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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(3R)-5-(2-oxopropyl)-2,3-dihydro-1-benzothiophen-3-yl]acetic acid —— C13H14O3S
    2-[(3R)-5-(2-oxopropyl)-2,3-dihydro-1-benzothiophen-3-yl]acetic acid
    —— (3S)-3-methyl-4-(3-oxo-1-benzothiophen-5-yl)butanoic acid —— C13H14O3S
    (3S)-3-methyl-4-(3-oxo-1-benzothiophen-5-yl)butanoic acid
    —— (3S)-3-(2-oxo-3H-1-benzothiophen-5-yl)pentanoic acid —— C13H14O3S
    (3S)-3-(2-oxo-3H-1-benzothiophen-5-yl)pentanoic acid
    —— 2-[(3R)-5-propanoyl-2,3-dihydro-1-benzothiophen-3-yl]acetic acid —— C13H14O3S
    2-[(3R)-5-propanoyl-2,3-dihydro-1-benzothiophen-3-yl]acetic acid
    —— (3R)-3-(2-oxo-3H-1-benzothiophen-5-yl)pentanoic acid —— C13H14O3S
    (3R)-3-(2-oxo-3H-1-benzothiophen-5-yl)pentanoic acid
    —— (3R)-3-methyl-4-(3-oxo-1-benzothiophen-5-yl)butanoic acid —— C13H14O3S
    (3R)-3-methyl-4-(3-oxo-1-benzothiophen-5-yl)butanoic acid
    —— (3R)-3-(3-oxo-1-benzothiophen-5-yl)pentanoic acid —— C13H14O3S
    (3R)-3-(3-oxo-1-benzothiophen-5-yl)pentanoic acid
    —— (3S)-3-(3-oxo-1-benzothiophen-5-yl)pentanoic acid —— C13H14O3S
    (3S)-3-(3-oxo-1-benzothiophen-5-yl)pentanoic acid
    —— 2-[(3S)-5-(2-oxopropyl)-2,3-dihydro-1-benzothiophen-3-yl]acetic acid —— C13H14O3S
    2-[(3S)-5-(2-oxopropyl)-2,3-dihydro-1-benzothiophen-3-yl]acetic acid
    —— 2-[(3S)-5-propanoyl-2,3-dihydro-1-benzothiophen-3-yl]acetic acid —— C13H14O3S
    2-[(3S)-5-propanoyl-2,3-dihydro-1-benzothiophen-3-yl]acetic acid
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide —— C14H14ClNOS2
    (2S)-2-(2-chlorophenyl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C14H18ClNO3S2
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C14H18ClNO3S2
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— 6-Amino-1-cyclopropyl-5-[2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrimidine-2,4-dione —— C13H16N6O3S
    6-Amino-1-cyclopropyl-5-[2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrimidine-2,4-dione
    —— 1-[(3R)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-2-one —— C14H17NOS
    1-[(3R)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-2-one
    —— 5-[[(3R)-3-methylpyrrolidin-3-yl]methyl]-1-benzothiophen-3-one —— C14H17NOS
    5-[[(3R)-3-methylpyrrolidin-3-yl]methyl]-1-benzothiophen-3-one
    —— 1-[(3R)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-1-one —— C14H17NOS
    1-[(3R)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-1-one
    —— 1-[(3S)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-1-one —— C14H17NOS
    1-[(3S)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-1-one
    —— 2-(1-benzyltetrazol-5-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylacetamide —— C17H23N5O3S2
    2-(1-benzyltetrazol-5-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylacetamide
    —— 1-[(3S)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-2-one —— C14H17NOS
    1-[(3S)-spiro[2H-1-benzothiophene-3,3'-pyrrolidine]-5-yl]propan-2-one
    —— 2-(5-Methyl-3-phenyl-1,2-oxazol-4-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C16H14N6O2S
    2-(5-Methyl-3-phenyl-1,2-oxazol-4-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 2-(5-Methyl-3-phenyl-1,2-oxazol-4-yl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C19H18N6O2S
    2-(5-Methyl-3-phenyl-1,2-oxazol-4-yl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 2-methyl-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-5-phenylthieno[2,3-d]pyrimidine —— C19H18N6OS2
    2-methyl-4-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-5-phenylthieno[2,3-d]pyrimidine
    —— 5-[[(3S)-3-methylpyrrolidin-3-yl]methyl]-1-benzothiophen-3-one —— C14H17NOS
    5-[[(3S)-3-methylpyrrolidin-3-yl]methyl]-1-benzothiophen-3-one
    —— 5-methyl-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-6-phenylthieno[2,3-d]pyrimidine —— C19H18N6OS2
    5-methyl-4-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-6-phenylthieno[2,3-d]pyrimidine
    —— 1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1-ethyltetrazol-5-yl)sulfanylethanone —— C16H16N6OS3
    1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1-ethyltetrazol-5-yl)sulfanylethanone
    —— 2-(1-Benzyltetrazol-5-yl)sulfanyl-1-(1-cyclopropyl-2,5-dimethylpyrrol-3-yl)ethanone —— C19H21N5OS
    2-(1-Benzyltetrazol-5-yl)sulfanyl-1-(1-cyclopropyl-2,5-dimethylpyrrol-3-yl)ethanone
    —— 2-(7-chloro-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidin-8-yl)acetic acid —— C8H7ClN2O3S
    2-(7-chloro-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidin-8-yl)acetic acid
    —— 2-(5-chloro-7-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)acetic acid —— C8H7ClN2O3S
    2-(5-chloro-7-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)acetic acid
    —— 2-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-5-(5-ethyl-4-methylthiophen-2-yl)-1,3,4-oxadiazole —— C14H16N6OS2
    2-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-5-(5-ethyl-4-methylthiophen-2-yl)-1,3,4-oxadiazole
    —— 5,6-Dimethyl-4-pyrimidin-2-ylsulfanyl-2-thiophen-2-ylthieno[2,3-d]pyrimidine —— C16H12N4S3
    5,6-Dimethyl-4-pyrimidin-2-ylsulfanyl-2-thiophen-2-ylthieno[2,3-d]pyrimidine
    —— 7-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-methyl-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C12H12N6OS2
    7-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-3-methyl-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H17FN4O2S2
    N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 7-(2-aminoethyl)-6-chloro-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazin-8-one —— C9H12ClN3OS
    7-(2-aminoethyl)-6-chloro-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazin-8-one
    —— 4-[(5-Chloro-1,3-benzothiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidine —— C13H6ClN3S3
    4-[(5-Chloro-1,3-benzothiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidine
    —— 2-(5-Methyl-6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole —— C20H19N5OS2
    2-(5-Methyl-6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole
    —— [(4'aS)-2',2',8'-trimethylspiro[1,3-dithiane-2,7'-3,4,5,6-tetrahydro-1H-naphthalene]-4'a-yl]methanol —— C17H28OS2
    [(4'aS)-2',2',8'-trimethylspiro[1,3-dithiane-2,7'-3,4,5,6-tetrahydro-1H-naphthalene]-4'a-yl]methanol
    —— (Z)-3-(furan-2-yl)-N-(2-phenylsulfanylethyl)prop-2-enamide —— C15H15NO2S
    (Z)-3-(furan-2-yl)-N-(2-phenylsulfanylethyl)prop-2-enamide
    —— 2-(3-hydroxy-4-oxo-5,6-dihydrothieno[2,3-b]thiopyran-2-yl)acetic acid —— C9H8O4S2
    2-(3-hydroxy-4-oxo-5,6-dihydrothieno[2,3-b]thiopyran-2-yl)acetic acid
    —— 2-(6-methyl-5,7-dioxo-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidin-8-yl)acetic acid —— C9H10N2O4S
    2-(6-methyl-5,7-dioxo-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidin-8-yl)acetic acid
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide —— C17H18ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-(2-chlorophenyl)sulfanylpropanamide —— C16H15Cl2NOS
    (2R)-N-[(2-chlorophenyl)methyl]-2-(2-chlorophenyl)sulfanylpropanamide
    —— N-hydroxy-N-[[(2S)-2-methyl-2,3-dihydro-1-benzothiophen-7-yl]methyl]acetamide —— C12H15NO2S
    N-hydroxy-N-[[(2S)-2-methyl-2,3-dihydro-1-benzothiophen-7-yl]methyl]acetamide
    —— (3S,4S)-1-methyl-4-(2-methylsulfanylpyrimidin-5-yl)piperidin-3-amine —— C11H18N4S
    (3S,4S)-1-methyl-4-(2-methylsulfanylpyrimidin-5-yl)piperidin-3-amine
    —— 5-[(2S)-1-amino-2-hydroxybutan-2-yl]-1-benzothiophen-3-one —— C12H15NO2S
    5-[(2S)-1-amino-2-hydroxybutan-2-yl]-1-benzothiophen-3-one
    —— (3S,4R)-1-methyl-4-(2-methylsulfanylpyrimidin-5-yl)piperidin-3-amine —— C11H18N4S
    (3S,4R)-1-methyl-4-(2-methylsulfanylpyrimidin-5-yl)piperidin-3-amine
    —— 1-[(3S)-3-[hydroxy(methyl)amino]-2,3-dihydro-1-benzothiophen-5-yl]propan-1-one —— C12H15NO2S
    1-[(3S)-3-[hydroxy(methyl)amino]-2,3-dihydro-1-benzothiophen-5-yl]propan-1-one
    —— (2S)-2-cyclopentyl-2-(5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazol-3-yl)ethanamine —— C11H18N4S
    (2S)-2-cyclopentyl-2-(5,6-dihydro-[1,3]thiazolo[2,3-c][1,2,4]triazol-3-yl)ethanamine
    —— N-hydroxy-N-[[(2R)-2-methyl-2,3-dihydro-1-benzothiophen-7-yl]methyl]acetamide —— C12H15NO2S
    N-hydroxy-N-[[(2R)-2-methyl-2,3-dihydro-1-benzothiophen-7-yl]methyl]acetamide
    —— 1-[(3R)-3-[hydroxy(methyl)amino]-2,3-dihydro-1-benzothiophen-5-yl]propan-1-one —— C12H15NO2S
    1-[(3R)-3-[hydroxy(methyl)amino]-2,3-dihydro-1-benzothiophen-5-yl]propan-1-one