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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (CF3)2CHCSSC6H4Cl-p 33830-46-5 C10H5ClF6S2
    (CF3)2CHCSSC6H4Cl-p
    —— 3,6-Dimethyl-5-(propylthio)-1,3-oxazine-2,4(3H)-dione 135679-12-8 C9H13NO3S
    3,6-Dimethyl-5-(propylthio)-1,3-oxazine-2,4(3H)-dione
    —— (S)-N-t-Boc-2-amino-2-phenyl-1-thiophenylethane 171002-01-0 C19H23NO2S
    (S)-N-t-Boc-2-amino-2-phenyl-1-thiophenylethane
    —— (R)-N-(2-methyl-3-bromo-4-[4-carboxyphenylsulphanyl]phenyl)-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide 329926-95-6 C18H15BrF3NO4S
    (R)-N-(2-methyl-3-bromo-4-[4-carboxyphenylsulphanyl]phenyl)-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide
    —— 4-Methyl-2-methylsulfanyl-6-phenylamino-nicotinonitrile 51562-83-5 C14H13N3S
    4-Methyl-2-methylsulfanyl-6-phenylamino-nicotinonitrile
    —— 1-tert-butyl-3-(ethylthio)propyne 129578-04-7 C9H16S
    1-tert-butyl-3-(ethylthio)propyne
    —— N-hydroxy-N-[5-(iso-propylthio)thien-2-yl]methyl urea 132707-52-9 C9H14N2O2S2
    N-hydroxy-N-[5-(iso-propylthio)thien-2-yl]methyl urea
    —— 1-[(3-amino-isothiazolo[3,4-<i>d</i>]pyrimidin-6-ylsulfanyl)-acetyl]-piperidine 56584-44-2 C12H15N5OS2
    1-[(3-amino-isothiazolo[3,4-<i>d</i>]pyrimidin-6-ylsulfanyl)-acetyl]-piperidine
    —— Dithiocarbonic acid O-allyl ester S-p-tolyl ester 19711-03-6 C11H12OS2
    Dithiocarbonic acid O-allyl ester S-p-tolyl ester
    —— Bis(β-carbonylhydrazinoaethyl)sulfon 5034-72-0 C6H14N4O4S
    Bis(β-carbonylhydrazinoaethyl)sulfon
    —— 5-Aethylmercapto-2-<4-phenyl-thiosemicarbazono-methyl>-furan 106421-74-3 C14H15N3OS2
    5-Aethylmercapto-2-<4-phenyl-thiosemicarbazono-methyl>-furan
    —— 2-[(2-dimethylamino-6,7-dihydro-thieno[3,2-<i>d</i>]pyrimidin-4-yl)-methyl-amino]-ethanol 4856-62-6 C11H18N4OS
    2-[(2-dimethylamino-6,7-dihydro-thieno[3,2-<i>d</i>]pyrimidin-4-yl)-methyl-amino]-ethanol
    —— Tribromo-trichloromethanesulfonyl-methane 3739-27-3 C2Br3Cl3O2S
    Tribromo-trichloromethanesulfonyl-methane
    —— 6-Phenyl-2-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-3-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethylsulfanyl)-pyran-4-one 75782-02-4 C17H6F14O2S
    6-Phenyl-2-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-3-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethylsulfanyl)-pyran-4-one
    —— 1320208-96-5 C12H13N5S2
    —— 2-Amino-5-(3-trifluoromethyl-phenylsulfanyl)-benzonitrile 51124-17-5 C14H9F3N2S
    2-Amino-5-(3-trifluoromethyl-phenylsulfanyl)-benzonitrile
    —— O-ethyl [ethoxycarbothioylsulfanyl(diethyl)stannyl]sulfanylmethanethioate 149787-08-6 C10H20O2S4Sn
    O-ethyl [ethoxycarbothioylsulfanyl(diethyl)stannyl]sulfanylmethanethioate
    —— 2,13-dimethyl-6,9-dithia-2,13-distibatetradecane 2,13-disulfide 80238-48-8 C12H28S4Sb2
    2,13-dimethyl-6,9-dithia-2,13-distibatetradecane 2,13-disulfide
    —— (2S,4S)-4-Acetylsulfanyl-2-[1-(2-hydroxy-ethyl)-1H-tetrazol-5-ylsulfanylmethyl]-pyrrolidine-1-carboxylic acid allyl ester 288400-18-0 C14H21N5O4S2
    (2S,4S)-4-Acetylsulfanyl-2-[1-(2-hydroxy-ethyl)-1H-tetrazol-5-ylsulfanylmethyl]-pyrrolidine-1-carboxylic acid allyl ester
    —— 2-Methyl-3-phenylsulfanylmethyl-cyclopropane-1,1-dicarboxylic acid dimethyl ester 24212-88-2 C15H18O4S
    2-Methyl-3-phenylsulfanylmethyl-cyclopropane-1,1-dicarboxylic acid dimethyl ester
    —— 1-ethenyl-5-ethenylsulfanyl-3-methyl-1,2,4-triazole 108078-97-3 C7H9N3S
    1-ethenyl-5-ethenylsulfanyl-3-methyl-1,2,4-triazole
    —— 2-Vinylsulfonyl-acetylchlorid 20854-30-2 C4H5ClO3S
    2-Vinylsulfonyl-acetylchlorid
    —— 1-((p-tolylthio)ethynyl)pyrrolidine 80880-58-6 C13H15NS
    1-((p-tolylthio)ethynyl)pyrrolidine
    —— 2-Methylencyclohexylmethyl-p-tolyl-thioether 109449-69-6 C15H20S
    2-Methylencyclohexylmethyl-p-tolyl-thioether
    —— 1-Dimethylamino-4-methylpent-1-en-3-thion 56010-10-7 C8H15NS
    1-Dimethylamino-4-methylpent-1-en-3-thion
    —— S-Phenyl-trichlorthioacetimidat 46233-93-6 C8H6Cl3NS
    S-Phenyl-trichlorthioacetimidat
    —— 11-(11-Hydroxy-undecylsulfanylmethylsulfanylmethylsulfanyl)-undecan-1-ol 4167-62-8 C24H50O2S3
    11-(11-Hydroxy-undecylsulfanylmethylsulfanylmethylsulfanyl)-undecan-1-ol
    —— 2,3,4,5-Tetrafluoro-6-(2,3,5,6-tetrafluoro-phenylsulfanyl)-phenylamine 13645-77-7 C12H3F8NS
    2,3,4,5-Tetrafluoro-6-(2,3,5,6-tetrafluoro-phenylsulfanyl)-phenylamine
    —— 4-Methylmercapto-2-propyloxy-pyrimidin 13207-89-1 C8H12N2OS
    4-Methylmercapto-2-propyloxy-pyrimidin
    —— (5-chloro-2,4-dinitro-phenyl)-phenyl sulfide 14710-97-5 C12H7ClN2O4S
    (5-chloro-2,4-dinitro-phenyl)-phenyl sulfide
    —— bis-(2,2,2-trifluoro-1-propoxy-1-trifluoromethyl-ethyl)-disulfane 39237-78-0 C12H14F12O2S2
    bis-(2,2,2-trifluoro-1-propoxy-1-trifluoromethyl-ethyl)-disulfane
    —— (NZ)-N-(6-benzyl-2-phenylsulfanyl-2-propylcyclohexylidene)hydroxylamine 104260-97-1 C22H27NOS
    (NZ)-N-(6-benzyl-2-phenylsulfanyl-2-propylcyclohexylidene)hydroxylamine
    —— (4-(5-bromo-2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)phenyl)(4-methylpiperazin-1-yl)methanone 953043-93-1 C23H21BrN6OS2
    (4-(5-bromo-2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)phenyl)(4-methylpiperazin-1-yl)methanone
    —— ethyl 6-(2-(6-amino-8-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)ethoxy)hexanoate 1012059-44-7 C22H26BrN5O5S
    ethyl 6-(2-(6-amino-8-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)ethoxy)hexanoate
    —— 2-[(1-Cyclopropyl-1H-tetrazol-5-yl)thio]-4-pyridinecarboximidamide 1019547-46-6 C10H11N7S
    2-[(1-Cyclopropyl-1H-tetrazol-5-yl)thio]-4-pyridinecarboximidamide
    —— 2-[2-(2-fluorophenyl)sulfanylphenyl]acetic acid 73129-25-6 C14H11FO2S
    2-[2-(2-fluorophenyl)sulfanylphenyl]acetic acid
    —— (R)-N-{2,3-difluoro-4-[4-(N,N-dimethylcarbamoyl)phenylsulphanyl]phenyl}-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide 329926-56-9 C19H17F5N2O3S
    (R)-N-{2,3-difluoro-4-[4-(N,N-dimethylcarbamoyl)phenylsulphanyl]phenyl}-2-hydroxy-2-methyl-3,3,3-trifluoropropanamide
    —— 5-(2-amino-7(9)<i>H</i>-purin-6-ylsulfanyl)-1-methyl-4-nitro-1<i>H</i>-imidazole-2-carboxylic acid 94045-80-4 C10H8N8O4S
    5-(2-amino-7(9)<i>H</i>-purin-6-ylsulfanyl)-1-methyl-4-nitro-1<i>H</i>-imidazole-2-carboxylic acid
    —— 4-[(3-Aminophenyl)thio]-N-methyl-2-pyridinecarboxamide 284462-88-0 C13H13N3OS
    4-[(3-Aminophenyl)thio]-N-methyl-2-pyridinecarboxamide
    —— 6-Ethoxy-1,3-dimethyl-1H,8H-pyrimido[5,4-b][1,4]thiazine-2,4,7-trione 94216-17-8 C10H13N3O4S
    6-Ethoxy-1,3-dimethyl-1H,8H-pyrimido[5,4-b][1,4]thiazine-2,4,7-trione
    —— 2-(propoxymethylthio)pyridine 77555-24-9 C9H13NOS
    2-(propoxymethylthio)pyridine
    —— [(2R,3S,5R)-3-acetyloxy-5-(4-methylsulfanyl-2-oxo-5-undec-1-ynylpyrimidin-1-yl)oxolan-2-yl]methyl acetate 384338-52-7 C25H36N2O6S
    [(2R,3S,5R)-3-acetyloxy-5-(4-methylsulfanyl-2-oxo-5-undec-1-ynylpyrimidin-1-yl)oxolan-2-yl]methyl acetate
    —— 1,1-bis-methylsulfanyl-heptane 15486-59-6 C9H20S2
    1,1-bis-methylsulfanyl-heptane
    —— 4-phenylthio 2,7,9-trimethyl pyrido<3',2':4,5>thieno<3,2-d>pyrimidine 128257-01-2 C18H15N3S2
    4-phenylthio 2,7,9-trimethyl pyrido<3',2':4,5>thieno<3,2-d>pyrimidine
    —— S-5-Hexenyl-O-methyl xanthate 129055-92-1 C8H14OS2
    S-5-Hexenyl-O-methyl xanthate
    —— 5-butyl-2-dimethylamino-4-methyl-6-propoxycarbonylsulfanyl-pyrimidine 22589-65-7 C15H25N3O2S
    5-butyl-2-dimethylamino-4-methyl-6-propoxycarbonylsulfanyl-pyrimidine
    —— isopropyl-thiophosphoramidic acid <i>O</i>-[1-(2-cyano-ethyl)-5-methylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl] ester <i>O</i>'-ethyl ester 58277-88-6 C11H20N5O2PS2
    isopropyl-thiophosphoramidic acid <i>O</i>-[1-(2-cyano-ethyl)-5-methylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl] ester <i>O</i>'-ethyl ester
    —— (1R,2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-1-methoxy-1-phenylsulfanyl-butan-2-ol 134678-21-0 C17H30O3SSi
    (1R,2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-1-methoxy-1-phenylsulfanyl-butan-2-ol
    —— (4-ethylamino-phenyl)-(4-amino-phenyl)-sulfide 101939-45-1 C14H16N2S
    (4-ethylamino-phenyl)-(4-amino-phenyl)-sulfide
    —— Trimethyl-methylmercapto-phosphoniumjodid 35449-66-2 C4H12PS*I
    Trimethyl-methylmercapto-phosphoniumjodid