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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-amino-1,3,4-thiadiazol-2-yl)-N'-[(E)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C16H15N5O2S2
    2-(5-amino-1,3,4-thiadiazol-2-yl)-N'-[(E)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide —— C19H18N4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide
    —— 2,2'-(1,3,4-thiadiazole-2,5-diyldisulfanediyl)bis{N'-[(E)-(4-chlorophenyl)methylidene]acetohydrazide} —— C20H16Cl2N6O2S3
    2,2'-(1,3,4-thiadiazole-2,5-diyldisulfanediyl)bis{N'-[(E)-(4-chlorophenyl)methylidene]acetohydrazide}
    —— 2-{[2-(butylsulfanyl)-6-methylpyrimidin-4-yl]sulfanyl}-N'-[(E)-phenylmethylidene]acetohydrazide —— C18H22N4OS2
    2-{[2-(butylsulfanyl)-6-methylpyrimidin-4-yl]sulfanyl}-N'-[(E)-phenylmethylidene]acetohydrazide
    —— 2-[(4-Methoxyphenyl)sulfanyl]benzaldehyde oxime —— C14H13NO2S
    2-[(4-Methoxyphenyl)sulfanyl]benzaldehyde oxime
    —— 3-[(4-chlorophenyl)sulfanyl]-N'-[(E)-phenylmethylidene]propanehydrazide —— C16H15ClN2OS
    3-[(4-chlorophenyl)sulfanyl]-N'-[(E)-phenylmethylidene]propanehydrazide
    —— 2-[(4-methylphenyl)sulfanyl]-N'-[(E)-pyridin-2-ylmethylidene]acetohydrazide —— C15H15N3OS
    2-[(4-methylphenyl)sulfanyl]-N'-[(E)-pyridin-2-ylmethylidene]acetohydrazide
    —— 2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-4-ylmethylideneamino]acetamide —— C18H18ClN7OS
    2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-pyridin-4-ylmethylideneamino]acetamide
    —— (E)-1-(4-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12BrClN4S
    (E)-1-(4-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C15H13ClN4S2
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— N'-[(E)-{4-[(4-ethyl-5-phenyl-4H-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl}methylidene]furan-2-carbohydrazide —— C22H18N6O4S
    N'-[(E)-{4-[(4-ethyl-5-phenyl-4H-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl}methylidene]furan-2-carbohydrazide
    —— N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}pyridine-4-carbohydrazide —— C15H11N7O3S
    N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}pyridine-4-carbohydrazide
    —— (E)-2-((5-amino-1,3,4-thiadiazol-2-yl)thio)-N'-(4-fluorobenzylidene)acetohydrazide —— C11H10FN5OS2
    (E)-2-((5-amino-1,3,4-thiadiazol-2-yl)thio)-N'-(4-fluorobenzylidene)acetohydrazide
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(4-methylphenyl)methylidene]acetohydrazide —— C19H17ClN4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(4-methylphenyl)methylidene]acetohydrazide
    —— N'-[(E)-(3-chlorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C19H17ClN4OS3
    N'-[(E)-(3-chlorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 2-(4-chlorophenoxy)-N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}acetohydrazide —— C17H13ClN6O4S
    2-(4-chlorophenoxy)-N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}acetohydrazide
    —— N'-{(E)-[4-(diethylamino)phenyl]methylidene}-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C23H27N5OS3
    N'-{(E)-[4-(diethylamino)phenyl]methylidene}-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E,2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide —— C22H22N4OS3
    2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E,2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide
    —— N'-(3-pyridinylmethylene)-2-(2-pyridinylsulfanyl)acetohydrazide —— C13H12N4OS
    N'-(3-pyridinylmethylene)-2-(2-pyridinylsulfanyl)acetohydrazide
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-pyridin-4-ylmethylidene]acetohydrazide —— C17H14ClN5OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-pyridin-4-ylmethylidene]acetohydrazide
    —— (E)-N'-(2-chlorobenzylidene)-2-((4-(4-chlorophenyl)thiazol-2-yl)thio)acetohydrazide —— C18H13Cl2N3OS2
    (E)-N'-(2-chlorobenzylidene)-2-((4-(4-chlorophenyl)thiazol-2-yl)thio)acetohydrazide
    —— 2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-methylthiophen-2-yl)methylidene]acetohydrazide —— C18H18N4OS4
    2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-methylthiophen-2-yl)methylidene]acetohydrazide
    —— (E)-1-(4-methylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C18H18N4S
    (E)-1-(4-methylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-[4-(diethylamino)phenyl]methylideneamino]acetamide —— C22H24ClN5OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-[4-(diethylamino)phenyl]methylideneamino]acetamide
    —— N'-[(E)-{3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl}methylidene]furan-2-carbohydrazide —— C19H11N5O6S2
    N'-[(E)-{3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl}methylidene]furan-2-carbohydrazide
    —— 2-(1-methylpyrrol-2-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C15H17N3OS
    2-(1-methylpyrrol-2-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine —— C18H19BrN4OS
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine —— C16H15BrN4OS
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine
    —— N'-(4-(Methylthio)benzylidene)-4,5,6,7-tetrahydro-1H-indazole-3-carbohydrazide —— C16H18N4OS
    N'-(4-(Methylthio)benzylidene)-4,5,6,7-tetrahydro-1H-indazole-3-carbohydrazide
    —— 2-(1-Methylimidazol-2-yl)sulfanyl-5-(sulfinoamino)pyridine —— C9H10N4O2S2
    2-(1-Methylimidazol-2-yl)sulfanyl-5-(sulfinoamino)pyridine
    —— 2-[1-(2-Chloro-phenylamino)-eth-(E)-ylidene]-benzo[b]thiophen-3-one 126318-49-8 C16H12ClNOS
    2-[1-(2-Chloro-phenylamino)-eth-(E)-ylidene]-benzo[b]thiophen-3-one
    —— (1'S,5'S)-N-(2-thiophen-2-ylethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C18H25NOS3
    (1'S,5'S)-N-(2-thiophen-2-ylethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— (1'R,5'R)-N-(2-thiophen-2-ylethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C18H25NOS3
    (1'R,5'R)-N-(2-thiophen-2-ylethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— 2-((6-(Furan-2-yl)pyridazin-3-yl)thio)acetamide —— C10H9N3O2S
    2-((6-(Furan-2-yl)pyridazin-3-yl)thio)acetamide
    —— 1-Mercapto-buta-1,3-diene —— C4H6S
    1-Mercapto-buta-1,3-diene
    —— 2-[1-(3-methylanilino)ethylidene]-1-benzothiophen-3-one —— C17H15NOS
    2-[1-(3-methylanilino)ethylidene]-1-benzothiophen-3-one
    —— 4-Amino-3-[(4-nitrophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid —— C34H24N8O10S3
    4-Amino-3-[(4-nitrophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid
    —— 2-(3-Chlorophenyl)-4-[[4-[4-[[1-(3-chlorophenyl)-3-methyl-5-oxopyrazol-4-ylidene]methylamino]phenyl]sulfanylanilino]methylidene]-5-methylpyrazol-3-one —— C34H26Cl2N6O2S
    2-(3-Chlorophenyl)-4-[[4-[4-[[1-(3-chlorophenyl)-3-methyl-5-oxopyrazol-4-ylidene]methylamino]phenyl]sulfanylanilino]methylidene]-5-methylpyrazol-3-one
    —— [3-(4-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine —— C11H9ClN4OS
    [3-(4-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine
    —— 6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-pentylsulfanyl-2H-1,2,4-triazin-5-one —— C25H26N6O2S
    6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-pentylsulfanyl-2H-1,2,4-triazin-5-one
    —— 6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dibromocyclohexa-2,4-dien-1-one —— C24H16Br2N2OS2
    6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dibromocyclohexa-2,4-dien-1-one
    —— 4-bromo-6-[[2-[4-[methyl-[(4-methyl-1,2,5-oxadiazol-3-yl)methyl]amino]-6-phenylsulfanyl-1,3,5-triazin-2-yl]hydrazinyl]methylidene]cyclohexa-2,4-dien-1-one —— C21H19BrN8O2S
    4-bromo-6-[[2-[4-[methyl-[(4-methyl-1,2,5-oxadiazol-3-yl)methyl]amino]-6-phenylsulfanyl-1,3,5-triazin-2-yl]hydrazinyl]methylidene]cyclohexa-2,4-dien-1-one
    —— 4-fluoro-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]ethenyl}aniline —— C15H17FN4S
    4-fluoro-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]ethenyl}aniline
    —— 2-(1-methylimidazolidin-2-ylidene)-1-benzothiophen-3-one —— C12H12N2OS
    2-(1-methylimidazolidin-2-ylidene)-1-benzothiophen-3-one
    —— (2Z)-5-amino-2-(2-oxo-2-pyrrolidin-1-ylethylidene)-6-(pyrrol-2-ylidenemethyl)-3H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C16H16N6O2S
    (2Z)-5-amino-2-(2-oxo-2-pyrrolidin-1-ylethylidene)-6-(pyrrol-2-ylidenemethyl)-3H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— N-[2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)ethenyl]-4-methylaniline —— C20H20N4S
    N-[2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)ethenyl]-4-methylaniline
    —— 4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one —— C18H16ClN3OS
    4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one
    —— 6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-4-nitrocyclohexa-2,4-dien-1-one —— C18H16N4O3S
    6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-4-nitrocyclohexa-2,4-dien-1-one
    —— 2-[(pyridin-2-ylamino)methylidene]-1-benzothiophen-3-one —— C14H10N2OS
    2-[(pyridin-2-ylamino)methylidene]-1-benzothiophen-3-one
    —— 6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one —— C18H17N3OS
    6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one