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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[1-(2-chloroanilino)ethylidene]-1-benzothiophen-3-one —— C16H12ClNOS
    2-[1-(2-chloroanilino)ethylidene]-1-benzothiophen-3-one
    —— 2-[1-(3-chloroanilino)ethylidene]-1-benzothiophen-3-one —— C16H12ClNOS
    2-[1-(3-chloroanilino)ethylidene]-1-benzothiophen-3-one
    —— 2-[1-(4-bromoanilino)ethylidene]-1-benzothiophen-3-one —— C16H12BrNOS
    2-[1-(4-bromoanilino)ethylidene]-1-benzothiophen-3-one
    —— 2,5-dibromo-N-[1-[[2-(4-chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]benzenesulfonamide —— C23H21Br2ClN2O2S2
    2,5-dibromo-N-[1-[[2-(4-chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]benzenesulfonamide
    —— 1-(1-Benzofuran-2-ylmethyl)-3-[1-[[2-(4-chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]-1-(furan-2-ylmethyl)urea —— C32H30ClN3O3S
    1-(1-Benzofuran-2-ylmethyl)-3-[1-[[2-(4-chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]-1-(furan-2-ylmethyl)urea
    —— 3-[1-[[2-(4-Chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]-1-[(4-ethoxy-3-methoxyphenyl)methyl]-1-(furan-2-ylmethyl)urea —— C33H36ClN3O4S
    3-[1-[[2-(4-Chlorophenyl)sulfanylphenyl]methyl]pyrrolidin-3-yl]-1-[(4-ethoxy-3-methoxyphenyl)methyl]-1-(furan-2-ylmethyl)urea
    —— 2-(2,4,6-trimethylphenyl)ethyl N-[2-[3,5-bis(methylsulfanyl)-1,2,4-triazol-4-yl]ethyl]carbamate —— C18H26N4O2S2
    2-(2,4,6-trimethylphenyl)ethyl N-[2-[3,5-bis(methylsulfanyl)-1,2,4-triazol-4-yl]ethyl]carbamate
    —— [(1'R,2'S,5'S)-7'-oxospiro[1,3-dithiane-2,4'-bicyclo[3.2.1]octane]-2'-yl] methanesulfonate —— C12H18O4S3
    [(1'R,2'S,5'S)-7'-oxospiro[1,3-dithiane-2,4'-bicyclo[3.2.1]octane]-2'-yl] methanesulfonate
    —— (1S,5R,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7lambda6-thiabicyclo[4.2.0]oct-3-en-5-amine —— C11H19NO2S
    (1S,5R,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7lambda6-thiabicyclo[4.2.0]oct-3-en-5-amine
    —— (1R,5S,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7λ6-thiabicyclo[4.2.0]oct-3-en-5-amine —— C11H19NO2S
    (1R,5S,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7λ6-thiabicyclo[4.2.0]oct-3-en-5-amine
    —— (1R,5R,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7lambda6-thiabicyclo[4.2.0]oct-3-en-5-amine —— C11H19NO2S
    (1R,5R,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7lambda6-thiabicyclo[4.2.0]oct-3-en-5-amine
    —— (1S,5S,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7λ6-thiabicyclo[4.2.0]oct-3-en-5-amine —— C11H19NO2S
    (1S,5S,6S)-N,N,8,8-tetramethyl-7,7-dioxo-7λ6-thiabicyclo[4.2.0]oct-3-en-5-amine
    —— [(1'R,2'S,5'R)-7'-oxospiro[1,3-dithiane-2,4'-bicyclo[3.2.1]octane]-2'-yl] methanesulfonate —— C12H18O4S3
    [(1'R,2'S,5'R)-7'-oxospiro[1,3-dithiane-2,4'-bicyclo[3.2.1]octane]-2'-yl] methanesulfonate
    —— 2-(4-bromophenyl)sulfanyl-5-morpholin-4-ylsulfonyl-N-[[(2R)-oxolan-2-yl]methyl]benzamide —— C22H25BrN2O5S2
    2-(4-bromophenyl)sulfanyl-5-morpholin-4-ylsulfonyl-N-[[(2R)-oxolan-2-yl]methyl]benzamide
    —— 2-(4-bromophenyl)sulfanyl-5-morpholin-4-ylsulfonyl-N-[[(2S)-oxolan-2-yl]methyl]benzamide —— C22H25BrN2O5S2
    2-(4-bromophenyl)sulfanyl-5-morpholin-4-ylsulfonyl-N-[[(2S)-oxolan-2-yl]methyl]benzamide
    —— (2S,3S,6R)-N,N,2-trimethyl-6-pyrimidin-2-ylsulfanyloxan-3-amine —— C12H19N3OS
    (2S,3S,6R)-N,N,2-trimethyl-6-pyrimidin-2-ylsulfanyloxan-3-amine
    —— O-[(1R,2R,4R)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate —— C12H18O2S2
    O-[(1R,2R,4R)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate
    —— O-[(1R,2R,4S)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate —— C12H18O2S2
    O-[(1R,2R,4S)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate
    —— (1'S,2'R,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'R,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— (1'S,2'R,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'R,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— O-[(1S,7S)-4-tricyclo[5.3.1.02,6]undec-2(6)-enyl] methylsulfanylmethanethioate —— C13H18OS2
    O-[(1S,7S)-4-tricyclo[5.3.1.02,6]undec-2(6)-enyl] methylsulfanylmethanethioate
    —— 3-hydroxy-2-[(1R)-1-phenylsulfanylethyl]cyclohex-2-en-1-one —— C14H16O2S
    3-hydroxy-2-[(1R)-1-phenylsulfanylethyl]cyclohex-2-en-1-one
    —— O-[(1R,7R)-4-tricyclo[5.3.1.02,6]undec-2(6)-enyl] methylsulfanylmethanethioate —— C13H18OS2
    O-[(1R,7R)-4-tricyclo[5.3.1.02,6]undec-2(6)-enyl] methylsulfanylmethanethioate
    —— 3-hydroxy-2-[(1S)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1S)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one
    —— (1R,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1R,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— 3-hydroxy-2-[(1S)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1S)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one
    —— (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— (1S,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1S,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]non-6-ene]-2'-one —— C11H14OS2
    (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]non-6-ene]-2'-one
    —— (1S,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1S,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— (1R,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1R,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— 3-hydroxy-2-[(1R)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1R)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one
    —— 3-hydroxy-2-[(1R)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1R)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one
    —— 3-hydroxy-2-[(1S)-1-phenylsulfanylethyl]cyclohex-2-en-1-one —— C14H16O2S
    3-hydroxy-2-[(1S)-1-phenylsulfanylethyl]cyclohex-2-en-1-one
    —— (NE)-N-[(1S,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine —— C12H13F2N3O3S
    (NE)-N-[(1S,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine
    —— (2R)-N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C17H26N4OS
    (2R)-N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— (2R)-N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C17H26N4OS
    (2R)-N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— (3'aR)-spiro[1,3-dithiane-2,4'-2,3,3a,5-tetrahydropentalene]-1'-one —— C11H14OS2
    (3'aR)-spiro[1,3-dithiane-2,4'-2,3,3a,5-tetrahydropentalene]-1'-one
    —— (1'R,5'S)-spiro[1,3-dithiane-2,2'-bicyclo[3.2.1]oct-3-ene]-6'-one —— C11H14OS2
    (1'R,5'S)-spiro[1,3-dithiane-2,2'-bicyclo[3.2.1]oct-3-ene]-6'-one
    —— (1R,4R,6R,9R)-5,12-bis(2-phenylsulfanylethyl)tetracyclo[7.2.1.04,11.06,10]dodeca-2,7-diene —— C28H30S2
    (1R,4R,6R,9R)-5,12-bis(2-phenylsulfanylethyl)tetracyclo[7.2.1.04,11.06,10]dodeca-2,7-diene
    —— (1E)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine —— C12H21NO4S2
    (1E)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine
    —— (1R,6R)-8-methylsulfanyl-7-azabicyclo[4.2.2]deca-2,4,7,9-tetraene —— C10H11NS
    (1R,6R)-8-methylsulfanyl-7-azabicyclo[4.2.2]deca-2,4,7,9-tetraene
    —— (1E,3Z)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine —— C12H21NO4S2
    (1E,3Z)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine
    —— methyl (1R,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1R,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— methyl (1S,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1S,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— methyl (1R,3S,6R)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1R,3S,6R)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— [2-oxo-2-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C26H28N2O3S
    [2-oxo-2-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— (1R,5R)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene —— C15H24S
    (1R,5R)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene
    —— (1S,5S)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene —— C15H24S
    (1S,5S)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene