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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole —— C13H21N5OS
    2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole
    —— Methyl 2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate —— C7H10N2O3S
    Methyl 2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— Ethyl 2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate —— C8H12N2O3S
    Ethyl 2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— 2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole —— C10H15N5OS
    2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole
    —— 2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole —— C16H19N5OS
    2-[(4-Ethyl-5-propyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole —— C15H17N5OS
    2-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-5-propyl-1,3,4-oxadiazole
    —— 2-Methyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C9H12N4O2S
    2-Methyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 6-Amino-5-[2-(4-bromophenyl)sulfanylacetyl]-3-methyl-1-propylpyrimidine-2,4-dione —— C16H18BrN3O3S
    6-Amino-5-[2-(4-bromophenyl)sulfanylacetyl]-3-methyl-1-propylpyrimidine-2,4-dione
    —— (2S)-2-(4-bromophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide —— C16H19BrN2OS
    (2S)-2-(4-bromophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate —— C16H13N4O4S-
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate
    —— (2R)-2-(4-bromophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide —— C16H19BrN2OS
    (2R)-2-(4-bromophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide
    —— methyl 3-[2,5-dimethyl-3-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrrol-1-yl]propanoate —— C14H18N4O3S
    methyl 3-[2,5-dimethyl-3-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrrol-1-yl]propanoate
    —— N-[(2S)-4-phenylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(2S)-4-phenylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C16H19N3O4S
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— 1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C18H17N5O2S
    1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 2-thiophen-2-yl-4-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3-oxazole —— C10H8N4OS2
    2-thiophen-2-yl-4-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3-oxazole
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate —— C13H14N3O3S-
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid —— C16H14N4O4S
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid
    —— 1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C17H17FN4OS
    1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (Z)-3-(5-bromothiophen-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C10H7BrN2O3S2
    (Z)-3-(5-bromothiophen-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— methyl 2,4-dimethyl-5-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate —— C13H16N4O3S
    methyl 2,4-dimethyl-5-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate
    —— 2-(1H-1,2,4-triazol-5-ylsulfanyl)-N-(2,2,2-trifluoroethyl)acetamide —— C6H7F3N4OS
    2-(1H-1,2,4-triazol-5-ylsulfanyl)-N-(2,2,2-trifluoroethyl)acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H20N4O3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid —— C16H11ClN2O4S
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(5-methylfuran-2-yl)prop-2-enoic acid
    —— N-(1-adamantyl)-N-[(4-chlorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C21H25ClN4OS
    N-(1-adamantyl)-N-[(4-chlorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(2S)-2-phenylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H16N4OS
    N-[(2S)-2-phenylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoic acid —— C15H17N3O4S
    (E)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-piperidin-1-ylfuran-2-yl)prop-2-enoic acid
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H20N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid —— C16H12N2O4S2
    (Z)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid
    —— N-(1-adamantyl)-N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C19H24N4O2S
    N-(1-adamantyl)-N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (E)-3-(5-bromofuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C10H7BrN2O4S
    (E)-3-(5-bromofuran-2-yl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H15N5OS
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C16H13BrN2O4S
    [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H21BrN2O3S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate —— C20H12NO4S2-
    (E)-2-(1,3-benzoxazol-2-ylsulfanyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoate
    —— (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate —— C18H15ClN3O3S-
    (Z)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate
    —— (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C17H13ClN2O4S
    (E)-3-[5-(5-chloro-2-methylphenyl)furan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid —— C12H12N2O3S2
    (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate —— C17H15N4O4S-
    (Z)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoate
    —— [2-(Methylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C12H14BrNO3S
    [2-(Methylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— N-(2,3-dihydro-1,4-benzodioxin-6-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide —— C21H18N2O3S
    N-(2,3-dihydro-1,4-benzodioxin-6-yl)-2-(4-methylphenyl)sulfanylpyridine-3-carboxamide
    —— 2-[2-[(4-fluorophenyl)sulfanylmethyl]-5-methoxy-4-oxopyridin-1-yl]-N-(furan-2-ylmethyl)acetamide —— C20H19FN2O4S
    2-[2-[(4-fluorophenyl)sulfanylmethyl]-5-methoxy-4-oxopyridin-1-yl]-N-(furan-2-ylmethyl)acetamide
    —— Ethyl 2-[2-[(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methylsulfanyl]-1,3-thiazol-4-yl]acetate —— C14H13N3O3S3
    Ethyl 2-[2-[(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methylsulfanyl]-1,3-thiazol-4-yl]acetate
    —— 1-(2,5-Dimethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea —— C18H20FN3OS2
    1-(2,5-Dimethylphenyl)-3-[3-(4-fluorophenyl)sulfanylpropanoylamino]thiourea
    —— 1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]-2-(2,4,6-trimethylphenyl)sulfanylethanone —— C19H29N2O3S2+
    1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]-2-(2,4,6-trimethylphenyl)sulfanylethanone
    —— N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C15H20ClNO3S2
    N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— 1-(2,5-Dimethylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea —— C18H21N3OS2
    1-(2,5-Dimethylphenyl)-3-[[2-(4-methylphenyl)sulfanylacetyl]amino]thiourea
    —— (2S)-N-benzyl-2-(2,4,6-trimethylphenyl)sulfanylpropanamide —— C19H23NOS
    (2S)-N-benzyl-2-(2,4,6-trimethylphenyl)sulfanylpropanamide
    —— N-(furan-2-ylmethyl)-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C16H19NO2S
    N-(furan-2-ylmethyl)-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— (2S)-N-cyclopentyl-2-(2,4,6-trimethylphenyl)sulfanylpropanamide —— C17H25NOS
    (2S)-N-cyclopentyl-2-(2,4,6-trimethylphenyl)sulfanylpropanamide