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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N,N-diethyl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C14H18N4O2S
    (2S)-N,N-diethyl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide —— C21H31N3O3S2
    (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide
    —— (2S)-N-[(2R)-butan-2-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C14H18N4O2S
    (2S)-N-[(2R)-butan-2-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclopropylmethyl)acetamide —— C20H27N3O2S2
    2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclopropylmethyl)acetamide
    —— (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide —— C20H25N3O2S2
    (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide
    —— 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclopropylmethyl)acetamide —— C20H27N3O2S2
    2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(cyclopropylmethyl)acetamide
    —— (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide —— C21H31N3O3S2
    (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide
    —— (2R)-N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C16H20N4O2S
    (2R)-N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-fluorophenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C17H16FN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-fluorophenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— N-[(E)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C24H27BrN6OS
    N-[(E)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-N-[(2R)-butan-2-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C14H18N4O2S
    (2R)-N-[(2R)-butan-2-yl]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-[(4-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide —— C16H17FN2OS
    (2S)-N-[(4-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide
    —— (2S)-N-prop-2-ynyl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C13H12N4O2S
    (2S)-N-prop-2-ynyl-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(4-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide —— C16H17FN2OS
    (2R)-N-[(4-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide
    —— (2S)-N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C16H20N4O2S
    (2S)-N-ethyl-N-(2-methylprop-2-enyl)-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 5-methyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-4,5,6,7-tetrahydro-1-benzothiophene-2-carboxamide —— C20H20N6O3S2
    5-methyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-4,5,6,7-tetrahydro-1-benzothiophene-2-carboxamide
    —— (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]propanamide —— C14H26N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]propanamide
    —— (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide —— C21H31N3O3S2
    (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methoxypropyl)propanamide
    —— (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide —— C20H25N3O2S2
    (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide
    —— (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide —— C20H25N3O2S2
    (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide
    —— 2-({5-[1-(3-chloroanilino)ethyl]-4-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[4-(diethylamino)benzylidene]acetohydrazide —— C24H30ClN7OS
    2-({5-[1-(3-chloroanilino)ethyl]-4-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[4-(diethylamino)benzylidene]acetohydrazide
    —— 2-(4-bromo-3,5-dimethylpyrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C15H17BrN4OS
    2-(4-bromo-3,5-dimethylpyrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— N'-(2-CL-3-PH-2-Propenylidene)2-((4,6-dimethyl-2-pyrimidinyl)thio)acetohydrazide —— C17H17ClN4OS
    N'-(2-CL-3-PH-2-Propenylidene)2-((4,6-dimethyl-2-pyrimidinyl)thio)acetohydrazide
    —— (2S)-N,N-diethyl-2-(4-fluorophenyl)sulfanylpropanamide —— C13H18FNOS
    (2S)-N,N-diethyl-2-(4-fluorophenyl)sulfanylpropanamide
    —— (2S)-N-ethyl-2-(4-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide —— C15H20FNOS
    (2S)-N-ethyl-2-(4-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide
    —— (2R)-N,N-diethyl-2-(4-fluorophenyl)sulfanylpropanamide —— C13H18FNOS
    (2R)-N,N-diethyl-2-(4-fluorophenyl)sulfanylpropanamide
    —— 5-[[(2R,4R)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole —— C12H12ClN3O2S
    5-[[(2R,4R)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole
    —— (2S)-2-[4-[2-(1H-imidazol-2-ylsulfanyl)acetyl]piperazin-1-yl]-2-thiophen-2-ylacetonitrile —— C15H17N5OS2
    (2S)-2-[4-[2-(1H-imidazol-2-ylsulfanyl)acetyl]piperazin-1-yl]-2-thiophen-2-ylacetonitrile
    —— 5-[[(2S,4R)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole —— C12H12ClN3O2S
    5-[[(2S,4R)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole
    —— (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-pentan-2-yl]propanamide —— C14H26N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-pentan-2-yl]propanamide
    —— (2R)-N-ethyl-2-(4-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide —— C15H20FNOS
    (2R)-N-ethyl-2-(4-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide
    —— (2R)-N-ethyl-2-(2-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide —— C15H20FNOS
    (2R)-N-ethyl-2-(2-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide
    —— (2R)-2-[4-[2-(1H-imidazol-2-ylsulfanyl)acetyl]piperazin-1-yl]-2-thiophen-2-ylacetonitrile —— C15H17N5OS2
    (2R)-2-[4-[2-(1H-imidazol-2-ylsulfanyl)acetyl]piperazin-1-yl]-2-thiophen-2-ylacetonitrile
    —— (2S)-N,N-diethyl-2-(2-fluorophenyl)sulfanylpropanamide —— C13H18FNOS
    (2S)-N,N-diethyl-2-(2-fluorophenyl)sulfanylpropanamide
    —— 2-(4-fluoroanilino)-N-[(E)-[2-(4-methylphenyl)sulfanyl-5-nitrophenyl]methylideneamino]acetamide —— C22H19FN4O3S
    2-(4-fluoroanilino)-N-[(E)-[2-(4-methylphenyl)sulfanyl-5-nitrophenyl]methylideneamino]acetamide
    —— 5-[[(2S,4S)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole —— C12H12ClN3O2S
    5-[[(2S,4S)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole
    —— (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-pentan-2-yl]propanamide —— C14H26N4O2S
    (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-pentan-2-yl]propanamide
    —— (2S)-N-ethyl-2-(2-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide —— C15H20FNOS
    (2S)-N-ethyl-2-(2-fluorophenyl)sulfanyl-N-(2-methylprop-2-enyl)propanamide
    —— 5-[[(2R,4S)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole —— C12H12ClN3O2S
    5-[[(2R,4S)-2-(4-chlorophenyl)-1,3-dioxolan-4-yl]methylsulfanyl]-1H-1,2,4-triazole
    —— (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]propanamide —— C14H26N4O2S
    (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]propanamide
    —— N'-[(E)-{4-[(4-chlorophenyl)sulfanyl]phenyl}methylidene]benzohydrazide —— C20H15ClN2OS
    N'-[(E)-{4-[(4-chlorophenyl)sulfanyl]phenyl}methylidene]benzohydrazide
    —— 6-(phenylsulfanyl)imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(2,6-dichlorobenzyl)oxime —— C19H13Cl2N3OS2
    6-(phenylsulfanyl)imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(pyridin-3-yl)ethylidene]acetohydrazide —— C18H16ClN5OS3
    2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(pyridin-3-yl)ethylidene]acetohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2,5-difluorophenyl)methylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C20H16F2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2,5-difluorophenyl)methylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— (2E)-2-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarbothioamide —— C12H9BrClN3OS2
    (2E)-2-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarbothioamide
    —— 6-[(4-methylphenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(3,4-dichlorobenzyl)oxime —— C20H15Cl2N3OS2
    6-[(4-methylphenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(3,4-dichlorobenzyl)oxime
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}acetohydrazide —— C22H24ClN5O2S3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}acetohydrazide
    —— 2-((4-Chlorophenyl)sulfanyl)nicotinaldehyde o-(3-fluorobenzyl)oxime —— C19H14ClFN2OS
    2-((4-Chlorophenyl)sulfanyl)nicotinaldehyde o-(3-fluorobenzyl)oxime
    —— (2S)-2-(5-fluoropyridin-2-yl)-3-(2-methylsulfanylpyridin-4-yl)-3-oxopropanenitrile —— C14H10FN3OS
    (2S)-2-(5-fluoropyridin-2-yl)-3-(2-methylsulfanylpyridin-4-yl)-3-oxopropanenitrile
    —— N'-[(E)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-3-(trifluoromethyl)benzohydrazide —— C20H15F3N2O2S
    N'-[(E)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-3-(trifluoromethyl)benzohydrazide