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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(Methylsulfonylmethyl)cyclopropane-1-carbothioamide —— C6H11NO2S2
    1-(Methylsulfonylmethyl)cyclopropane-1-carbothioamide
    —— 1-(Ethylsulfonylmethyl)cyclopropane-1-carbonitrile —— C7H11NO2S
    1-(Ethylsulfonylmethyl)cyclopropane-1-carbonitrile
    —— [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (2E,4E)-hexa-2,4-dienoate —— C16H18BrNO3S
    [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (2E,4E)-hexa-2,4-dienoate
    —— 1-Ethylsulfonylcyclobutane-1-carbothioamide —— C7H13NO2S2
    1-Ethylsulfonylcyclobutane-1-carbothioamide
    —— [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (1R,2R)-2-methylcyclopropane-1-carboxylate —— C15H18BrNO3S
    [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (1R,2R)-2-methylcyclopropane-1-carboxylate
    —— 1-Ethylsulfonylcyclopropane-1-carbothioamide —— C6H11NO2S2
    1-Ethylsulfonylcyclopropane-1-carbothioamide
    —— 1-Methylsulfonylcyclobutane-1-carbothioamide —— C6H11NO2S2
    1-Methylsulfonylcyclobutane-1-carbothioamide
    —— 1-(Methylsulfonyl)cyclopropane-1-carbothioamide —— C5H9NO2S2
    1-(Methylsulfonyl)cyclopropane-1-carbothioamide
    —— (4-Cyclohexyl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)-methanol —— C10H17N3OS
    (4-Cyclohexyl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)-methanol
    —— (4-(4-Fluorobenzyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol —— C11H12FN3OS
    (4-(4-Fluorobenzyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol
    —— (4-(2-Fluorobenzyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol —— C11H12FN3OS
    (4-(2-Fluorobenzyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol
    —— [4-(3-Fluoro-benzyl)-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl]-methanol —— C11H12FN3OS
    [4-(3-Fluoro-benzyl)-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl]-methanol
    —— (4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol —— C6H11N3OS
    (4-Ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(2,4-dimethylphenyl)methyl]-N-methylpropanamide —— C20H27N3OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(2,4-dimethylphenyl)methyl]-N-methylpropanamide
    —— (4-Cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol —— C9H15N3OS
    (4-Cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methanol
    —— (4-(Cyclopropylmethyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol —— C8H13N3OS
    (4-(Cyclopropylmethyl)-5-(methylthio)-4H-1,2,4-triazol-3-yl)methanol
    —— 2-(4-bromophenyl)sulfanyl-N-phenylmethoxyacetamide —— C15H14BrNO2S
    2-(4-bromophenyl)sulfanyl-N-phenylmethoxyacetamide
    —— 3-(4-fluorophenyl)sulfanyl-N-phenylmethoxypropanamide —— C16H16FNO2S
    3-(4-fluorophenyl)sulfanyl-N-phenylmethoxypropanamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-phenylmethoxyacetamide —— C16H16BrNO2S
    2-(4-bromo-2-methylphenyl)sulfanyl-N-phenylmethoxyacetamide
    —— 2-(4-fluorophenyl)sulfanyl-N-phenylmethoxyacetamide —— C15H14FNO2S
    2-(4-fluorophenyl)sulfanyl-N-phenylmethoxyacetamide
    —— 2-(2-methylphenyl)sulfanyl-N-phenylmethoxyacetamide —— C16H17NO2S
    2-(2-methylphenyl)sulfanyl-N-phenylmethoxyacetamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-phenylmethoxypropanamide —— C17H21N3O2S
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-phenylmethoxypropanamide
    —— 3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]propan-1-one —— C20H27N5OS
    3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]propan-1-one
    —— 2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone —— C20H24N6O2S
    2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone
    —— methyl (2S)-2-methoxypropanimidothioate —— C5H11NOS
    methyl (2S)-2-methoxypropanimidothioate
    —— 2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone —— C20H20FN5O2S
    2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone
    —— 2-(4-Bromo-2-methylphenyl)sulfanyl-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone —— C19H22BrN3OS
    2-(4-Bromo-2-methylphenyl)sulfanyl-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone
    —— 7,11-Dithia-dispiro[3.1.5.1]dodecane-2-carboxylic acid —— C11H16O2S2
    7,11-Dithia-dispiro[3.1.5.1]dodecane-2-carboxylic acid
    —— 7,10-Dithiadispiro[3.1.46.14]undecane-2-carboxylic acid —— C10H14O2S2
    7,10-Dithiadispiro[3.1.46.14]undecane-2-carboxylic acid
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C18H21F2N3OS
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C16H13F4NOS
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— ethyl (2S)-2-cyclohexyl-2-methylsulfonylacetate —— C11H20O4S
    ethyl (2S)-2-cyclohexyl-2-methylsulfonylacetate
    —— ethyl (2R)-2-cyclopentyl-2-methylsulfonylacetate —— C10H18O4S
    ethyl (2R)-2-cyclopentyl-2-methylsulfonylacetate
    —— 5-(Ethylsulfonyl)spiro[2.3]hexane-5-carbonitrile —— C9H13NO2S
    5-(Ethylsulfonyl)spiro[2.3]hexane-5-carbonitrile
    —— (5-Ethylsulfonylspiro[2.3]hexan-5-yl)methanol —— C9H16O3S
    (5-Ethylsulfonylspiro[2.3]hexan-5-yl)methanol
    —— 5-Ethylsulfonylspiro[2.3]hexane-5-carboxylic acid —— C9H14O4S
    5-Ethylsulfonylspiro[2.3]hexane-5-carboxylic acid
    —— 5-Methanesulfonyl-spiro[2.3]hexane-5-carboxylic acid ethyl ester —— C10H16O4S
    5-Methanesulfonyl-spiro[2.3]hexane-5-carboxylic acid ethyl ester
    —— 5-Ethanesulfonyl-spiro[2.3]hexane-5-carboxylic acid ethyl ester —— C11H18O4S
    5-Ethanesulfonyl-spiro[2.3]hexane-5-carboxylic acid ethyl ester
    —— (5-Methylsulfonylspiro[2.3]hexan-5-yl)methanol —— C8H14O3S
    (5-Methylsulfonylspiro[2.3]hexan-5-yl)methanol
    —— [(1S,2S)-1-(methoxymethyl)-2-(methylsulfonylmethyl)cyclopropyl]methanol —— C8H16O4S
    [(1S,2S)-1-(methoxymethyl)-2-(methylsulfonylmethyl)cyclopropyl]methanol
    —— ethyl (2S)-2-cyclopentyl-2-methylsulfonylacetate —— C10H18O4S
    ethyl (2S)-2-cyclopentyl-2-methylsulfonylacetate
    —— Methyl 5-methylsulfonylspiro[2.3]hexane-5-carboxylate —— C9H14O4S
    Methyl 5-methylsulfonylspiro[2.3]hexane-5-carboxylate
    —— ethyl (2R)-2-cyclohexyl-2-methylsulfonylacetate —— C11H20O4S
    ethyl (2R)-2-cyclohexyl-2-methylsulfonylacetate
    —— (1R,2S)-1-(aminomethyl)-2-(ethylsulfonylmethyl)cyclopropan-1-amine —— C7H16N2O2S
    (1R,2S)-1-(aminomethyl)-2-(ethylsulfonylmethyl)cyclopropan-1-amine
    —— tert-butyl N-[(1R,2S)-1-(aminomethyl)-2-(methylsulfonylmethyl)cyclopropyl]carbamate —— C11H22N2O4S
    tert-butyl N-[(1R,2S)-1-(aminomethyl)-2-(methylsulfonylmethyl)cyclopropyl]carbamate
    —— (1R,2R)-1-(aminomethyl)-2-(methylsulfonylmethyl)cyclopropan-1-amine —— C6H14N2O2S
    (1R,2R)-1-(aminomethyl)-2-(methylsulfonylmethyl)cyclopropan-1-amine
    —— tert-butyl N-[(1R,2R)-1-(aminomethyl)-2-(ethylsulfonylmethyl)cyclopropyl]carbamate —— C12H24N2O4S
    tert-butyl N-[(1R,2R)-1-(aminomethyl)-2-(ethylsulfonylmethyl)cyclopropyl]carbamate
    —— (1S,2S)-1-amino-2-(methylsulfonylmethyl)cyclopropane-1-carbonitrile —— C6H10N2O2S
    (1S,2S)-1-amino-2-(methylsulfonylmethyl)cyclopropane-1-carbonitrile
    —— (1R,2S)-2-(ethylsulfonylmethyl)-1-(hydroxymethyl)cyclopropane-1-carbonitrile —— C8H13NO3S
    (1R,2S)-2-(ethylsulfonylmethyl)-1-(hydroxymethyl)cyclopropane-1-carbonitrile
    —— [(1R,2R)-1-(methoxymethyl)-2-(methylsulfonylmethyl)cyclopropyl]methanamine —— C8H17NO3S
    [(1R,2R)-1-(methoxymethyl)-2-(methylsulfonylmethyl)cyclopropyl]methanamine