[[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]sulfanyl]-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile
    —— 1-{4-[(5-Amino-6-methoxy-4-pyrimidinyl)sulfanyl]-2-chloro-5-nitrophenyl}ethanone oxime —— C13H12ClN5O4S
    1-{4-[(5-Amino-6-methoxy-4-pyrimidinyl)sulfanyl]-2-chloro-5-nitrophenyl}ethanone oxime
    —— 2-[[5-cyclohexyl-4-[(Z)-(2-methyl-1,3-thiazol-4-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H18N5O2S2-
    2-[[5-cyclohexyl-4-[(Z)-(2-methyl-1,3-thiazol-4-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-cyclohexyl-4-[(Z)-(1,3,5-trimethylpyrazol-4-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H24N6O2S
    2-[[5-cyclohexyl-4-[(Z)-(1,3,5-trimethylpyrazol-4-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C19H24N4O2S
    2-[[5-cyclohexyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C20H29N5O2S
    2-[[5-cyclohexyl-4-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-(2,4,5-trimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C20H26N4O2S
    2-[[5-cyclohexyl-4-[(Z)-(2,4,5-trimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C19H23N4O2S-
    2-[[5-cyclohexyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-cyclohexyl-4-[(Z)-(2-fluorophenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H19FN4O2S
    2-[[5-cyclohexyl-4-[(Z)-(2-fluorophenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-furan-2-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H17N4O3S-
    2-[[5-cyclohexyl-4-[(Z)-furan-2-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-cyclohexyl-4-[(Z)-(3-methylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C18H22N4O2S
    2-[[5-cyclohexyl-4-[(Z)-(3-methylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C20H24N4O2S
    2-[[5-cyclohexyl-4-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-(2,4-dimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C19H24N4O2S
    2-[[5-cyclohexyl-4-[(Z)-(2,4-dimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-pyridin-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H19N5O2S
    2-[[5-cyclohexyl-4-[(Z)-pyridin-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(Z)-benzylideneamino]-5-cyclohexyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C17H20N4O2S
    2-[[4-[(Z)-benzylideneamino]-5-cyclohexyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-cyclohexyl-4-[(Z)-thiophen-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H17N4O2S2-
    2-[[5-cyclohexyl-4-[(Z)-thiophen-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-cyclohexyl-4-[(Z)-(4-fluorophenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H18FN4O2S-
    2-[[5-cyclohexyl-4-[(Z)-(4-fluorophenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate