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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-methyl-2-[4-[(3R)-3-methylpiperidin-1-yl]sulfonyl-2-nitrophenyl]sulfanyl-1,3-thiazole —— C16H19N3O4S3
    4-methyl-2-[4-[(3R)-3-methylpiperidin-1-yl]sulfonyl-2-nitrophenyl]sulfanyl-1,3-thiazole
    —— [2-Oxo-2-[(2-phenylacetyl)amino]ethyl] 2-phenylsulfanylpyridine-3-carboxylate —— C22H18N2O4S
    [2-Oxo-2-[(2-phenylacetyl)amino]ethyl] 2-phenylsulfanylpyridine-3-carboxylate
    —— (7R)-7-methyl-4-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C15H14F3N5S2
    (7R)-7-methyl-4-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 3-(2,4-Dinitrophenyl)sulfanyl-4-methyl-5-(trifluoromethyl)-1,2,4-triazole —— C10H6F3N5O4S
    3-(2,4-Dinitrophenyl)sulfanyl-4-methyl-5-(trifluoromethyl)-1,2,4-triazole
    —— 4-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]thieno[2,3-d]pyrimidine —— C10H6F3N5S2
    4-[[4-Methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]thieno[2,3-d]pyrimidine
    —— N-[4-(5-pyrrolidin-1-ylsulfonylpyridin-2-yl)sulfanylphenyl]acetamide —— C17H19N3O3S2
    N-[4-(5-pyrrolidin-1-ylsulfonylpyridin-2-yl)sulfanylphenyl]acetamide
    —— N-tert-butyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-3-nitrobenzenesulfonamide —— C14H17N3O4S3
    N-tert-butyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-3-nitrobenzenesulfonamide
    —— 6-(2,4-dimethylphenyl)sulfanyl-N,N-diethylpyridine-3-sulfonamide —— C17H22N2O2S2
    6-(2,4-dimethylphenyl)sulfanyl-N,N-diethylpyridine-3-sulfonamide
    —— 12-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C13H11N3S3
    12-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 2-(2,4-Dimethylphenyl)sulfanyl-3-nitropyridine —— C13H12N2O2S
    2-(2,4-Dimethylphenyl)sulfanyl-3-nitropyridine
    —— N-[4-(4-fluoro-2-nitrophenyl)sulfanylphenyl]acetamide —— C14H11FN2O3S
    N-[4-(4-fluoro-2-nitrophenyl)sulfanylphenyl]acetamide
    —— N-[4-[5-(diethylsulfamoyl)pyridin-2-yl]sulfanylphenyl]acetamide —— C17H21N3O3S2
    N-[4-[5-(diethylsulfamoyl)pyridin-2-yl]sulfanylphenyl]acetamide
    —— 5-(Methoxymethylsulfanyl)-3-methyl-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidine-2,4-dione —— C15H22N4O3S
    5-(Methoxymethylsulfanyl)-3-methyl-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— N-[4-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide —— C16H15N3OS2
    N-[4-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide
    —— 2-(4-Chloro-2-nitrophenyl)sulfanyl-4-methyl-1,3-thiazole —— C10H7ClN2O2S2
    2-(4-Chloro-2-nitrophenyl)sulfanyl-4-methyl-1,3-thiazole
    —— 1-[(1R)-1-cyclohexylethyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea —— C16H32N2O3S
    1-[(1R)-1-cyclohexylethyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea
    —— 4-Methyl-2-(2-nitro-4-pyrrolidin-1-ylsulfonylphenyl)sulfanyl-1,3-thiazole —— C14H15N3O4S3
    4-Methyl-2-(2-nitro-4-pyrrolidin-1-ylsulfonylphenyl)sulfanyl-1,3-thiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-4-methyl-1,3-thiazole —— C10H7ClN2O2S2
    2-(2-Chloro-4-nitrophenyl)sulfanyl-4-methyl-1,3-thiazole
    —— N-[4-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide —— C20H15N3OS2
    N-[4-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide
    —— N-[4-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide —— C17H17N3OS2
    N-[4-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylphenyl]acetamide
    —— 2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-3-nitropyridine —— C13H10N2O4S
    2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-3-nitropyridine
    —— 4-[6-(2,5-Dimethylphenyl)sulfanylpyridin-3-yl]sulfonylmorpholine —— C17H20N2O3S2
    4-[6-(2,5-Dimethylphenyl)sulfanylpyridin-3-yl]sulfonylmorpholine
    —— 2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-5-piperidin-1-ylsulfonylpyridine —— C18H20N2O4S2
    2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-5-piperidin-1-ylsulfonylpyridine
    —— 1-[(1S)-1-cyclohexylethyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea —— C16H32N2O3S
    1-[(1S)-1-cyclohexylethyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea
    —— N-[4-[4-(methylsulfamoyl)-2-nitrophenyl]sulfanylphenyl]acetamide —— C15H15N3O5S2
    N-[4-[4-(methylsulfamoyl)-2-nitrophenyl]sulfanylphenyl]acetamide
    —— 4-(2,4-Dimethylphenyl)sulfanyl-3-nitrobenzenesulfonamide —— C14H14N2O4S2
    4-(2,4-Dimethylphenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 4-[6-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridin-3-yl]sulfonylmorpholine —— C17H18N2O5S2
    4-[6-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridin-3-yl]sulfonylmorpholine
    —— 1-[(1-methylimidazol-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C15H20N4OS
    1-[(1-methylimidazol-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 12-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-10-[(4-methylpiperidin-1-yl)methyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C20H26N6S2
    12-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-10-[(4-methylpiperidin-1-yl)methyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 1-[(1-methylimidazol-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C15H20N4OS
    1-[(1-methylimidazol-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 6,8-Dichloro-3-(2-nitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine —— C12H6Cl2N4O2S
    6,8-Dichloro-3-(2-nitrophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine
    —— N-[[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine —— C17H24N6S2
    N-[[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine
    —— 6-(2,5-dimethylphenyl)sulfanyl-N,N-diethylpyridine-3-sulfonamide —— C17H22N2O2S2
    6-(2,5-dimethylphenyl)sulfanyl-N,N-diethylpyridine-3-sulfonamide
    —— (7S)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C15H17N5S2
    (7S)-4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 5-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-nitropyridine —— C13H10N2O4S
    5-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-nitropyridine
    —— 2,4-Dimethyl-1-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene —— C15H15NO4S2
    2,4-Dimethyl-1-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethyl-2-[(4-methylpiperidin-1-yl)methyl]thieno[2,3-d]pyrimidine —— C19H26N6S2
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethyl-2-[(4-methylpiperidin-1-yl)methyl]thieno[2,3-d]pyrimidine
    —— 4-[[4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C17H23N6OS2+
    4-[[4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 6-(2,3-dihydro-1,4-benzodioxin-6-ylsulfanyl)-N,N-diethylpyridine-3-sulfonamide —— C17H20N2O4S2
    6-(2,3-dihydro-1,4-benzodioxin-6-ylsulfanyl)-N,N-diethylpyridine-3-sulfonamide
    —— 4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C14H15N5S2
    4-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 6-(4-Fluoro-2-nitrophenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine —— C14H10FNO4S
    6-(4-Fluoro-2-nitrophenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine
    —— 4-Chloro-5-(2,3-dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-phenylpyridazin-3-one —— C18H13ClN2O3S
    4-Chloro-5-(2,3-dihydro-1,4-benzodioxin-6-ylsulfanyl)-2-phenylpyridazin-3-one
    —— 2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C14H10ClN3OS3
    2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 2-(3,4-Dimethylphenyl)sulfanyl-5-pyrrolidin-1-ylsulfonylpyridine —— C17H20N2O2S2
    2-(3,4-Dimethylphenyl)sulfanyl-5-pyrrolidin-1-ylsulfonylpyridine
    —— 2-(2,4-Dimethylphenyl)sulfanyl-5-pyrrolidin-1-ylsulfonylpyridine —— C17H20N2O2S2
    2-(2,4-Dimethylphenyl)sulfanyl-5-pyrrolidin-1-ylsulfonylpyridine
    —— 1-[(1R)-1-(3,5-dimethyl-1,2-oxazol-4-yl)ethyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C17H23N3O2S
    1-[(1R)-1-(3,5-dimethyl-1,2-oxazol-4-yl)ethyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 1-(2-tert-butylsulfonylethyl)-3-[(1R)-1-cyclohexylethyl]urea —— C15H30N2O3S
    1-(2-tert-butylsulfonylethyl)-3-[(1R)-1-cyclohexylethyl]urea
    —— 1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S)-1-(1-methylpyrazol-4-yl)ethyl]urea —— C15H19FN4OS
    1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S)-1-(1-methylpyrazol-4-yl)ethyl]urea
    —— 1-(2-tert-butylsulfonylethyl)-3-[(1S)-1-cyclohexylethyl]urea —— C15H30N2O3S
    1-(2-tert-butylsulfonylethyl)-3-[(1S)-1-cyclohexylethyl]urea
    —— 1-[(1S)-1-(3,5-dimethyl-1,2-oxazol-4-yl)ethyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C17H23N3O2S
    1-[(1S)-1-(3,5-dimethyl-1,2-oxazol-4-yl)ethyl]-3-[(2R)-2-phenylsulfanylpropyl]urea