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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H18N4O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-benzyl-N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C16H16N4O2S
    N-benzyl-N-(furan-2-ylmethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H18N4O4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[3-(N-methylanilino)propyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H19N5OS
    N-[3-(N-methylanilino)propyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H16N4OS2
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-propyl-N-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H16N6O2S2
    N-propyl-N-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C15H14N4OS2
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-ethyl-N-[(3-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H15FN4OS
    N-ethyl-N-[(3-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(5-Bromothiophen-2-yl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C12H8BrN3O2S2
    2-(5-Bromothiophen-2-yl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C18H15FN2O2S2
    N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C21H27N3O3S
    N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C16H15NO4S
    1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C19H17ClN4O3S
    N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 3-[(1-Oxidopyridin-1-ium-2-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole —— C15H12N2O2S
    3-[(1-Oxidopyridin-1-ium-2-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole
    —— 1-[(Z)-3-(furan-2-yl)prop-2-enyl]-4-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperidine —— C17H24N4OS
    1-[(Z)-3-(furan-2-yl)prop-2-enyl]-4-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperidine
    —— 1-(Furan-2-ylmethyl)-3-(2-phenylsulfanylethyl)thiourea —— C14H16N2OS2
    1-(Furan-2-ylmethyl)-3-(2-phenylsulfanylethyl)thiourea
    —— 4-[(5-methyl-1,2-oxazol-3-yl)methyl]-N-(2-phenylsulfanylethyl)piperazine-1-carbothioamide —— C18H24N4OS2
    4-[(5-methyl-1,2-oxazol-3-yl)methyl]-N-(2-phenylsulfanylethyl)piperazine-1-carbothioamide
    —— 1-(2-Morpholin-4-ylethyl)-3-(2-phenylsulfanylethyl)thiourea —— C15H23N3OS2
    1-(2-Morpholin-4-ylethyl)-3-(2-phenylsulfanylethyl)thiourea
    —— 1-(2-Adamantyl)-3-(2-phenylsulfanylethyl)thiourea —— C19H26N2S2
    1-(2-Adamantyl)-3-(2-phenylsulfanylethyl)thiourea
    —— 1-(dimethylamino)-1-[(3R)-1,1-dioxothiolan-3-yl]-3-(2-phenylsulfanylethyl)thiourea —— C15H23N3O2S3
    1-(dimethylamino)-1-[(3R)-1,1-dioxothiolan-3-yl]-3-(2-phenylsulfanylethyl)thiourea
    —— 1-(2-phenylsulfanylethyl)-3-[(R)-phenyl(thiophen-2-yl)methyl]thiourea —— C20H20N2S3
    1-(2-phenylsulfanylethyl)-3-[(R)-phenyl(thiophen-2-yl)methyl]thiourea
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-4-[(5-methyl-1,2-oxazol-3-yl)methyl]piperazin-4-ium-1-carbothioamide —— C18H24ClN4OS2+
    N-[2-(4-chlorophenyl)sulfanylethyl]-4-[(5-methyl-1,2-oxazol-3-yl)methyl]piperazin-4-ium-1-carbothioamide
    —— 1-Benzyl-3-(2-phenylsulfanylethyl)thiourea —— C16H18N2S2
    1-Benzyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-Ethyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea —— C13H25N5S2
    1-Ethyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea
    —— 1-Cyclopropyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea —— C14H25N5S2
    1-Cyclopropyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea
    —— 4-[(5-methyl-1,2-oxazol-3-yl)methyl]-N-(2-phenylsulfanylethyl)piperazin-4-ium-1-carbothioamide —— C18H25N4OS2+
    4-[(5-methyl-1,2-oxazol-3-yl)methyl]-N-(2-phenylsulfanylethyl)piperazin-4-ium-1-carbothioamide
    —— 4-(4-Bromophenyl)sulfanyl-3-nitrobenzenesulfonamide —— C12H9BrN2O4S2
    4-(4-Bromophenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 1-[2-(2-Fluorophenyl)ethyl]-3-(2-phenylsulfanylethyl)thiourea —— C17H19FN2S2
    1-[2-(2-Fluorophenyl)ethyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 2-(4-Bromophenyl)sulfanyl-5-piperidin-1-ylsulfonylpyridine —— C16H17BrN2O2S2
    2-(4-Bromophenyl)sulfanyl-5-piperidin-1-ylsulfonylpyridine
    —— N-methyl-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide —— C11H12N4O4S2
    N-methyl-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide
    —— N-tert-butyl-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide —— C14H18N4O4S2
    N-tert-butyl-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide
    —— N-(4-methylcyclohexyl)-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide —— C17H22N4O4S2
    N-(4-methylcyclohexyl)-4-(1-methylimidazol-2-yl)sulfanyl-3-nitrobenzenesulfonamide
    —— (3S,5S)-3,5-dimethyl-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]sulfonylpiperidine —— C17H22N4O4S2
    (3S,5S)-3,5-dimethyl-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]sulfonylpiperidine
    —— 4-[[(7R)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C18H24N7OS2+
    4-[[(7R)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 10-[(4-Methylpiperidin-1-yl)methyl]-12-(1-methyltetrazol-5-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C18H23N7S2
    10-[(4-Methylpiperidin-1-yl)methyl]-12-(1-methyltetrazol-5-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 12-(1-Methyltetrazol-5-yl)sulfanyl-10-(phenylsulfanylmethyl)-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C18H16N6S3
    12-(1-Methyltetrazol-5-yl)sulfanyl-10-(phenylsulfanylmethyl)-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— N-ethyl-6-(1-methyltetrazol-5-yl)sulfanyl-N-phenylpyridine-3-sulfonamide —— C15H16N6O2S2
    N-ethyl-6-(1-methyltetrazol-5-yl)sulfanyl-N-phenylpyridine-3-sulfonamide
    —— 4-[[12-(1-Methylimidazol-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium —— C18H22N5OS2+
    4-[[12-(1-Methylimidazol-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium
    —— 12-(1-Methylimidazol-2-yl)sulfanyl-10-[(4-methylpiperidin-1-yl)methyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C20H25N5S2
    12-(1-Methylimidazol-2-yl)sulfanyl-10-[(4-methylpiperidin-1-yl)methyl]-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 4-[[(7S)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C18H23N7OS2
    4-[[(7S)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— 4-[[5,6-Dimethyl-4-(1-methyltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C15H19N7OS2
    4-[[5,6-Dimethyl-4-(1-methyltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— 4-(1-methylimidazol-2-yl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide —— C13H16N4O4S2
    4-(1-methylimidazol-2-yl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide
    —— 4-(2-chlorophenyl)sulfanyl-N-methyl-3-nitrobenzenesulfonamide —— C13H11ClN2O4S2
    4-(2-chlorophenyl)sulfanyl-N-methyl-3-nitrobenzenesulfonamide
    —— 4-chloro-5-(4-chloro-benzylsulfanyl)-2-phenyl-2<i>H</i>-pyridazin-3-one 16461-50-0 C17H12Cl2N2OS
    4-chloro-5-(4-chloro-benzylsulfanyl)-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide —— C13H23N5OS
    (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide
    —— N,N-diethyl-3-nitro-4-phenylsulfanylbenzenesulfonamide —— C16H18N2O4S2
    N,N-diethyl-3-nitro-4-phenylsulfanylbenzenesulfonamide
    —— N-[2-(dimethylamino)ethyl]-3-nitro-4-phenylsulfanylbenzenesulfonamide —— C16H19N3O4S2
    N-[2-(dimethylamino)ethyl]-3-nitro-4-phenylsulfanylbenzenesulfonamide
    —— 2-Phenylsulfanyl-5-piperidin-1-ylsulfonylpyridine —— C16H18N2O2S2
    2-Phenylsulfanyl-5-piperidin-1-ylsulfonylpyridine
    —— 12-Phenylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C15H12N2S2
    12-Phenylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 1-Methyl-4-(3-nitro-4-phenylsulfanylphenyl)sulfonylpiperazine —— C17H19N3O4S2
    1-Methyl-4-(3-nitro-4-phenylsulfanylphenyl)sulfonylpiperazine