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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (3S)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate —— C21H18FNO5S
    methyl (3S)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate
    —— (4S)-4-(4-methylsulfanylphenyl)-1-(thiophen-2-ylmethyl)-2,4-dihydropyrazolo[3,4-e][1,4]thiazepin-7-one —— C18H17N3OS3
    (4S)-4-(4-methylsulfanylphenyl)-1-(thiophen-2-ylmethyl)-2,4-dihydropyrazolo[3,4-e][1,4]thiazepin-7-one
    —— methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-phenylpropanoate —— C22H20O5S
    methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-phenylpropanoate
    —— (4R)-4-(4-methylsulfanylphenyl)-1-(thiophen-2-ylmethyl)-2,4-dihydropyrazolo[3,4-e][1,4]thiazepin-7-one —— C18H17N3OS3
    (4R)-4-(4-methylsulfanylphenyl)-1-(thiophen-2-ylmethyl)-2,4-dihydropyrazolo[3,4-e][1,4]thiazepin-7-one
    —— 5-[(2,5-dimethylphenyl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine —— C18H19N3S2
    5-[(2,5-dimethylphenyl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— methyl (3S)-3-[6-[(2-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate —— C21H18FNO5S
    methyl (3S)-3-[6-[(2-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate
    —— methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-thiophen-2-ylpropanoate —— C20H18O5S2
    methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-thiophen-2-ylpropanoate
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C19H26N4OS2
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)propanamide —— C18H20N4O2S2
    (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)propanamide
    —— N-(2-methylphenyl)-5-(3-phenylpropylsulfanyl)-1,3,4-thiadiazol-2-amine —— C18H19N3S2
    N-(2-methylphenyl)-5-(3-phenylpropylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— methyl (3R)-3-[6-[(2-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate —— C21H18FNO5S
    methyl (3R)-3-[6-[(2-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-pyridin-3-ylpropanoate
    —— methyl (3S)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-thiophen-2-ylpropanoate —— C20H18O5S2
    methyl (3S)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-3-thiophen-2-ylpropanoate
    —— methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-4-methylpentanoate —— C19H22O5S
    methyl (3R)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-4-methylpentanoate
    —— methyl (3S)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-4-methylpentanoate —— C19H22O5S
    methyl (3S)-3-[3-hydroxy-4-oxo-6-(phenylsulfanylmethyl)pyran-2-yl]-4-methylpentanoate
    —— methyl (3S)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(furan-2-yl)propanoate —— C20H17FO6S
    methyl (3S)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(furan-2-yl)propanoate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2-(4-chlorophenyl)acetate —— C22H18ClNO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2-(4-chlorophenyl)acetate
    —— methyl (3R)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(furan-2-yl)propanoate —— C20H17FO6S
    methyl (3R)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(furan-2-yl)propanoate
    —— 3-(2-morpholin-4-yl-2-oxoethyl)-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C21H25N3O3S
    3-(2-morpholin-4-yl-2-oxoethyl)-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— 2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)-N-(furan-2-ylmethyl)acetamide —— C19H19N3O3S
    2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)-N-(furan-2-ylmethyl)acetamide
    —— 2-[2-[(2-chlorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetamide —— C16H16ClN3O2S
    2-[2-[(2-chlorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetamide
    —— 3-Benzyl-2-benzylsulfanyl-6-methylpyrimidin-4-one —— C19H18N2OS
    3-Benzyl-2-benzylsulfanyl-6-methylpyrimidin-4-one
    —— 3-Butyl-5-[(4-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C13H17FN4S
    3-Butyl-5-[(4-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 3-[(4-Chlorophenyl)methyl]-6-methyl-2-methylsulfanylpyrimidin-4-one —— C13H13ClN2OS
    3-[(4-Chlorophenyl)methyl]-6-methyl-2-methylsulfanylpyrimidin-4-one
    —— N-benzyl-2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)acetamide —— C21H21N3O2S
    N-benzyl-2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)acetamide
    —— 2-Benzylsulfanyl-6-methyl-3-(2-morpholin-4-yl-2-oxoethyl)pyrimidin-4-one —— C18H21N3O3S
    2-Benzylsulfanyl-6-methyl-3-(2-morpholin-4-yl-2-oxoethyl)pyrimidin-4-one
    —— 2-(2-methylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)-N-[(1S)-1-phenylethyl]acetamide —— C18H21N3O2S
    2-(2-methylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)-N-[(1S)-1-phenylethyl]acetamide
    —— 2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)-N-[(1R)-1-phenylethyl]acetamide —— C24H25N3O2S
    2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)-N-[(1R)-1-phenylethyl]acetamide
    —— 3-Butyl-5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C13H16ClFN4S
    3-Butyl-5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 3-[(4-chlorophenyl)methyl]-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C22H21ClN2OS
    3-[(4-chlorophenyl)methyl]-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— 2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetamide —— C16H17N3O2S
    2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetamide
    —— 3-benzyl-2-benzylsulfanyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C21H20N2OS
    3-benzyl-2-benzylsulfanyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— N-(2-methylpropyl)-2-(2-methylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetamide —— C14H21N3O2S
    N-(2-methylpropyl)-2-(2-methylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetamide
    —— 2-benzylsulfanyl-3-[(3-chlorophenyl)methyl]-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C21H19ClN2OS
    2-benzylsulfanyl-3-[(3-chlorophenyl)methyl]-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— 2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)-N-(2-methylpropyl)acetamide —— C18H23N3O2S
    2-(2-benzylsulfanyl-4-methyl-6-oxopyrimidin-1-yl)-N-(2-methylpropyl)acetamide
    —— 2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C20H19N3O2S2
    2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— 2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)-N-[(1S)-1-phenylethyl]acetamide —— C16H19N3O2S
    2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)-N-[(1S)-1-phenylethyl]acetamide
    —— 2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetonitrile —— C16H15N3OS
    2-(2-benzylsulfanyl-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl)acetonitrile
    —— N,N-dibenzyl-2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide —— C22H23N3O2S
    N,N-dibenzyl-2-(4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide
    —— 2-Benzylsulfanyl-3-[(2-chloro-6-fluorophenyl)methyl]-6-methylpyrimidin-4-one —— C19H16ClFN2OS
    2-Benzylsulfanyl-3-[(2-chloro-6-fluorophenyl)methyl]-6-methylpyrimidin-4-one
    —— 2-benzylsulfanyl-3-ethyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C16H18N2OS
    2-benzylsulfanyl-3-ethyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— 2-Benzylsulfanyl-3-[(4-chlorophenyl)methyl]-6-methylpyrimidin-4-one —— C19H17ClN2OS
    2-Benzylsulfanyl-3-[(4-chlorophenyl)methyl]-6-methylpyrimidin-4-one
    —— 3-[(2-Fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C9H9FN4S
    3-[(2-Fluorophenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— 2-methylsulfanyl-3-(2-morpholin-4-yl-2-oxoethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C14H19N3O3S
    2-methylsulfanyl-3-(2-morpholin-4-yl-2-oxoethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— 2-[2-[(2-chlorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetonitrile —— C16H14ClN3OS
    2-[2-[(2-chlorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetonitrile
    —— N-(furan-2-ylmethyl)-2-[4-oxo-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetamide —— C22H23N3O3S
    N-(furan-2-ylmethyl)-2-[4-oxo-2-(2-phenylethylsulfanyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-3-yl]acetamide
    —— 2-Benzylsulfanyl-6-methyl-3-[(4-methylphenyl)methyl]pyrimidin-4-one —— C20H20N2OS
    2-Benzylsulfanyl-6-methyl-3-[(4-methylphenyl)methyl]pyrimidin-4-one
    —— 3-[(2-chloro-6-fluorophenyl)methyl]-2-methylsulfanyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one —— C15H14ClFN2OS
    3-[(2-chloro-6-fluorophenyl)methyl]-2-methylsulfanyl-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-one
    —— [2-(2,5-dimethylphenyl)sulfanylpyridin-3-yl]-[(2S)-2-(5-methyl-1,2,4-oxadiazol-3-yl)morpholin-4-yl]methanone —— C21H22N4O3S
    [2-(2,5-dimethylphenyl)sulfanylpyridin-3-yl]-[(2S)-2-(5-methyl-1,2,4-oxadiazol-3-yl)morpholin-4-yl]methanone
    —— [2-(2,5-dimethylphenyl)sulfanylpyridin-3-yl]-[(2R)-2-(5-methyl-1,2,4-oxadiazol-3-yl)morpholin-4-yl]methanone —— C21H22N4O3S
    [2-(2,5-dimethylphenyl)sulfanylpyridin-3-yl]-[(2R)-2-(5-methyl-1,2,4-oxadiazol-3-yl)morpholin-4-yl]methanone
    —— 2-[[2-[(4-Amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]amino]ethyl-diethylazanium —— C12H25N6OS+
    2-[[2-[(4-Amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]amino]ethyl-diethylazanium