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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoate —— C16H10FN2O3S2-
    (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoate
    —— (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoic acid —— C16H11FN2O3S2
    (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoic acid
    —— (E)-2-[4-(4-methylphenyl)-1,3-thiazol-2-yl]-3-(4-methylsulfanylphenyl)prop-2-enenitrile —— C20H16N2S2
    (E)-2-[4-(4-methylphenyl)-1,3-thiazol-2-yl]-3-(4-methylsulfanylphenyl)prop-2-enenitrile
    —— (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid —— C16H11FN2O3S2
    (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S)-1-phenylethyl]propanamide —— C18H23N3OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S)-1-phenylethyl]propanamide
    —— (E)-2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoic acid —— C16H11ClN2O3S2
    (E)-2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylthiophen-2-yl)prop-2-enoic acid
    —— (E)-2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-thiophen-2-ylprop-2-enoate —— C15H8ClN2O3S2-
    (E)-2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-thiophen-2-ylprop-2-enoate
    —— 2-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C18H15ClN2OS
    2-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— 2-(2-bromophenyl)-5-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-1,3,4-oxadiazole —— C17H12BrClN2OS
    2-(2-bromophenyl)-5-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-1,3,4-oxadiazole
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-(4-methyl-1,3-thiazol-2-yl)acetamide —— C14H15N3OS2
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-(4-methyl-1,3-thiazol-2-yl)acetamide
    —— 2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C15H17N3OS2
    2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— N-[(3-chlorophenyl)methyl]-2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H19ClN4OS
    N-[(3-chlorophenyl)methyl]-2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C16H20N4OS2
    2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone —— C19H26N4OS
    2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)ethanone
    —— N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-nitropyridin-1-ium-2-amine —— C16H23N6O2S+
    N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-nitropyridin-1-ium-2-amine
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrrole-2-carboxamide —— C13H13N3OS
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrrole-2-carboxamide
    —— 2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C19H26N4O2S
    2-[(4,5-Dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-nitropyridin-2-amine —— C16H22N6O2S
    N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-nitropyridin-2-amine
    —— 4-(3-ethyl-2H-1,2,4-oxadiazol-5-ylidene)-2,5-dimethyl-N-[(4-methylsulfanylphenyl)methyl]pyrrole-3-sulfonamide —— C18H22N4O3S2
    4-(3-ethyl-2H-1,2,4-oxadiazol-5-ylidene)-2,5-dimethyl-N-[(4-methylsulfanylphenyl)methyl]pyrrole-3-sulfonamide
    —— 2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C15H18N4OS2
    2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— N-(cyclopentylcarbamoyl)-2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H23N5O2S
    N-(cyclopentylcarbamoyl)-2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-(3,4-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide —— C16H16F2N2O4S2
    4-(3,4-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide
    —— 4-(3,4-Difluorophenyl)sulfanylthieno[2,3-d]pyrimidine —— C12H6F2N2S2
    4-(3,4-Difluorophenyl)sulfanylthieno[2,3-d]pyrimidine
    —— 2,5-dimethyl-4-(5-methyl-3H-1,3,4-oxadiazol-2-ylidene)-N-[(4-methylsulfanylphenyl)methyl]pyrrole-3-sulfonamide —— C17H20N4O3S2
    2,5-dimethyl-4-(5-methyl-3H-1,3,4-oxadiazol-2-ylidene)-N-[(4-methylsulfanylphenyl)methyl]pyrrole-3-sulfonamide
    —— [(1S)-cyclohex-3-en-1-yl]-(3-cyclohexylsulfonylazetidin-1-yl)methanone —— C16H25NO3S
    [(1S)-cyclohex-3-en-1-yl]-(3-cyclohexylsulfonylazetidin-1-yl)methanone
    —— [(1R)-cyclohex-3-en-1-yl]-(3-cyclohexylsulfonylazetidin-1-yl)methanone —— C16H25NO3S
    [(1R)-cyclohex-3-en-1-yl]-(3-cyclohexylsulfonylazetidin-1-yl)methanone
    —— 1-[4-(3,4-Difluorophenyl)sulfanyl-3-nitrophenyl]sulfonylpyrrolidine —— C16H14F2N2O4S2
    1-[4-(3,4-Difluorophenyl)sulfanyl-3-nitrophenyl]sulfonylpyrrolidine
    —— 4-[[4-(3,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C19H19F2N3OS2
    4-[[4-(3,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— 3-nitro-N-(2-phenylsulfanylethyl)pyridin-1-ium-2-amine —— C13H14N3O2S+
    3-nitro-N-(2-phenylsulfanylethyl)pyridin-1-ium-2-amine
    —— 2-(3,4-Difluorophenyl)sulfanyl-5-nitrobenzonitrile —— C13H6F2N2O2S
    2-(3,4-Difluorophenyl)sulfanyl-5-nitrobenzonitrile
    —— 3-nitro-N-(2-phenylsulfanylethyl)pyridin-2-amine —— C13H13N3O2S
    3-nitro-N-(2-phenylsulfanylethyl)pyridin-2-amine
    —— 4-[[4-(3,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C19H20F2N3OS2+
    4-[[4-(3,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 2-(2-nitrophenyl)sulfanyl-1H-pyrimidin-6-one —— C10H7N3O3S
    2-(2-nitrophenyl)sulfanyl-1H-pyrimidin-6-one
    —— 2-(2-chloro-4-nitrophenyl)sulfanyl-1H-pyrimidin-6-one —— C10H6ClN3O3S
    2-(2-chloro-4-nitrophenyl)sulfanyl-1H-pyrimidin-6-one
    —— 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1H-pyrimidin-6-one —— C12H10N4OS2
    2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1H-pyrimidin-6-one
    —— 4-propyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1H-pyrimidin-6-one —— C13H12N4OS2
    4-propyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1H-pyrimidin-6-one
    —— 2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-4-propyl-1H-pyrimidin-6-one —— C14H15N3O5S2
    2-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1H-pyrimidin-6-one —— C14H12N4OS2
    2-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1H-pyrimidin-6-one
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(Z)-hydrazinylidenemethyl]-9-methylpyrido[1,2-a]pyrimidin-4-one —— C17H13N5OS2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(Z)-hydrazinylidenemethyl]-9-methylpyrido[1,2-a]pyrimidin-4-one
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-pyrimidin-4-ylsulfanylacetamide —— C11H15N3O2S
    N-[[(2S)-oxolan-2-yl]methyl]-2-pyrimidin-4-ylsulfanylacetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-5-(4-methylphenyl)-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide —— C26H24N2O5S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-5-(4-methylphenyl)-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-5-phenyl-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide —— C25H22N2O5S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-5-phenyl-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-5-(4-methylphenyl)-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide —— C26H24N2O5S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-5-(4-methylphenyl)-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]-2,3-dihydro-1,4-benzodioxine-6-sulfonamide —— C23H23NO7S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]-2,3-dihydro-1,4-benzodioxine-6-sulfonamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]-2,3-dihydro-1,4-benzodioxine-6-sulfonamide —— C23H23NO7S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]-2,3-dihydro-1,4-benzodioxine-6-sulfonamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]methanesulfonamide —— C16H19NO5S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-[(5-phenylsulfanylfuran-2-yl)methyl]methanesulfonamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-5-phenyl-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide —— C25H22N2O5S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-5-phenyl-N-[(5-phenylsulfanylfuran-2-yl)methyl]-1,2-oxazole-3-carboxamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-fluoro-N-[(5-phenylsulfanylfuran-2-yl)methyl]benzenesulfonamide —— C21H20FNO5S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-fluoro-N-[(5-phenylsulfanylfuran-2-yl)methyl]benzenesulfonamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C13H17N5OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5-bromothiophen-2-yl)methyl]-N-prop-2-enylacetamide —— C12H14BrN5OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5-bromothiophen-2-yl)methyl]-N-prop-2-enylacetamide