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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(1S,3R,4S)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine —— C9H20N2O2S
    [(1S,3R,4S)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine
    —— ethyl (1R,3S)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate —— C11H15NO4S
    ethyl (1R,3S)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate
    —— (3R)-3-ethylsulfonyl-2,2-dimethyloxirane —— C6H12O3S
    (3R)-3-ethylsulfonyl-2,2-dimethyloxirane
    —— [(1S,3R,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine —— C10H22N2O2S
    [(1S,3R,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine
    —— (1S,4S)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid —— C9H14O4S
    (1S,4S)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid
    —— (1S,2R,4R)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H14O4S
    (1S,2R,4R)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— [(1S,2S,4R)-2-methyl-4-methylsulfonylcyclopentyl]methanamine —— C8H17NO2S
    [(1S,2S,4R)-2-methyl-4-methylsulfonylcyclopentyl]methanamine
    —— (1S,2S,4S)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile —— C10H17NO3S
    (1S,2S,4S)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— [(1R,2S,4S)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine —— C10H21NO3S
    [(1R,2S,4S)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine
    —— ethyl (1S,3S,4S)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1S,3S,4S)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate
    —— (1R,2S,4S)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentane-1-carbonitrile —— C11H19NO3S
    (1R,2S,4S)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— [(1R,2S,4S)-1-(methoxymethyl)-2-methyl-4-methylsulfonylcyclopentyl]methanamine —— C10H21NO3S
    [(1R,2S,4S)-1-(methoxymethyl)-2-methyl-4-methylsulfonylcyclopentyl]methanamine
    —— ethyl (1S,3S)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate —— C11H15NO4S
    ethyl (1S,3S)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate
    —— (1S,2S,4S)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H14O4S
    (1S,2S,4S)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— ethyl (1R,3R)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate —— C11H15NO4S
    ethyl (1R,3R)-3-cyano-4-methylidene-3-methylsulfonylcyclopentane-1-carboxylate
    —— [(1R,3R,4S)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine —— C9H20N2O2S
    [(1R,3R,4S)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine
    —— ethyl (1R,3S,4R)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1R,3S,4R)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C13H17N5OS2
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— ethyl (1S,4R)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate —— C12H17NO4S
    ethyl (1S,4R)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate
    —— [(1R,2R,4S)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine —— C10H21NO3S
    [(1R,2R,4S)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine
    —— (1S,2S,4S)-1-(hydroxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile —— C9H15NO3S
    (1S,2S,4S)-1-(hydroxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile
    —— ethyl (1S,2S,4S)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate —— C11H17NO4S
    ethyl (1S,2S,4S)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate
    —— ethyl (1S,4R)-1-cyano-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylate —— C11H15NO4S
    ethyl (1S,4R)-1-cyano-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylate
    —— ethyl (1S,4S)-1-cyano-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylate —— C11H15NO4S
    ethyl (1S,4S)-1-cyano-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylate
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide —— C17H17F2NOS
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— [(1R,2R,4R)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine —— C10H21NO3S
    [(1R,2R,4R)-4-(methoxymethyl)-2-methyl-1-methylsulfonylcyclopentyl]methanamine
    —— (1R,2S,4S)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile —— C10H17NO3S
    (1R,2S,4S)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— (1R,2R,4R)-4-(hydroxymethyl)-2-methyl-1-methylsulfonylcyclopentane-1-carbonitrile —— C9H15NO3S
    (1R,2R,4R)-4-(hydroxymethyl)-2-methyl-1-methylsulfonylcyclopentane-1-carbonitrile
    —— ethyl (1S,2S,4S)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1S,2S,4S)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate
    —— ethyl (1R,3S,4R)-3-cyano-4-methyl-3-methylsulfonylcyclopentane-1-carboxylate —— C11H17NO4S
    ethyl (1R,3S,4R)-3-cyano-4-methyl-3-methylsulfonylcyclopentane-1-carboxylate
    —— ethyl (1R,3R)-3-cyano-3-ethylsulfonyl-4-methylidenecyclopentane-1-carboxylate —— C12H17NO4S
    ethyl (1R,3R)-3-cyano-3-ethylsulfonyl-4-methylidenecyclopentane-1-carboxylate
    —— [(1R,3R,4R)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine —— C9H20N2O2S
    [(1R,3R,4R)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine
    —— (1S,2S,4R)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H14O4S
    (1S,2S,4R)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— (1S,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentane-1-carbonitrile —— C11H19NO3S
    (1S,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— ethyl (1S,2S,4R)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1S,2S,4R)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate
    —— ethyl (1R,4R)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate —— C12H17NO4S
    ethyl (1R,4R)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate
    —— [(1R,3R,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine —— C10H22N2O2S
    [(1R,3R,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine
    —— (1R,2S,4R)-4-(hydroxymethyl)-2-methyl-1-methylsulfonylcyclopentane-1-carbonitrile —— C9H15NO3S
    (1R,2S,4R)-4-(hydroxymethyl)-2-methyl-1-methylsulfonylcyclopentane-1-carbonitrile
    —— (1S,4R)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid —— C9H14O4S
    (1S,4R)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid
    —— [(1R,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine —— C11H23NO3S
    [(1R,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine
    —— ethyl (1S,4S)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate —— C12H17NO4S
    ethyl (1S,4S)-1-cyano-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylate
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide —— C17H17F2NOS
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— [(1S,2S,4S)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine —— C11H23NO3S
    [(1S,2S,4S)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine
    —— ethyl (1R,2S,4S)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate —— C11H17NO4S
    ethyl (1R,2S,4S)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate
    —— (1S,2S,4R)-1-(hydroxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile —— C9H15NO3S
    (1S,2S,4R)-1-(hydroxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile
    —— 2-Ethylsulfonylpent-1-en-4-yne —— C7H10O2S
    2-Ethylsulfonylpent-1-en-4-yne
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H14BrN5OS2
    N-[2-(4-bromophenyl)sulfanylethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— ethyl (1S,3R)-3-cyano-3-ethylsulfonyl-4-methylidenecyclopentane-1-carboxylate —— C12H17NO4S
    ethyl (1S,3R)-3-cyano-3-ethylsulfonyl-4-methylidenecyclopentane-1-carboxylate
    —— (1S,2S,4R)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile —— C10H17NO3S
    (1S,2S,4R)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— ethyl (1S,3S,4R)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1S,3S,4R)-3-cyano-3-ethylsulfonyl-4-methylcyclopentane-1-carboxylate