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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-methyl-N-[(1S,2R)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H23N3O2S
    N-methyl-N-[(1S,2R)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-methyl-N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H23N3O2S
    N-methyl-N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C20H20ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C18H22ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C18H22ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— N-methyl-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H23N3O2S
    N-methyl-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C18H22ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 2-[4-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N-methylanilino]ethanol —— C19H20ClN5OS
    2-[4-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N-methylanilino]ethanol
    —— (1R)-N-[(2-tert-butylsulfanylpyridin-4-yl)methyl]-1-(1-methylpyrazol-4-yl)ethanamine —— C16H24N4S
    (1R)-N-[(2-tert-butylsulfanylpyridin-4-yl)methyl]-1-(1-methylpyrazol-4-yl)ethanamine
    —— (1S)-N-[(2-tert-butylsulfanylpyridin-4-yl)methyl]-1-(1-methylpyrazol-4-yl)ethanamine —— C16H24N4S
    (1S)-N-[(2-tert-butylsulfanylpyridin-4-yl)methyl]-1-(1-methylpyrazol-4-yl)ethanamine
    —— (2S)-3-(4-fluorophenyl)sulfanyl-N-(1-hydroxy-2-methylpropan-2-yl)-2-methylpropanamide —— C14H20FNO2S
    (2S)-3-(4-fluorophenyl)sulfanyl-N-(1-hydroxy-2-methylpropan-2-yl)-2-methylpropanamide
    —— (2R)-3-(4-fluorophenyl)sulfanyl-N-(1-hydroxy-2-methylpropan-2-yl)-2-methylpropanamide —— C14H20FNO2S
    (2R)-3-(4-fluorophenyl)sulfanyl-N-(1-hydroxy-2-methylpropan-2-yl)-2-methylpropanamide
    —— 5-({2,4-Bisnitrophenyl}sulfanyl)-2-furaldehyde dimethylhydrazone —— C13H12N4O5S
    5-({2,4-Bisnitrophenyl}sulfanyl)-2-furaldehyde dimethylhydrazone
    —— N'-[2-(phenylsulfanyl)benzylidene]-2-(4-propylphenoxy)acetohydrazide —— C24H24N2O2S
    N'-[2-(phenylsulfanyl)benzylidene]-2-(4-propylphenoxy)acetohydrazide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide —— C15H14FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide
    —— 1-ethyl-2-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanylimidazole —— C8H11F3N2S
    1-ethyl-2-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanylimidazole
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide —— C13H11FN2OS2
    2-(2-fluorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide
    —— 2-(3,5-dimethylpyrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C15H18N4OS
    2-(3,5-dimethylpyrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 1-ethyl-2-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanylimidazole —— C8H11F3N2S
    1-ethyl-2-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanylimidazole
    —— 4-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-1-propan-2-ylpiperidin-4-ol —— C18H28F2N2OS
    4-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-1-propan-2-ylpiperidin-4-ol
    —— 4-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-1-propan-2-ylpiperidin-4-ol —— C18H28F2N2OS
    4-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-1-propan-2-ylpiperidin-4-ol
    —— N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)propyl]-3-pyridin-2-ylsulfanylpropanamide —— C14H19N5OS
    N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)propyl]-3-pyridin-2-ylsulfanylpropanamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(oxolan-2-ylmethyl)acetamide —— C15H18N4O2S2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(oxolan-2-ylmethyl)acetamide
    —— (2S)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-(2H-triazol-4-ylsulfanyl)butanenitrile —— C15H11N5OS2
    (2S)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-(2H-triazol-4-ylsulfanyl)butanenitrile
    —— (2R)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-(2H-triazol-4-ylsulfanyl)butanenitrile —— C15H11N5OS2
    (2R)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-(2H-triazol-4-ylsulfanyl)butanenitrile
    —— N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]-3-phenylsulfanylpropanamide —— C17H25NOS
    N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]-3-phenylsulfanylpropanamide
    —— N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]-3-phenylsulfanylpropanamide —— C17H25NOS
    N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]-3-phenylsulfanylpropanamide
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide —— C16H19NOS2
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide
    —— N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-thiophen-2-ylsulfanylacetamide —— C18H21NOS2
    N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-thiophen-2-ylsulfanylacetamide
    —— N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-thiophen-2-ylsulfanylacetamide —— C18H21NOS2
    N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-thiophen-2-ylsulfanylacetamide
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide —— C16H19NOS2
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide
    —— 2-[(E)-(4-methylsulfanylphenyl)methylideneamino]guanidine —— C9H12N4S
    2-[(E)-(4-methylsulfanylphenyl)methylideneamino]guanidine
    —— N-[(E)-benzylideneamino]-2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]acetamide —— C14H15N5O3S
    N-[(E)-benzylideneamino]-2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]acetamide
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-2-ethylbutylideneamino]thiourea —— C14H19F2N3S2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-2-ethylbutylideneamino]thiourea
    —— N-[(3-chlorophenyl)methyl]-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H15ClN6O2S
    N-[(3-chlorophenyl)methyl]-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C11H11BrN6OS
    2-[[5-[(2E)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-ethyl-2-phenylsulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C13H16F3NOS
    (2R)-N-ethyl-2-phenylsulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide —— C14H14ClNOS2
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide
    —— (2S)-N-ethyl-2-phenylsulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C13H16F3NOS
    (2S)-N-ethyl-2-phenylsulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide —— C14H14ClNOS2
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-thiophen-2-ylsulfanylacetamide
    —— N-[(2S)-1-hydroxypropan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C11H13F3N2O2S
    N-[(2S)-1-hydroxypropan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(2R)-2-hydroxypropyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C11H13F3N2O2S
    N-[(2R)-2-hydroxypropyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide —— C13H18N4O2S2
    2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide —— C13H14ClN3O3S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-1-hydroxypropan-2-yl]acetamide —— C18H20N4O3S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-1-hydroxypropan-2-yl]acetamide
    —— N-[(2S)-2-hydroxypropyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C11H13F3N2O2S
    N-[(2S)-2-hydroxypropyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide —— C18H20N4O3S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-hydroxypropan-2-yl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-hydroxypropan-2-yl]acetamide —— C13H14ClN3O3S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-1-hydroxypropan-2-yl]acetamide
    —— 1-(3,5-dimethylpyrazol-1-yl)-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C14H15N7O2S
    1-(3,5-dimethylpyrazol-1-yl)-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— N-[(E)-benzylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C19H21N5S
    N-[(E)-benzylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine