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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C19H22ClNOS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide —— C19H22ClNOS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(furan-2-ylmethyl)propanamide —— C14H14ClNO2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(furan-2-ylmethyl)propanamide
    —— methyl 5-[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C17H18ClNO3S
    methyl 5-[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— (2R)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H22N4OS2
    (2R)-N-benzyl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 5-(cyclohexylmethylsulfanyl)-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H23N3S2
    5-(cyclohexylmethylsulfanyl)-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 5-[(3,5-dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine —— C16H18N4OS2
    5-[(3,5-dimethyl-1,2-oxazol-4-yl)methylsulfanyl]-N-(4-ethylphenyl)-1,3,4-thiadiazol-2-amine
    —— N,N-bis(2-cyanoethyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H20N6OS2
    N,N-bis(2-cyanoethyl)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2-fluorophenoxy)acetamide —— C20H15ClFNO2S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(2-fluorophenoxy)acetamide
    —— 4-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidine —— C19H21NOS
    4-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidine
    —— Propan-2-yl 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C15H19N3O2S2
    Propan-2-yl 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— N-(4-ethylphenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H16FN3S2
    N-(4-ethylphenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(5-nitro-2-oxopyridin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C19H15N3O4S
    2-(5-nitro-2-oxopyridin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— 4-[(6R)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidine —— C19H21NOS
    4-[(6R)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidine
    —— (3S)-3-(4-chlorophenyl)sulfanyloxolane-2,5-dione —— C10H7ClO3S
    (3S)-3-(4-chlorophenyl)sulfanyloxolane-2,5-dione
    —— [2-Oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H23NO3S
    [2-Oxo-2-(1,2,5-trimethylpyrrol-3-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(Cycloheptylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H27NO3S
    [2-(Cycloheptylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(3-Methylbutylamino)-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C17H24BrNO3S
    [2-(3-Methylbutylamino)-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C16H19BrN2O3S
    [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[(4-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C18H24BrNO3S
    [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H22N2O2S2
    [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 2-(2,5-dimethylphenyl)sulfanylacetate
    —— N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H24N4O3S
    N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(1-adamantyl)-2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H29N4O2S+
    N-(1-adamantyl)-2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— [2-[[(1S)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C24H33NO3S
    [2-[[(1S)-1-(1-adamantyl)ethyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— 1-Morpholin-4-yl-2-[5-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]thiophen-2-yl]ethanone —— C14H15N3O3S3
    1-Morpholin-4-yl-2-[5-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]thiophen-2-yl]ethanone
    —— 2-[5-[2-(3,4-Dimethylphenyl)sulfanylacetyl]thiophen-2-yl]-1-morpholin-4-ylethanone —— C20H23NO3S2
    2-[5-[2-(3,4-Dimethylphenyl)sulfanylacetyl]thiophen-2-yl]-1-morpholin-4-ylethanone
    —— N-(2-benzylsulfanylethyl)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H20N4O2S2
    N-(2-benzylsulfanylethyl)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-methyl-2-[(Z)-3,3,3-trifluoroprop-1-enyl]sulfanylbenzene —— C10H9F3S
    1-methyl-2-[(Z)-3,3,3-trifluoroprop-1-enyl]sulfanylbenzene
    —— (3aR)-5-(trifluoromethyl)-3aH-thieno[2,3-b]pyrrole-4-carboxylic acid —— C8H4F3NO2S
    (3aR)-5-(trifluoromethyl)-3aH-thieno[2,3-b]pyrrole-4-carboxylic acid
    —— 2-[[5-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H14N4OS4
    2-[[5-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[2-[Benzyl(methyl)amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H16N4O2S3
    2-[[5-[2-[Benzyl(methyl)amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[2-[(4-Fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H13FN4O2S3
    2-[[5-[2-[(4-Fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C15H17FN4O2S3
    (2S)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-[[5-[2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H20N4O2S3
    2-[[5-[2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H20N4O2S3
    2-[[5-[2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-benzyl-2-[[5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H22N4O2S3
    N-benzyl-2-[[5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-ethanimidoyl-4-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-3-oxobutanenitrile —— C16H17N5O2S
    (2R)-2-ethanimidoyl-4-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-3-oxobutanenitrile
    —— 2-[(4-amino-5-benzylsulfanyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-diethylacetamide —— C15H21N5OS2
    2-[(4-amino-5-benzylsulfanyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-diethylacetamide
    —— 2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C13H24N6O2S2
    2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— N-[(4-chlorophenyl)methyl]-N-methyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C17H15ClN4O2S
    N-[(4-chlorophenyl)methyl]-N-methyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2R)-4-phenylbutan-2-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H20N4O2S
    N-[(2R)-4-phenylbutan-2-yl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H20N4O2S
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2R)-2-phenylpropyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H18N4O2S
    N-[(2R)-2-phenylpropyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C18H17FN4O2S
    (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 2-[[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole —— C17H11ClN4OS2
    2-[[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C17H22N4O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— [2-(Cyclopropylamino)-2-oxoethyl] 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C15H14ClN3O4S
    [2-(Cyclopropylamino)-2-oxoethyl] 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— Cyanomethyl 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C12H8ClN3O3S
    Cyanomethyl 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— N-cyclopropyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C12H12N4O2S
    N-cyclopropyl-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide