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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(1S)-cyclohex-2-en-1-yl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine —— C11H18N4OS
    3-[(1S)-cyclohex-2-en-1-yl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine
    —— 3-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine —— C13H16F2N4OS
    3-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine
    —— (3R,5R)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C16H18N2O3S
    (3R,5R)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— 3-(2-methoxyethyl)-5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine —— C14H20N4OS
    3-(2-methoxyethyl)-5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— 2-methyl-5-[(1S)-1-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C15H16N4O2S
    2-methyl-5-[(1S)-1-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— (2S)-2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide —— C11H21N5OS
    (2S)-2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide
    —— (3S)-1-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]pyrrolidin-2-one —— C16H19N3O2S
    (3S)-1-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]pyrrolidin-2-one
    —— 4-cyclohexyl-3-methyl-5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole —— C16H27N3O2S
    4-cyclohexyl-3-methyl-5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole
    —— 6-methyl-3-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C14H15N5OS
    6-methyl-3-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— (2R)-2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide —— C11H21N5OS
    (2R)-2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide
    —— (3S,5S)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C16H18N2O3S
    (3S,5S)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— 3-cyclopropyl-5-[(1R)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C10H12N4OS
    3-cyclopropyl-5-[(1R)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— 3-ethyl-4-methyl-5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole —— C12H21N3O2S
    3-ethyl-4-methyl-5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole
    —— 3-butyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-amine —— C12H22N4OS
    3-butyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-amine
    —— 2-methyl-5-[(1R)-1-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C15H16N4O2S
    2-methyl-5-[(1R)-1-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— 3-butyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-amine —— C12H22N4OS
    3-butyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-4-amine
    —— 3-cyclopropyl-5-[(1S)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C10H12N4OS
    3-cyclopropyl-5-[(1S)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— (3S,5R)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C16H18N2O3S
    (3S,5R)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— 3-[(1R)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine —— C13H16F2N4OS
    3-[(1R)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-(2-methoxyethyl)-1,2,4-triazol-4-amine
    —— 6-methyl-3-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C14H15N5OS
    6-methyl-3-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 3-ethyl-4-methyl-5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole —— C12H21N3O2S
    3-ethyl-4-methyl-5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole
    —— (3R,5S)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C16H18N2O3S
    (3R,5S)-5-methyl-3-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— 5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1H-1,2,4-triazole —— C9H15N3O2S
    5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1H-1,2,4-triazole
    —— (2S)-2-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C14H15N3OS
    (2S)-2-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (2R)-2-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C14H15N3OS
    (2R)-2-[[5-(3-phenylpropyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (2R)-N,N-dimethyl-2-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H19N3O2S
    (2R)-N,N-dimethyl-2-[[5-(2-phenylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 4-cyclohexyl-3-methyl-5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole —— C16H27N3O2S
    4-cyclohexyl-3-methyl-5-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-1,2,4-triazole
    —— 3-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]pyrazine-2-carbonitrile —— C16H16N4S
    3-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]pyrazine-2-carbonitrile
    —— 3-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]pyrazine-2-carbonitrile —— C16H16N4S
    3-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]pyrazine-2-carbonitrile
    —— 5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1H-1,2,4-triazole —— C9H15N3O2S
    5-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-1H-1,2,4-triazole
    —— 4-[[(3S)-1-(6-ethylsulfanylpyrazin-2-yl)piperidin-3-yl]methyl]morpholine —— C16H26N4OS
    4-[[(3S)-1-(6-ethylsulfanylpyrazin-2-yl)piperidin-3-yl]methyl]morpholine
    —— 4-[[(3R)-1-(6-ethylsulfanylpyrazin-2-yl)piperidin-3-yl]methyl]morpholine —— C16H26N4OS
    4-[[(3R)-1-(6-ethylsulfanylpyrazin-2-yl)piperidin-3-yl]methyl]morpholine
    —— 4-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]sulfonylbutanenitrile —— C15H20N2O2S2
    4-[(3S)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]sulfonylbutanenitrile
    —— (3R)-3-(phenylsulfanylmethyl)pyrrolidine-1-sulfonamide —— C11H16N2O2S2
    (3R)-3-(phenylsulfanylmethyl)pyrrolidine-1-sulfonamide
    —— [(2S)-1-(sulfamoylamino)propan-2-yl]sulfanylbenzene —— C9H14N2O2S2
    [(2S)-1-(sulfamoylamino)propan-2-yl]sulfanylbenzene
    —— N-[(2R)-2-phenylsulfanylpropyl]ethanesulfonamide —— C11H17NO2S2
    N-[(2R)-2-phenylsulfanylpropyl]ethanesulfonamide
    —— (E)-3-(1-benzylpyrazol-4-yl)-N'-[2-(2-fluorophenyl)sulfanylacetyl]prop-2-enehydrazide —— C21H19FN4O2S
    (E)-3-(1-benzylpyrazol-4-yl)-N'-[2-(2-fluorophenyl)sulfanylacetyl]prop-2-enehydrazide
    —— (3R)-4,4,4-trifluoro-3-hydroxy-3-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]butanehydrazide —— C14H17F3N2O3S
    (3R)-4,4,4-trifluoro-3-hydroxy-3-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]butanehydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]propanehydrazide —— C20H19FN4O3S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]propanehydrazide
    —— 3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide —— C21H22N4O3S
    3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide
    —— 4-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]sulfonylbutanenitrile —— C15H20N2O2S2
    4-[(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]sulfonylbutanenitrile
    —— Ethyl 4-[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]-4-oxobutanoate —— C14H17FN2O4S
    Ethyl 4-[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]-4-oxobutanoate
    —— 6-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-4-oxo-1-phenylpyridazine-3-carbohydrazide —— C21H20N4O3S
    6-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-4-oxo-1-phenylpyridazine-3-carbohydrazide
    —— 2-[3,5-dimethyl-1-(2-methylpropyl)pyrazol-4-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C19H25FN4O2S
    2-[3,5-dimethyl-1-(2-methylpropyl)pyrazol-4-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— [(2R)-1-(sulfamoylamino)propan-2-yl]sulfanylbenzene —— C9H14N2O2S2
    [(2R)-1-(sulfamoylamino)propan-2-yl]sulfanylbenzene
    —— N-[(2S)-2-phenylsulfanylpropyl]ethanesulfonamide —— C11H17NO2S2
    N-[(2S)-2-phenylsulfanylpropyl]ethanesulfonamide
    —— (3R)-1-ethylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C13H19NO2S2
    (3R)-1-ethylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine
    —— (3S)-3-(phenylsulfanylmethyl)pyrrolidine-1-sulfonamide —— C11H16N2O2S2
    (3S)-3-(phenylsulfanylmethyl)pyrrolidine-1-sulfonamide
    —— (3S)-1-ethylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C13H19NO2S2
    (3S)-1-ethylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine
    —— 1,1-diethyl-3-methyl-3-[(1S,2R)-2-methylsulfonylcyclohexyl]urea —— C13H26N2O3S
    1,1-diethyl-3-methyl-3-[(1S,2R)-2-methylsulfonylcyclohexyl]urea