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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C17H14ClF2NO3S
    [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H23F2NO3S
    [(2R)-1-(cyclohexylmethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— (2R)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide —— C18H20N4OS2
    (2R)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H18F2N2O3S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C19H18F3NO3S
    [(2R)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C13H12F2N2O3S
    [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H16F3NO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H12F2N2O3S2
    [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— (2-Amino-2-oxoethyl) 2-(2,5-difluorophenyl)sulfanylacetate —— C10H9F2NO3S
    (2-Amino-2-oxoethyl) 2-(2,5-difluorophenyl)sulfanylacetate
    —— [2-(2-Acetylhydrazinyl)-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C12H12F2N2O4S
    [2-(2-Acetylhydrazinyl)-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C20H21F2NO3S
    [2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H16F2N2O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H23F2NO3S
    [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— (2R)-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-ethylpropanamide —— C9H15N5O2S
    (2R)-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-ethylpropanamide
    —— N-[2-(2-fluorophenyl)ethyl]-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H28FN5O2S
    N-[2-(2-fluorophenyl)ethyl]-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-[(1S)-cyclopent-2-en-1-yl]acetate —— C17H20BrNO3S
    [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-[(1S)-cyclopent-2-en-1-yl]acetate
    —— (2S)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide —— C11H21N5OS
    (2S)-2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide
    —— N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C16H24N4O3S2
    N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— 4-[4-(2-Methylpropyl)-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine —— C20H25N5O2S
    4-[4-(2-Methylpropyl)-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine
    —— (2R)-N-ethyl-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H24N4OS2
    (2R)-N-ethyl-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 3-cyclopropyl-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine —— C16H18N6OS
    3-cyclopropyl-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— N-[(1S)-1-cyclopropylethyl]-2-[[5-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H24N4O2S3
    N-[(1S)-1-cyclopropylethyl]-2-[[5-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide —— C19H20FN5OS
    2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide
    —— 2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]acetamide —— C16H15ClN4O2S2
    2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]acetamide
    —— [2-[2-(2-methylphenyl)ethylamino]-2-oxoethyl] (2S)-2-(4-methylphenyl)sulfanylpropanoate —— C21H25NO3S
    [2-[2-(2-methylphenyl)ethylamino]-2-oxoethyl] (2S)-2-(4-methylphenyl)sulfanylpropanoate
    —— 2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide —— C20H22FN5OS
    2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide
    —— N-cyclopropyl-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide —— C20H26FN5O2S
    N-cyclopropyl-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide
    —— N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24N4O3S
    N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C19H27N5O2S
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide —— C19H27N5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24N4O3S
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H15ClN4OS
    N-[2-(3-chlorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide —— C17H25N5O2S2
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide
    —— 5-[(3-chlorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C10H10ClN3S2
    5-[(3-chlorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide —— C18H24FN5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide
    —— 5-methyl-7-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-[1,2,4]triazolo[1,5-a]pyrimidine —— C9H9N7S
    5-methyl-7-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-[1,2,4]triazolo[1,5-a]pyrimidine
    —— N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H15N5O2S
    N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole —— C13H12N4OS
    3-[(4-Methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole
    —— 5-[(2-fluorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C10H10FN3S2
    5-[(2-fluorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C9H13N3OS2
    (2S)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C19H27N5O2S
    N-[[4-(dimethylamino)phenyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 4-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine —— C21H23ClN4OS
    4-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine
    —— (2S)-2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C19H27N5O2S
    (2S)-2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— 4-[4-Benzyl-5-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine —— C20H21ClN4OS
    4-[4-Benzyl-5-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine
    —— 2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide —— C19H27N5O2S
    2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide
    —— 2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C22H31N5O2S
    2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-cyanoethyl)acetamide —— C18H22N6O2S
    2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-cyanoethyl)acetamide
    —— 4-[4-Benzyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine —— C22H26N4OS
    4-[4-Benzyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine
    —— 2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylacetamide —— C18H25N5O2S
    2-[(4-benzyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylacetamide
    —— 4-[4-Benzyl-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine —— C21H24N4OS2
    4-[4-Benzyl-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]morpholine