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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]acetamide —— C18H25N3OS
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]acetamide
    —— (5S,7S)-1-isothiocyanato-3-methyladamantane —— C12H17NS
    (5S,7S)-1-isothiocyanato-3-methyladamantane
    —— (5R,7R)-1-isothiocyanato-3-methyladamantane —— C12H17NS
    (5R,7R)-1-isothiocyanato-3-methyladamantane
    —— (3R,5R)-1-isothiocyanato-3,5-dimethyladamantane —— C13H19NS
    (3R,5R)-1-isothiocyanato-3,5-dimethyladamantane
    —— (1S,2S,5R)-2-phenylsulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one —— C12H12O3S
    (1S,2S,5R)-2-phenylsulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one
    —— 3-[(S)-dodecylsulfinyl]propanoic acid —— C15H30O3S
    3-[(S)-dodecylsulfinyl]propanoic acid
    —— (2R)-3-amino-2-[2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-3-enenitrile —— C14H11BrN4O2S
    (2R)-3-amino-2-[2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-3-enenitrile
    —— (3S,5S)-1-isothiocyanato-3,5-dimethyladamantane —— C13H19NS
    (3S,5S)-1-isothiocyanato-3,5-dimethyladamantane
    —— (1R,4S,5R)-5-isothiocyanatobicyclo[2.2.1]hept-2-ene —— C8H9NS
    (1R,4S,5R)-5-isothiocyanatobicyclo[2.2.1]hept-2-ene
    —— (1R,6S,7R,12R)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione —— C14H18S
    (1R,6S,7R,12R)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione
    —— (1R,6S,7R,12S)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione —— C14H18S
    (1R,6S,7R,12S)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione
    —— N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-2-[3-(trifluoromethyl)anilino]acetamide —— C20H15F3N6O3S
    N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-2-[3-(trifluoromethyl)anilino]acetamide
    —— 1-(3-chloro-2-methylphenyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C18H16ClN7O2S2
    1-(3-chloro-2-methylphenyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— 1-(2-methylprop-2-enyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C15H17N7O2S2
    1-(2-methylprop-2-enyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— (1S,2S,3S,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1S,2S,3S,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— (1S,2R,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1S,2R,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— (1R,6R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]bicyclo[4.1.0]heptane-7-carboxamide —— C16H20N2OS
    (1R,6R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]bicyclo[4.1.0]heptane-7-carboxamide
    —— N-[(Z)-[2-methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-morpholin-4-ylsulfonylbenzamide —— C26H25N9O4S2
    N-[(Z)-[2-methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-morpholin-4-ylsulfonylbenzamide
    —— 3-[(Z)-methoxyiminomethyl]-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one —— C17H15N3O2S
    3-[(Z)-methoxyiminomethyl]-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one
    —— 2-(Trifluoromethylthio)benzaldoxime —— C8H6F3NOS
    2-(Trifluoromethylthio)benzaldoxime
    —— 1-bromo-2-[(S)-methylsulfinyl]ethane —— C3H7BrOS
    1-bromo-2-[(S)-methylsulfinyl]ethane
    —— 1-bromo-2-[(R)-methylsulfinyl]ethane —— C3H7BrOS
    1-bromo-2-[(R)-methylsulfinyl]ethane
    —— (1R,6R,7S,12S)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione —— C14H18S
    (1R,6R,7S,12S)-pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane-3-thione
    —— 3-(2,4,5-Trichlorphenylthio)-1-propin 17727-63-8 C9H5Cl3S
    3-(2,4,5-Trichlorphenylthio)-1-propin
    —— 3-fluoro-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide —— C21H14FN3O2S
    3-fluoro-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— 2-[(4Z)-4-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-2,5-dioxoimidazolidin-1-yl]-N-(2-methylphenyl)acetamide —— C25H20ClN3O3S
    2-[(4Z)-4-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-2,5-dioxoimidazolidin-1-yl]-N-(2-methylphenyl)acetamide
    —— 2-methyl-3-[(Z)-(4-phenylsulfanylphenyl)methylideneamino]quinazolin-4-one —— C22H17N3OS
    2-methyl-3-[(Z)-(4-phenylsulfanylphenyl)methylideneamino]quinazolin-4-one
    —— (3S)-1-aminopentane-3-thiol —— C5H13NS
    (3S)-1-aminopentane-3-thiol
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine —— C20H21ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine
    —— 4-[(Z)-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline —— C23H28BrN5S
    4-[(Z)-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline
    —— (2R)-2-(4-ethylsulfanylphenyl)-4-piperazin-1-ylbutan-2-ol —— C16H26N2OS
    (2R)-2-(4-ethylsulfanylphenyl)-4-piperazin-1-ylbutan-2-ol
    —— (2S)-2-(4-ethylsulfanylphenyl)-4-piperazin-1-ylbutan-2-ol —— C16H26N2OS
    (2S)-2-(4-ethylsulfanylphenyl)-4-piperazin-1-ylbutan-2-ol
    —— 2-(4-ethylsulfanylphenyl)sulfanyl-1-piperazin-1-ylethanone —— C14H20N2OS2
    2-(4-ethylsulfanylphenyl)sulfanyl-1-piperazin-1-ylethanone
    —— (2R)-1-piperazin-1-yl-2-(4-propan-2-ylsulfanylphenyl)propan-2-ol —— C16H26N2OS
    (2R)-1-piperazin-1-yl-2-(4-propan-2-ylsulfanylphenyl)propan-2-ol
    —— N-methyl-2-[5-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-2-yl]ethanamine —— C15H20N2S2
    N-methyl-2-[5-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-2-yl]ethanamine
    —— 3-[4-(4-ethylsulfanylphenyl)-1,3-thiazol-2-yl]propanoic acid —— C14H15NO2S2
    3-[4-(4-ethylsulfanylphenyl)-1,3-thiazol-2-yl]propanoic acid
    —— 5-(4-methylsulfanylphenyl)-1-piperazin-1-ylpentan-1-one —— C16H24N2OS
    5-(4-methylsulfanylphenyl)-1-piperazin-1-ylpentan-1-one
    —— (2R)-2-cyclohexyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid —— C17H24O2S
    (2R)-2-cyclohexyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid
    —— (2S)-2-cyclohexyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid —— C17H24O2S
    (2S)-2-cyclohexyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid
    —— N-methyl-2-[4-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-2-yl]ethanamine —— C15H20N2S2
    N-methyl-2-[4-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-2-yl]ethanamine
    —— 2-(4-butylphenyl)sulfanyl-1-piperazin-1-ylethanone —— C16H24N2OS
    2-(4-butylphenyl)sulfanyl-1-piperazin-1-ylethanone
    —— 1-[(1R)-1-(4-cyclopentylsulfanylphenyl)ethyl]piperazine —— C17H26N2S
    1-[(1R)-1-(4-cyclopentylsulfanylphenyl)ethyl]piperazine
    —— (R)-(4-cyclopentylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C17H25NOS
    (R)-(4-cyclopentylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— (S)-(4-cyclopentylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol —— C17H25NOS
    (S)-(4-cyclopentylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol
    —— (R)-(4-cyclopentylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol —— C17H25NOS
    (R)-(4-cyclopentylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol
    —— (S)-(4-cyclopentylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C17H25NOS
    (S)-(4-cyclopentylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— [4-(4-cyclopentylsulfanylphenyl)-1,3-thiazol-2-yl]methanamine —— C15H18N2S2
    [4-(4-cyclopentylsulfanylphenyl)-1,3-thiazol-2-yl]methanamine
    —— 1-[(1S)-1-(4-cyclopentylsulfanylphenyl)ethyl]piperazine —— C17H26N2S
    1-[(1S)-1-(4-cyclopentylsulfanylphenyl)ethyl]piperazine
    —— [1-(4-cyclopentylsulfanylphenyl)cyclohexyl]methanamine —— C18H27NS
    [1-(4-cyclopentylsulfanylphenyl)cyclohexyl]methanamine
    —— (2S)-2-cyclopentyl-2-(4-cyclopentylsulfanylphenyl)ethanamine —— C18H27NS
    (2S)-2-cyclopentyl-2-(4-cyclopentylsulfanylphenyl)ethanamine