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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C12H11N3OS
    (2S)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2-methylphenyl)sulfanylacetate —— C16H14N2O3S2
    (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2-methylphenyl)sulfanylacetate
    —— [2-(4-Amino-1-methyl-2,6-dioxo-3-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C19H23N3O5S
    [2-(4-Amino-1-methyl-2,6-dioxo-3-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C14H16N2O3S
    [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-(Tert-butylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C15H21NO3S
    [2-(Tert-butylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— (2R)-1-butylsulfanyl-2-methyl-3-methylsulfonylpropane —— C9H20O2S2
    (2R)-1-butylsulfanyl-2-methyl-3-methylsulfonylpropane
    —— 1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C13H26N2O3S
    1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— 1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C13H26N2O3S
    1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— 1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C13H26N2O3S
    1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— methyl 2,4-dimethyl-5-[(2S)-2-[2-(2-methylphenyl)sulfanylacetyl]oxypropanoyl]-1H-pyrrole-3-carboxylate —— C20H23NO5S
    methyl 2,4-dimethyl-5-[(2S)-2-[2-(2-methylphenyl)sulfanylacetyl]oxypropanoyl]-1H-pyrrole-3-carboxylate
    —— N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2,2-dimethyl-4-methylsulfonylbutan-1-amine —— C15H27NO2S
    N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2,2-dimethyl-4-methylsulfonylbutan-1-amine
    —— [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C20H20N2O3S2
    [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(2-methylphenyl)sulfanylacetate —— C14H19NO3S
    [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(2-methylphenyl)sulfanylacetate
    —— 2-(2-Bromophenyl)-5-[(4-fluorophenyl)sulfanylmethyl]-1,3,4-oxadiazole —— C15H10BrFN2OS
    2-(2-Bromophenyl)-5-[(4-fluorophenyl)sulfanylmethyl]-1,3,4-oxadiazole
    —— (2R)-2-(4-fluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]propanamide —— C16H22FNOS
    (2R)-2-(4-fluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]propanamide
    —— 1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-(2-methyl-2-methylsulfonylpropyl)urea —— C14H28N2O3S
    1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-(2-methyl-2-methylsulfonylpropyl)urea
    —— 1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-(2-methyl-2-methylsulfonylpropyl)urea —— C14H28N2O3S
    1-cyclopropyl-1-[(2S)-3-methylbutan-2-yl]-3-(2-methyl-2-methylsulfonylpropyl)urea
    —— 1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C13H26N2O3S
    1-cyclopropyl-1-[(2R)-3-methylbutan-2-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— 2-[(2R)-2-phenylpropyl]-5-(2-thiomorpholin-4-ylethylsulfanyl)-1,3,4-oxadiazole —— C17H23N3OS2
    2-[(2R)-2-phenylpropyl]-5-(2-thiomorpholin-4-ylethylsulfanyl)-1,3,4-oxadiazole
    —— 2-[(2S)-2-phenylpropyl]-5-(2-thiomorpholin-4-ylethylsulfanyl)-1,3,4-oxadiazole —— C17H23N3OS2
    2-[(2S)-2-phenylpropyl]-5-(2-thiomorpholin-4-ylethylsulfanyl)-1,3,4-oxadiazole
    —— N-[[(1R,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2,2-dimethyl-4-methylsulfonylbutan-1-amine —— C15H27NO2S
    N-[[(1R,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2,2-dimethyl-4-methylsulfonylbutan-1-amine
    —— 2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C13H14ClFN3OS+
    2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— N,N-dimethyl-4-[(2R,5R)-5-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C21H24N4O2S
    N,N-dimethyl-4-[(2R,5R)-5-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— 4-[(2R,5R)-5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline —— C19H23N5O2S
    4-[(2R,5R)-5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline
    —— N,N-dimethyl-4-[(2R,5R)-5-[(4-methyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C16H21N3OS2
    N,N-dimethyl-4-[(2R,5R)-5-[(4-methyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— N,N-dimethyl-4-[(2S,5S)-5-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C15H21N4OS2+
    N,N-dimethyl-4-[(2S,5S)-5-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— 4-[(2R,5S)-5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline —— C19H23N5O2S
    4-[(2R,5S)-5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline
    —— (2S)-N-[(3R)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C19H18F3NO2S
    (2S)-N-[(3R)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-[(3R)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C19H18F3NO2S
    (2R)-N-[(3R)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-[(3S)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C19H18F3NO2S
    (2R)-N-[(3S)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2S)-N-[(3S)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C19H18F3NO2S
    (2S)-N-[(3S)-4,4,4-trifluoro-3-hydroxy-3-phenylbutyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— N,N-dimethyl-4-[(2R,5R)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C21H25N4O2S+
    N,N-dimethyl-4-[(2R,5R)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— N,N-dimethyl-4-[(2S,5S)-5-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C20H25N5O2S
    N,N-dimethyl-4-[(2S,5S)-5-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— 4-[(2S,5R)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline —— C18H20N4O3S
    4-[(2S,5R)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline
    —— N,N-dimethyl-4-[(2S,5S)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C21H25N4O2S+
    N,N-dimethyl-4-[(2S,5S)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— 4-[(2S,5R)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline —— C20H22FN4O2S+
    4-[(2S,5R)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline
    —— 4-[(2S,5R)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline —— C18H21N4O3S+
    4-[(2S,5R)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline
    —— N,N-dimethyl-4-[(2S,5S)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C18H22N5OS2+
    N,N-dimethyl-4-[(2S,5S)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— 4-[(2R,5R)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline —— C20H21FN4O2S
    4-[(2R,5R)-5-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline
    —— 4-[(2S,5S)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline —— C18H20N4O3S
    4-[(2S,5S)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]-N,N-dimethylaniline
    —— N,N-dimethyl-4-[(2S,5R)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C18H21N5OS2
    N,N-dimethyl-4-[(2S,5R)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— (2R)-3-(6-tert-butylimidazo[2,1-b][1,3,4]thiadiazol-2-yl)sulfanylpropane-1,2-diol —— C11H17N3O2S2
    (2R)-3-(6-tert-butylimidazo[2,1-b][1,3,4]thiadiazol-2-yl)sulfanylpropane-1,2-diol
    —— (2S)-2-[4-(2-phenylsulfanylethyl)piperazin-1-yl]propan-1-ol —— C15H24N2OS
    (2S)-2-[4-(2-phenylsulfanylethyl)piperazin-1-yl]propan-1-ol
    —— N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]-6-methylsulfanylpyridazin-3-amine —— C14H24N4OS
    N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]-6-methylsulfanylpyridazin-3-amine
    —— (2R)-2-[4-(2-phenylsulfanylethyl)piperazin-1-yl]propan-1-ol —— C15H24N2OS
    (2R)-2-[4-(2-phenylsulfanylethyl)piperazin-1-yl]propan-1-ol
    —— N,N-dimethyl-4-[(2R,5R)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C21H24N4O2S
    N,N-dimethyl-4-[(2R,5R)-5-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— N,N-dimethyl-4-[(2R,5S)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C20H22N4O2S
    N,N-dimethyl-4-[(2R,5S)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]-6-methylsulfanylpyridazin-3-amine —— C14H24N4OS
    N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]-6-methylsulfanylpyridazin-3-amine
    —— (2S)-3-(6-tert-butylimidazo[2,1-b][1,3,4]thiadiazol-2-yl)sulfanylpropane-1,2-diol —— C11H17N3O2S2
    (2S)-3-(6-tert-butylimidazo[2,1-b][1,3,4]thiadiazol-2-yl)sulfanylpropane-1,2-diol
    —— N,N-dimethyl-4-[(2R,5S)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C20H23N4O2S+
    N,N-dimethyl-4-[(2R,5S)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline