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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-phenyl-4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3-thiazol-2-amine —— C17H19N5S2
    N-phenyl-4-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3-thiazol-2-amine
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H27N4O2S+
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-hydroxy-N-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-ylmethyl)acetamide —— C9H14N4O2S
    N-hydroxy-N-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-ylmethyl)acetamide
    —— 5-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole —— C11H10N6OS2
    5-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole
    —— (3R)-3-hydroxy-3-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-yl)propanoic acid —— C10H14N2O3S
    (3R)-3-hydroxy-3-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-yl)propanoic acid
    —— (2S)-2-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-yl)-3-methylbutanoic acid —— C10H15N3O2S
    (2S)-2-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-yl)-3-methylbutanoic acid
    —— (2R)-2-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-yl)-3-methylbutanoic acid —— C10H15N3O2S
    (2R)-2-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-yl)-3-methylbutanoic acid
    —— (2S)-2-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid —— C10H15N3O2S
    (2S)-2-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid
    —— N-hydroxy-N-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-ylmethyl)acetamide —— C10H15N3O2S
    N-hydroxy-N-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-ylmethyl)acetamide
    —— (2R)-2-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid —— C10H15N3O2S
    (2R)-2-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid
    —— (3R)-3-hydroxy-3-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-yl)propanoic acid —— C11H15NO3S
    (3R)-3-hydroxy-3-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-yl)propanoic acid
    —— (3S)-3-hydroxy-3-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-yl)propanoic acid —— C10H14N2O3S
    (3S)-3-hydroxy-3-(5,6,7,8-tetrahydroimidazo[2,1-b][1,3]thiazepin-2-yl)propanoic acid
    —— (3R)-3-hydroxy-3-(5,6,7,8-tetrahydropyrazolo[5,1-b][1,3]thiazepin-2-yl)propanoic acid —— C10H14N2O3S
    (3R)-3-hydroxy-3-(5,6,7,8-tetrahydropyrazolo[5,1-b][1,3]thiazepin-2-yl)propanoic acid
    —— (3S)-3-hydroxy-3-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-yl)propanoic acid —— C11H15NO3S
    (3S)-3-hydroxy-3-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-yl)propanoic acid
    —— 2-(1-cyclopropyltetrazol-5-yl)sulfanyl-1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]ethanone —— C20H23N5OS
    2-(1-cyclopropyltetrazol-5-yl)sulfanyl-1-[2,5-dimethyl-1-[(1S)-1-phenylethyl]pyrrol-3-yl]ethanone
    —— (3S)-3-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid —— C10H15N3O2S
    (3S)-3-(5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b][1,3]thiazepin-2-yl)butanoic acid
    —— 2-(1-cyclopropyltetrazol-5-yl)sulfanyl-N-[(1-morpholin-4-ylcyclohexyl)methyl]acetamide —— C17H28N6O2S
    2-(1-cyclopropyltetrazol-5-yl)sulfanyl-N-[(1-morpholin-4-ylcyclohexyl)methyl]acetamide
    —— (3S)-3-hydroxy-3-(5,6,7,8-tetrahydropyrazolo[5,1-b][1,3]thiazepin-2-yl)propanoic acid —— C10H14N2O3S
    (3S)-3-hydroxy-3-(5,6,7,8-tetrahydropyrazolo[5,1-b][1,3]thiazepin-2-yl)propanoic acid
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C18H22N2O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— N-(cyclohexen-1-yl)-N-ethyl-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C14H21N3OS
    N-(cyclohexen-1-yl)-N-ethyl-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— N-hydroxy-N-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-ylmethyl)acetamide —— C11H16N2O2S
    N-hydroxy-N-(2,3,4,5-tetrahydropyrrolo[2,1-b][1,3]thiazepin-8-ylmethyl)acetamide
    —— 4-[(1-Cyclopentyltetrazol-5-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole —— C16H17N5S2
    4-[(1-Cyclopentyltetrazol-5-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole
    —— (2R)-N-carbamoyl-2-(1-propylimidazol-2-yl)sulfanylpropanamide —— C10H16N4O2S
    (2R)-N-carbamoyl-2-(1-propylimidazol-2-yl)sulfanylpropanamide
    —— (9aR)-3-(2-cyclohexylethyl)-7,8,9,9a-tetrahydro-6H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C16H24N4S
    (9aR)-3-(2-cyclohexylethyl)-7,8,9,9a-tetrahydro-6H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— 2-(Pyrrolidin-1-ium-1-ylmethyl)-5-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C14H16N5O2S2+
    2-(Pyrrolidin-1-ium-1-ylmethyl)-5-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-(3,4-dihydro-2H-pyrrolo[2,1-b][1,3]thiazin-7-ylmethyl)-N-hydroxyacetamide —— C10H14N2O2S
    N-(3,4-dihydro-2H-pyrrolo[2,1-b][1,3]thiazin-7-ylmethyl)-N-hydroxyacetamide
    —— N-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide —— C8H12N4O2S
    N-(6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide
    —— N-(6,7-dihydro-5H-imidazo[2,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide —— C9H13N3O2S
    N-(6,7-dihydro-5H-imidazo[2,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide
    —— N-(6,7-dihydro-5H-pyrazolo[5,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide —— C9H13N3O2S
    N-(6,7-dihydro-5H-pyrazolo[5,1-b][1,3]thiazin-2-ylmethyl)-N-hydroxyacetamide
    —— N-[(5-chlorothiophen-2-yl)methyl]-2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-methylacetamide —— C12H14ClN5OS2
    N-[(5-chlorothiophen-2-yl)methyl]-2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-methylacetamide
    —— 1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone —— C19H23N5O2S2
    1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone
    —— N-hydroxy-N-[(6-methyl-2-methylsulfanylpyrimidin-4-yl)methyl]acetamide —— C9H13N3O2S
    N-hydroxy-N-[(6-methyl-2-methylsulfanylpyrimidin-4-yl)methyl]acetamide
    —— N-hydroxy-N-[(2-methylsulfanylpyrimidin-4-yl)methyl]acetamide —— C8H11N3O2S
    N-hydroxy-N-[(2-methylsulfanylpyrimidin-4-yl)methyl]acetamide
    —— N-(2,3-dihydropyrrolo[2,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide —— C9H12N2O2S
    N-(2,3-dihydropyrrolo[2,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide
    —— N-hydroxy-N-[(2-methylsulfanylpyrimidin-5-yl)methyl]acetamide —— C8H11N3O2S
    N-hydroxy-N-[(2-methylsulfanylpyrimidin-5-yl)methyl]acetamide
    —— N-(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide —— C8H11N3O2S
    N-(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide
    —— N-(2,3-dihydropyrazolo[5,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide —— C8H11N3O2S
    N-(2,3-dihydropyrazolo[5,1-b][1,3]thiazol-6-ylmethyl)-N-hydroxyacetamide
    —— 2-((1-Methyl-1h-tetrazol-5-yl)thio)-1-(5-methylthiophen-2-yl)ethan-1-one —— C9H10N4OS2
    2-((1-Methyl-1h-tetrazol-5-yl)thio)-1-(5-methylthiophen-2-yl)ethan-1-one
    —— 1-{[4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3,3-dimethylbutan-2-one —— C14H19N3OS2
    1-{[4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3,3-dimethylbutan-2-one
    —— 5-Thiophen-2-yl-3-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,2-oxazole —— C14H11N5OS3
    5-Thiophen-2-yl-3-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,2-oxazole
    —— 4,6-Diamino-2-[(3-chlorophenyl)methylsulfanyl]pyridine-3-carbonitrile —— C13H11ClN4S
    4,6-Diamino-2-[(3-chlorophenyl)methylsulfanyl]pyridine-3-carbonitrile
    —— (2R)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylbutanenitrile —— C14H12N6OS3
    (2R)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylbutanenitrile
    —— 4,6-Diamino-2-[(3-chlorophenyl)methylsulfanyl]pyridin-1-ium-3-carbonitrile —— C13H12ClN4S+
    4,6-Diamino-2-[(3-chlorophenyl)methylsulfanyl]pyridin-1-ium-3-carbonitrile
    —— 1-(3-Isocyanatopropyl)-4-propan-2-ylsulfanylbenzene —— C13H17NOS
    1-(3-Isocyanatopropyl)-4-propan-2-ylsulfanylbenzene
    —— (3R)-3-(4-cyclopentylsulfanylphenyl)-3-(methylamino)propan-1-ol —— C15H23NOS
    (3R)-3-(4-cyclopentylsulfanylphenyl)-3-(methylamino)propan-1-ol
    —— (1R)-2-(propan-2-ylamino)-1-(4-propan-2-ylsulfanylphenyl)ethanol —— C14H23NOS
    (1R)-2-(propan-2-ylamino)-1-(4-propan-2-ylsulfanylphenyl)ethanol
    —— (3S)-3-(4-cyclopentylsulfanylphenyl)-3-(methylamino)propan-1-ol —— C15H23NOS
    (3S)-3-(4-cyclopentylsulfanylphenyl)-3-(methylamino)propan-1-ol
    —— (3R)-3-cyclopropyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C15H23NS
    (3R)-3-cyclopropyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— (3S)-3-cyclopropyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine —— C15H23NS
    (3S)-3-cyclopropyl-3-(4-propan-2-ylsulfanylphenyl)propan-1-amine
    —— (1R)-1-(4-cyclopentylsulfanylphenyl)-2-(ethylamino)ethanol —— C15H23NOS
    (1R)-1-(4-cyclopentylsulfanylphenyl)-2-(ethylamino)ethanol