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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-oxo-2-(propan-2-ylamino)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C19H21NO3S
    [2-oxo-2-(propan-2-ylamino)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [(2S)-1-amino-1-oxopropan-2-yl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C17H17NO3S
    [(2S)-1-amino-1-oxopropan-2-yl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-(cyclopropylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C19H19NO3S
    [2-(cyclopropylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C23H23NO3S
    [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C23H23NO3S
    [2-oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-(2-methylpropylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C20H23NO3S
    [2-(2-methylpropylamino)-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— Tert-butyl 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetate —— C21H21N3O2S
    Tert-butyl 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetate
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-thiophen-2-ylbutan-1-one —— C23H19N3OS2
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 3-(4-chlorophenyl)sulfanylpropanoate —— C20H19ClN2O2S2
    [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 3-(4-chlorophenyl)sulfanylpropanoate
    —— (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate —— C16H13ClN2O3S2
    (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C17H17ClN2O4S
    [2-[(1-Methylpyrrole-2-carbonyl)amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-oxo-2-(1H-pyrrol-2-yl)ethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C15H14ClNO3S
    [2-oxo-2-(1H-pyrrol-2-yl)ethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2R)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C19H26ClNO3S
    [(2R)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [(2R)-1-[2-(cyclohexen-1-yl)ethylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate —— C20H26ClNO3S
    [(2R)-1-[2-(cyclohexen-1-yl)ethylamino]-1-oxopropan-2-yl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H17N3OS2
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C17H16N2OS3
    2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— (2R)-N-(furan-2-ylmethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C17H16N2O2S2
    (2R)-N-(furan-2-ylmethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C18H22N2OS2
    N-[(1R,2S)-2-methylcyclohexyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H17N3OS2
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 4-[(4-Phenyl-1,3-thiazol-2-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole —— C17H12N2OS3
    4-[(4-Phenyl-1,3-thiazol-2-yl)sulfanylmethyl]-2-thiophen-2-yl-1,3-oxazole
    —— N,N-bis(2-cyanoethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H16N4OS2
    N,N-bis(2-cyanoethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-benzyl-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C20H20N2OS2
    (2R)-N-benzyl-N-methyl-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C17H19N3OS2
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C14H16N4O2S2
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-(2-cyanoethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H13N3OS2
    N-(2-cyanoethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[[5-[[2-(4-Methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H15N5OS4
    2-[[5-[[2-(4-Methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 4-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine —— C19H15FN4OS2
    4-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-N-(4-methylphenyl)-1,3-thiazol-2-amine
    —— (3R)-1-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]piperidine-1,3-dicarboxamide —— C18H23N5O2S
    (3R)-1-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]piperidine-1,3-dicarboxamide
    —— (3S)-1-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]piperidine-1,3-dicarboxamide —— C18H23N5O2S
    (3S)-1-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]piperidine-1,3-dicarboxamide
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 1-oxidopyridin-1-ium-4-carboxylate —— C22H20N2O4S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 1-oxidopyridin-1-ium-4-carboxylate
    —— [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C22H19N3O3S
    [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [(1S)-1-(4-fluorophenyl)ethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C22H16FNO2S
    [(1S)-1-(4-fluorophenyl)ethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate —— C22H18N2O4S
    [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [(2S)-1-[cyclohexyl(methyl)amino]-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate —— C24H26N2O3S
    [(2S)-1-[cyclohexyl(methyl)amino]-1-oxopropan-2-yl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [4-(6-amino-2-butylsulfanylpyrimidin-4-yl)-1,4-diazepan-1-yl]-[(2R)-oxolan-2-yl]methanone —— C18H29N5O2S
    [4-(6-amino-2-butylsulfanylpyrimidin-4-yl)-1,4-diazepan-1-yl]-[(2R)-oxolan-2-yl]methanone
    —— (3-Methylphenyl)methyl 2-(2-cyanophenyl)sulfanylbenzoate —— C22H17NO2S
    (3-Methylphenyl)methyl 2-(2-cyanophenyl)sulfanylbenzoate
    —— (2-Methylphenyl)methyl 2-(2-cyanophenyl)sulfanylbenzoate —— C22H17NO2S
    (2-Methylphenyl)methyl 2-(2-cyanophenyl)sulfanylbenzoate
    —— [2-(4-Fluoroanilino)-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C22H15FN2O3S
    [2-(4-Fluoroanilino)-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [4-(6-amino-2-butylsulfanylpyrimidin-4-yl)-1,4-diazepan-1-yl]-[(2S)-oxolan-2-yl]methanone —— C18H29N5O2S
    [4-(6-amino-2-butylsulfanylpyrimidin-4-yl)-1,4-diazepan-1-yl]-[(2S)-oxolan-2-yl]methanone
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C16H21N3O5S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— 2-[[5-[(2Z)-2-[[4-(diethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C18H27N7OS
    2-[[5-[(2Z)-2-[[4-(diethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 2-[[5-[(2Z)-2-[[4-(diethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C15H19N7S
    2-[[5-[(2Z)-2-[[4-(diethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— methyl 2-[[5-[(2Z)-2-[[4-(dimethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H18N6O2S
    methyl 2-[[5-[(2Z)-2-[[4-(dimethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-3-propylsulfanyl-1H-1,2,4-triazol-5-amine —— C16H24N6S
    N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-3-propylsulfanyl-1H-1,2,4-triazol-5-amine
    —— N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C19H23N7S
    N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2Z)-2-[[4-(dimethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C18H21N7O2S
    2-[[5-[(2Z)-2-[[4-(dimethylamino)phenyl]methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine —— C13H18N6S
    N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine
    —— 6-[(3S)-3-[1-[2-(dimethylamino)ethyl]imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine —— C17H27N7S
    6-[(3S)-3-[1-[2-(dimethylamino)ethyl]imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine
    —— 6-[(3R)-3-[1-[2-(dimethylamino)ethyl]imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine —— C17H27N7S
    6-[(3R)-3-[1-[2-(dimethylamino)ethyl]imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine
    —— N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-3-(2-methylpropylsulfanyl)-1H-1,2,4-triazol-5-amine —— C15H22N6S
    N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-3-(2-methylpropylsulfanyl)-1H-1,2,4-triazol-5-amine