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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-Cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetamide —— C17H23N4OS+
    2-[(4-Cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetamide
    —— [5-(4-Bromophenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium —— C16H19BrN5OS+
    [5-(4-Bromophenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium
    —— 2-[(4-Cyano-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]ethyl-dimethylazanium —— C18H28N4S+2
    2-[(4-Cyano-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]ethyl-dimethylazanium
    —— 3-[(4-Fluorobenzyl)sulfanyl]-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C21H22FN3OS
    3-[(4-Fluorobenzyl)sulfanyl]-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 3-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H8BrN2O3S-
    3-[[5-(3-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C9H7N2O4S-
    2-[[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— 2-[4-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]phenyl]acetic acid —— C11H11N3O2S2
    2-[4-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]phenyl]acetic acid
    —— 2-[[5-(5-methylthiophen-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C14H18N4O2S2
    2-[[5-(5-methylthiophen-3-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— ethyl 2-[[5-ethyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H21N3O3S
    ethyl 2-[[5-ethyl-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-Phenylsulfanyl-1-(4-prop-2-enylpiperazin-4-ium-1-yl)ethanone —— C15H21N2OS+
    2-Phenylsulfanyl-1-(4-prop-2-enylpiperazin-4-ium-1-yl)ethanone
    —— 1-(4-Morpholinyl)-3-{[2-(4-morpholinyl)-2-oxoethyl]sulfanyl}-5,6,7,8-tetrahydro-4-isoquinolinecarbonitrile —— C20H26N4O3S
    1-(4-Morpholinyl)-3-{[2-(4-morpholinyl)-2-oxoethyl]sulfanyl}-5,6,7,8-tetrahydro-4-isoquinolinecarbonitrile
    —— 3-[(4-Chlorobenzyl)sulfanyl]-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C21H22ClN3OS
    3-[(4-Chlorobenzyl)sulfanyl]-1-(morpholin-4-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 3-[(2-Hydroxyethyl)sulfanyl]-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile —— C16H21N3OS
    3-[(2-Hydroxyethyl)sulfanyl]-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinoline-4-carbonitrile
    —— 6-Methyl-3-(pentylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C16H18N4OS
    6-Methyl-3-(pentylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 3-(2-Methoxyethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C17H24N3OS+
    3-(2-Methoxyethylsulfanyl)-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-[(4-Chlorophenyl)methylsulfanyl]-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C21H23ClN3OS+
    3-[(4-Chlorophenyl)methylsulfanyl]-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— N-butyl-N-[(2-methylphenyl)methyl]-2-pyridin-4-ylsulfanylacetamide —— C19H24N2OS
    N-butyl-N-[(2-methylphenyl)methyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-[[4-methyl-5-(3-methylbutyl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]acetate —— C12H17N2O3S-
    2-[[4-methyl-5-(3-methylbutyl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]acetate
    —— (2R)-N-(2-morpholin-4-ylethyl)-2-phenylsulfanylpropanamide —— C15H22N2O2S
    (2R)-N-(2-morpholin-4-ylethyl)-2-phenylsulfanylpropanamide
    —— (2S)-N-(2-morpholin-4-ium-4-ylethyl)-2-phenylsulfanylpropanamide —— C15H23N2O2S+
    (2S)-N-(2-morpholin-4-ium-4-ylethyl)-2-phenylsulfanylpropanamide
    —— N-[(Z)-(1-benzyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C21H21FN4OS
    N-[(Z)-(1-benzyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-(2-phenylethyl)-2-pyridin-4-ylsulfanyl-N-(1,3-thiazol-2-ylmethyl)acetamide —— C19H19N3OS2
    N-(2-phenylethyl)-2-pyridin-4-ylsulfanyl-N-(1,3-thiazol-2-ylmethyl)acetamide
    —— N-[(Z)-(2,5-dimethylphenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C17H17FN2OS
    N-[(Z)-(2,5-dimethylphenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— (1S)-1-(3-fluoro-4-methylsulfanylphenyl)-N-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylmethyl)ethanamine —— C17H23FN4S
    (1S)-1-(3-fluoro-4-methylsulfanylphenyl)-N-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylmethyl)ethanamine
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(3R)-3-methylcyclohexylidene]amino]acetamide —— C15H19FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-[(3R)-3-methylcyclohexylidene]amino]acetamide
    —— N-[(Z)-(1-benzyl-5-chloro-3-methylpyrazol-4-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C20H18ClFN4OS
    N-[(Z)-(1-benzyl-5-chloro-3-methylpyrazol-4-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C16H14F2N2OS
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-(4-methylphenyl)ethylideneamino]acetamide —— C17H17FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-1-(4-methylphenyl)ethylideneamino]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(4-methylcyclohexylidene)amino]acetamide —— C15H19FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(4-methylcyclohexylidene)amino]acetamide
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12BrFN2OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-(3-methyl-1-phenylbutylidene)amino]acetamide —— C19H21FN2OS
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-(3-methyl-1-phenylbutylidene)amino]acetamide
    —— 1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C14H19N3OS2
    1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— 2-(2-ethylsulfanyl-4-methyl-6-oxo-1H-pyrimidin-5-yl)acetate —— C9H11N2O3S-
    2-(2-ethylsulfanyl-4-methyl-6-oxo-1H-pyrimidin-5-yl)acetate
    —— N-[(1R)-1-phenylethyl]-N-(pyridin-3-ylmethyl)-2-pyridin-4-ylsulfanylacetamide —— C21H21N3OS
    N-[(1R)-1-phenylethyl]-N-(pyridin-3-ylmethyl)-2-pyridin-4-ylsulfanylacetamide
    —— N-[(5-methyl-1H-imidazol-4-yl)methyl]-N-[(1R)-1-phenylethyl]-2-pyridin-4-ylsulfanylacetamide —— C20H22N4OS
    N-[(5-methyl-1H-imidazol-4-yl)methyl]-N-[(1R)-1-phenylethyl]-2-pyridin-4-ylsulfanylacetamide
    —— ethyl (1S,2S)-2-[[cyclohexyl-(2-pyridin-4-ylsulfanylacetyl)amino]methyl]cyclopropane-1-carboxylate —— C20H28N2O3S
    ethyl (1S,2S)-2-[[cyclohexyl-(2-pyridin-4-ylsulfanylacetyl)amino]methyl]cyclopropane-1-carboxylate
    —— (R)-[5-[(2-fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]-phenylmethanol —— C17H16FN3OS
    (R)-[5-[(2-fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]-phenylmethanol
    —— 3-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-methyl-1-[[(3S)-oxolan-3-yl]methyl]urea —— C17H26N2O2S
    3-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-methyl-1-[[(3S)-oxolan-3-yl]methyl]urea
    —— 1-[6-Methyl-2-(2-oxopropylsulfanyl)pyrimidin-4-yl]sulfanylpropan-2-one —— C11H14N2O2S2
    1-[6-Methyl-2-(2-oxopropylsulfanyl)pyrimidin-4-yl]sulfanylpropan-2-one
    —— 3-Methylsulfanyl-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C15H20N3S+
    3-Methylsulfanyl-1-pyrrolidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— N-[(1-methylpyrrol-2-yl)methyl]-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylacetamide —— C21H30N3O2S+
    N-[(1-methylpyrrol-2-yl)methyl]-N-(3-morpholin-4-ium-4-ylpropyl)-2-phenylsulfanylacetamide
    —— 3-(2-Hydroxyethylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C16H22N3O2S+
    3-(2-Hydroxyethylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C21H28N4O3S
    2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-{[4-cyano-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-3-yl]sulfanyl}-N-(furan-2-ylmethyl)acetamide —— C21H24N4O2S
    2-{[4-cyano-1-(pyrrolidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-3-yl]sulfanyl}-N-(furan-2-ylmethyl)acetamide
    —— 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C22H27N4O2S+
    2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 2-{[4-cyano-1-(piperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-3-yl]sulfanyl}-N-(furan-2-ylmethyl)acetamide —— C22H26N4O2S
    2-{[4-cyano-1-(piperidin-1-yl)-5,6,7,8-tetrahydroisoquinolin-3-yl]sulfanyl}-N-(furan-2-ylmethyl)acetamide
    —— 6-(4-Chlorophenyl)-3-[(phenylsulfanyl)methyl][1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C16H11ClN4S2
    6-(4-Chlorophenyl)-3-[(phenylsulfanyl)methyl][1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— methyl 2-[2-(2-chloroprop-2-enylsulfanyl)-6-oxo-1H-pyrimidin-4-yl]acetate —— C10H11ClN2O3S
    methyl 2-[2-(2-chloroprop-2-enylsulfanyl)-6-oxo-1H-pyrimidin-4-yl]acetate
    —— 2-(1-propylimidazol-2-yl)sulfanyl-1-(1H-pyrrol-2-yl)ethanone —— C12H15N3OS
    2-(1-propylimidazol-2-yl)sulfanyl-1-(1H-pyrrol-2-yl)ethanone
    —— 2-Amino-6-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]pyridin-1-ium-3,5-dicarbonitrile —— C12H10N5S2+
    2-Amino-6-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]pyridin-1-ium-3,5-dicarbonitrile