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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[4-Tert-butyl-5-(4-chlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid —— C23H25ClN2O2S
    2-[4-Tert-butyl-5-(4-chlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid
    —— [(Z)-1-butyltellanyl-2-phenylsulfanylethenoxy]-trimethylsilane —— C15H24OSSiTe
    [(Z)-1-butyltellanyl-2-phenylsulfanylethenoxy]-trimethylsilane
    —— 2-[4-methylsulfonyl-5-(1H-pyrazol-5-ylsulfanyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid —— C17H18N4O4S2
    2-[4-methylsulfonyl-5-(1H-pyrazol-5-ylsulfanyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid
    —— [4-(Piperidine-1-carbothioylsulfanyl)phenyl] piperidine-1-carbodithioate —— C18H24N2S4
    [4-(Piperidine-1-carbothioylsulfanyl)phenyl] piperidine-1-carbodithioate
    —— (3R)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3R)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— (3S)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H15NOS2
    (3S)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— 4,5,6-tris(methylsulfanyl)-1,2,3-dithiazine —— C6H9NS5
    4,5,6-tris(methylsulfanyl)-1,2,3-dithiazine
    —— (3S)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3S)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— 4,5,6-Tris(methylsulfanyl)dithiazin-3-ium;iodide —— C6H10INS5
    4,5,6-Tris(methylsulfanyl)dithiazin-3-ium;iodide
    —— (3R)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3R)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— (3R)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H15NOS2
    (3R)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— (3S)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3S)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— Oct-4-ynethioic acid S-(cyclohexyl-phenylsulfanyl-methyl) ester —— C21H28OS2
    Oct-4-ynethioic acid S-(cyclohexyl-phenylsulfanyl-methyl) ester
    —— (2R)-2-[(R)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine hydrochloride 667876-43-9 C19H23NOS*ClH
    (2R)-2-[(R)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine hydrochloride
    —— 1-(4-methylsulfanylphenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide —— C20H17NOS2
    1-(4-methylsulfanylphenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide
    —— 1-(4-nitrophenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide —— C19H14N2O3S
    1-(4-nitrophenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide
    —— N-(4-hydroxybutyl)-3-{2-[(4-methylphenyl)thio]phenyl}propanamide 710960-03-5 C20H25NO2S
    N-(4-hydroxybutyl)-3-{2-[(4-methylphenyl)thio]phenyl}propanamide
    —— N-(3-fluorophenyl)-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-amine —— C17H12FN5S
    N-(3-fluorophenyl)-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-amine
    —— Thioacetic acid S-((E)-1-phenylsulfanyl-undec-5-enyl) ester —— C19H28OS2
    Thioacetic acid S-((E)-1-phenylsulfanyl-undec-5-enyl) ester
    —— 1-[5-[(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-1,3,4-oxadiazol-2-yl]ethanone —— C15H19N5O2S
    1-[5-[(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-1,3,4-oxadiazol-2-yl]ethanone
    —— (2R,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2R,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (2S,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2S,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (3S)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C12H17NO2S2
    (3S)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine
    —— (3R)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C12H17NO2S2
    (3R)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine
    —— (2R,3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2R,3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (2S,3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2S,3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (2R)-4-methyl-5,5-bis(phenylsulfanyl)pent-4-en-2-ol —— C18H20OS2
    (2R)-4-methyl-5,5-bis(phenylsulfanyl)pent-4-en-2-ol
    —— 1-[(3S)-3-hydroxy-3-(trifluoromethyl)pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C13H14F3NO2S
    1-[(3S)-3-hydroxy-3-(trifluoromethyl)pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— (2R)-1-(2,3-dihydropyrido[2,3-b][1,4]thiazin-1-yl)-2-thiophen-2-ylpropan-1-one —— C14H14N2OS2
    (2R)-1-(2,3-dihydropyrido[2,3-b][1,4]thiazin-1-yl)-2-thiophen-2-ylpropan-1-one
    —— (2S)-1-(2,3-dihydropyrido[2,3-b][1,4]thiazin-1-yl)-2-thiophen-2-ylpropan-1-one —— C14H14N2OS2
    (2S)-1-(2,3-dihydropyrido[2,3-b][1,4]thiazin-1-yl)-2-thiophen-2-ylpropan-1-one
    —— 2-(1-Hydroxy-3-methylbut-2-enyl)-4-(2-methyl-1,3-dithian-2-yl)phenol —— C16H22O2S2
    2-(1-Hydroxy-3-methylbut-2-enyl)-4-(2-methyl-1,3-dithian-2-yl)phenol
    —— (E,5R,6R)-5-methoxy-2,2-dimethyl-6-phenylsulfanylnon-7-en-3-one —— C18H26O2S
    (E,5R,6R)-5-methoxy-2,2-dimethyl-6-phenylsulfanylnon-7-en-3-one
    —— 3-Hydroxy-5,5-dimethyl-2-(1-phenylsulfanyl-butyl)-cyclohex-2-enone —— C18H24O2S
    3-Hydroxy-5,5-dimethyl-2-(1-phenylsulfanyl-butyl)-cyclohex-2-enone
    —— 2-[[2-amino-4-(2-[18F]fluoroethyl)phenyl]thio]-N,N-dimethylbenzenemethanamine —— C17H21FN2S
    2-[[2-amino-4-(2-[18F]fluoroethyl)phenyl]thio]-N,N-dimethylbenzenemethanamine
    —— 1-[(3R)-3-hydroxy-3-(trifluoromethyl)pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C13H14F3NO2S
    1-[(3R)-3-hydroxy-3-(trifluoromethyl)pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,5S)-3,5-dimethylmorpholin-4-yl]methanone —— C15H19NO2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,5S)-3,5-dimethylmorpholin-4-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,5R)-3,5-dimethylmorpholin-4-yl]methanone —— C15H19NO2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,5R)-3,5-dimethylmorpholin-4-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,5S)-3,5-dimethylmorpholin-4-yl]methanone —— C15H19NO2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,5S)-3,5-dimethylmorpholin-4-yl]methanone
    —— 6-[(1R)-1-thiophen-2-ylethyl]sulfanylpyridine-3-carbonitrile —— C12H10N2S2
    6-[(1R)-1-thiophen-2-ylethyl]sulfanylpyridine-3-carbonitrile
    —— 6-[(1S)-1-thiophen-2-ylethyl]sulfanylpyridine-3-carbonitrile —— C12H10N2S2
    6-[(1S)-1-thiophen-2-ylethyl]sulfanylpyridine-3-carbonitrile
    —— ethyl 1-ethyl-1,4-dihydro-7-methylthio-4-oxoimidazo<1,5-b>pyridazine-3-carboxylate 156335-50-1 C12H15N3O3S
    ethyl 1-ethyl-1,4-dihydro-7-methylthio-4-oxoimidazo<1,5-b>pyridazine-3-carboxylate
    —— 1-((Z)-2-Cyclohexyl-1-nitro-vinylsulfanyl)-4-methyl-benzene —— C15H19NO2S
    1-((Z)-2-Cyclohexyl-1-nitro-vinylsulfanyl)-4-methyl-benzene
    —— (Z,3S,4S)-1-diazonio-3-methyl-4-phenylsulfanyloct-1-en-2-olate —— C15H20N2OS
    (Z,3S,4S)-1-diazonio-3-methyl-4-phenylsulfanyloct-1-en-2-olate
    —— N-[(3R)-1-azabicyclo[2.2.2]octan-3-yl]-5-(3-chlorophenyl)sulfanyl-1,3,4-thiadiazole-2-carboxamide —— C16H17ClN4OS2
    N-[(3R)-1-azabicyclo[2.2.2]octan-3-yl]-5-(3-chlorophenyl)sulfanyl-1,3,4-thiadiazole-2-carboxamide
    —— 1-(2,2,3,3-tetramethylcyclopropyl)-N-[4-methyl-1-[5-(1-methylethylthio)-1,3,4-oxadiazol-2-yl]-1-oxo-2-pentyl]carboxamide 477345-60-1 C19H31N3O3S
    1-(2,2,3,3-tetramethylcyclopropyl)-N-[4-methyl-1-[5-(1-methylethylthio)-1,3,4-oxadiazol-2-yl]-1-oxo-2-pentyl]carboxamide
    —— (2Z,3Z)-2,3-bis[amino-(3-aminophenyl)sulfanylmethylidene]butanedinitrile —— C18H16N6S2
    (2Z,3Z)-2,3-bis[amino-(3-aminophenyl)sulfanylmethylidene]butanedinitrile
    —— 4-[5-methyl-3-(3,3,3-trifluoropropylsulfanyl)-1,2-oxazol-4-yl]-N-phenylpyrimidin-2-amine —— C17H15F3N4OS
    4-[5-methyl-3-(3,3,3-trifluoropropylsulfanyl)-1,2-oxazol-4-yl]-N-phenylpyrimidin-2-amine
    —— [5-(3,5-Dichlorophenyl)sulfanyl-1,3-dimethylpyrazol-4-yl]-phenylmethanol —— C18H16Cl2N2OS
    [5-(3,5-Dichlorophenyl)sulfanyl-1,3-dimethylpyrazol-4-yl]-phenylmethanol
    —— [5-(Furan-2-yl)-2H-pyrazol-3-yl]-[6-Methyl-2-(4-methyl-phenylsulfanylmethyl)-pyrimidin-4-yl]-amine 438206-05-4 C20H19N5OS
    [5-(Furan-2-yl)-2H-pyrazol-3-yl]-[6-Methyl-2-(4-methyl-phenylsulfanylmethyl)-pyrimidin-4-yl]-amine
    —— exo-6-(3-(4-thiocarbamylbenzylthio)-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C17H20N4S3
    exo-6-(3-(4-thiocarbamylbenzylthio)-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane