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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-phenyl-5-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-1,3,4-oxadiazole —— C15H19N3OS
    2-phenyl-5-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-1,3,4-oxadiazole
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide —— C14H18N4OS2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide —— C20H30N4OS2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide
    —— 2-phenyl-5-[(3S)-pyrrolidin-3-yl]sulfanyl-1,3,4-oxadiazole —— C12H13N3OS
    2-phenyl-5-[(3S)-pyrrolidin-3-yl]sulfanyl-1,3,4-oxadiazole
    —— 2-phenyl-5-[[(3R)-piperidin-3-yl]methylsulfanyl]-1,3,4-oxadiazole —— C14H17N3OS
    2-phenyl-5-[[(3R)-piperidin-3-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 2-phenyl-5-[[(3S)-piperidin-3-yl]methylsulfanyl]-1,3,4-oxadiazole —— C14H17N3OS
    2-phenyl-5-[[(3S)-piperidin-3-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 2-phenyl-5-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]-1,3,4-oxadiazole —— C13H15N3OS
    2-phenyl-5-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— N-cycloheptyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H26N4OS2
    N-cycloheptyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-3,4-dimethylbenzenesulfonamide —— C22H23NO2S2
    N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-3,4-dimethylbenzenesulfonamide
    —— [4-[4-(Cyclobutanecarbonyloxy)phenyl]sulfanylphenyl] cyclobutanecarboxylate —— C22H22O4S
    [4-[4-(Cyclobutanecarbonyloxy)phenyl]sulfanylphenyl] cyclobutanecarboxylate
    —— (3-Cyano-4-imino-2-oxopentyl) 3-(2-chlorophenyl)sulfanylpropanoate —— C15H15ClN2O3S
    (3-Cyano-4-imino-2-oxopentyl) 3-(2-chlorophenyl)sulfanylpropanoate
    —— [(4R)-octan-4-yl] chloromethanedithioate —— C9H17ClS2
    [(4R)-octan-4-yl] chloromethanedithioate
    —— (4R)-4-bromo-4H-pyrazole-3-carbothioamide —— C4H4BrN3S
    (4R)-4-bromo-4H-pyrazole-3-carbothioamide
    —— (4S)-4-bromo-4H-pyrazole-3-carbothioamide —— C4H4BrN3S
    (4S)-4-bromo-4H-pyrazole-3-carbothioamide
    —— 2-Ethanimidoyl-3-oxo-4-pyrimidin-2-ylsulfanylbutanenitrile —— C10H10N4OS
    2-Ethanimidoyl-3-oxo-4-pyrimidin-2-ylsulfanylbutanenitrile
    —— 4-[2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethoxy]benzamide —— C21H17ClN2O3S
    4-[2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethoxy]benzamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-3-(4-chlorophenyl)sulfanylpropanamide —— C21H28ClNOS
    N-[(1R)-1-(1-adamantyl)ethyl]-3-(4-chlorophenyl)sulfanylpropanamide
    —— 2-{[3-(2-Methylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}-N-(2-phenylethyl)acetamide —— C28H24N4O2S3
    2-{[3-(2-Methylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}-N-(2-phenylethyl)acetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide —— C21H28FNOS
    N-[(1R)-1-(1-adamantyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C13H19F3N4OS
    N-[(1S,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]cyclopropanecarboxamide —— C18H19NOS
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]cyclopropanecarboxamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-(4-methylphenoxy)propanamide —— C24H25NO2S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-(4-methylphenoxy)propanamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(6-methoxy-1-benzofuran-3-yl)acetamide —— C25H23NO3S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(6-methoxy-1-benzofuran-3-yl)acetamide
    —— 2-(3,4-dimethylphenyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide —— C24H25NOS
    2-(3,4-dimethylphenyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide —— C23H23NO2S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide
    —— (1'S,5'R)-N-(furan-2-ylmethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C17H23NO2S2
    (1'S,5'R)-N-(furan-2-ylmethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— 2-(4-cyanophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C23H20N2O2S
    2-(4-cyanophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— 1-(2,3-Dimethylphenyl)-3-(3-phenylsulfanylpropanoylamino)thiourea —— C18H21N3OS2
    1-(2,3-Dimethylphenyl)-3-(3-phenylsulfanylpropanoylamino)thiourea
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenoxy)acetamide —— C23H23NO3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenoxy)acetamide
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-3-phenylpropanamide —— C21H18BrNOS
    N-[4-(4-bromophenyl)sulfanylphenyl]-3-phenylpropanamide
    —— 1-(Azepan-1-yl)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H18FN3OS3
    1-(Azepan-1-yl)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15FN6S
    3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C12H11BrN6S
    2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— 3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15BrN6S
    3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H22N6OS
    N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H13F2N3OS3
    N-[(4-fluorophenyl)methyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C14H16FN3O2S3
    2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C16H15BrN6S
    N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 3-benzylsulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H16FN5S
    3-benzylsulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-tert-butyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21FN6OS
    N-tert-butyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21FN6OS
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H16BrN5S
    3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C17H17FN6O2S
    2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— N-benzyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H19N7OS
    N-benzyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21N7OS
    N-cyclopentyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-(2-adamantyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C22H27N5OS
    1-(2-adamantyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— N-[(4-fluorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H19FN6OS
    N-[(4-fluorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C11H13N7OS
    2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21FN6OS
    N-cyclopentyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-ethanimidoyl-3-oxo-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C17H19N5O2S2
    2-ethanimidoyl-3-oxo-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile