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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-3-amino-2-[2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile —— C9H9F3N6OS
    (E)-3-amino-2-[2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 1-[(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-(2-hydroxyethyl)thiourea —— C10H16N2OS
    1-[(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-(2-hydroxyethyl)thiourea
    —— 1-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-(2-hydroxyethyl)thiourea —— C10H16N2OS
    1-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-3-(2-hydroxyethyl)thiourea
    —— 2-Phenylsulfanyl-propionic acid (1,2,2-trimethyl-propylidene)-hydrazide —— C15H22N2OS
    2-Phenylsulfanyl-propionic acid (1,2,2-trimethyl-propylidene)-hydrazide
    —— 4-fluoro-N-[(Z)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]benzamide —— C26H17FN4O3S
    4-fluoro-N-[(Z)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]benzamide
    —— 1-(3-chlorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C20H20ClN3S
    1-(3-chlorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— N,N-diethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C26H24N6O6S2
    N,N-diethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— N,N-diethyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide —— C21H23N7O6S2
    N,N-diethyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide
    —— N,N-diethyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C26H24N6O6S2
    N,N-diethyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(furan-2-yl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(furan-2-yl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— ethyl (2Z)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-thiophen-2-yl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H20N2O3S3
    ethyl (2Z)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-thiophen-2-yl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19ClN4OS3
    N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (E)-1,2-dichloro-3-isothiocyanatoprop-1-ene —— C4H3Cl2NS
    (E)-1,2-dichloro-3-isothiocyanatoprop-1-ene
    —— 4-chloro-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C15H17ClN4S
    4-chloro-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— 2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-7-[(E)-2-(4-methoxyphenyl)ethenyl]-[1,2,4]triazolo[1,5-a]pyrimidine —— C20H13ClF3N5OS
    2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-7-[(E)-2-(4-methoxyphenyl)ethenyl]-[1,2,4]triazolo[1,5-a]pyrimidine
    —— 4-fluoro-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C15H17FN4S
    4-fluoro-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— 4-methyl-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C16H20N4S
    4-methyl-N-[(Z)-2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(Z)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide —— C22H22N4OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(Z)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— 3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-[2-(methoxyimino)ethyl]-4-isothiazolecarbonitrile —— C13H8ClF3N4OS2
    3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-[2-(methoxyimino)ethyl]-4-isothiazolecarbonitrile
    —— (Z)-1-[6-(2-chlorophenyl)sulfanylpyridin-3-yl]-N-methoxymethanimine —— C13H11ClN2OS
    (Z)-1-[6-(2-chlorophenyl)sulfanylpyridin-3-yl]-N-methoxymethanimine
    —— ethyl (4S)-3-oxo-1,5-benzoxathiepine-4-carboxylate —— C12H12O4S
    ethyl (4S)-3-oxo-1,5-benzoxathiepine-4-carboxylate
    —— 2-[(2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide —— C23H27N7O6S2
    2-[(2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide
    —— 2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide —— C26H26N6O6S3
    2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide
    —— 2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide —— C26H26N6O6S3
    2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide
    —— (1R,2R,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2R,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— (1R,2S,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2S,3R,5S,7R)-2-[(S)-butylsulfinyl]-1,5-dimethyladamantane
    —— (1R,2S,3R,5S,7R)-2-[(R)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2S,3R,5S,7R)-2-[(R)-butylsulfinyl]-1,5-dimethyladamantane
    —— 2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide —— C23H27N7O6S2
    2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitro-N,N-dipropylbenzenesulfonamide
    —— (1R,2R,3R,5S,7R)-2-[(R)-butylsulfinyl]-1,5-dimethyladamantane —— C16H28OS
    (1R,2R,3R,5S,7R)-2-[(R)-butylsulfinyl]-1,5-dimethyladamantane
    —— N-butyl-N-methyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C27H26N6O6S2
    N-butyl-N-methyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— 2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-methyl-5-nitrobenzenesulfonamide —— C25H24N6O6S3
    2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-methyl-5-nitrobenzenesulfonamide
    —— N-butyl-N-methyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C27H26N6O6S2
    N-butyl-N-methyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— N-butyl-N-methyl-2-[(2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide —— C22H25N7O6S2
    N-butyl-N-methyl-2-[(2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide
    —— 2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-ethyl-5-nitrobenzenesulfonamide —— C26H26N6O6S3
    2-[(2E)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-ethyl-5-nitrobenzenesulfonamide
    —— N-butyl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C25H23N5O3S3
    N-butyl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— N-butyl-N-methyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide —— C22H25N7O6S2
    N-butyl-N-methyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide
    —— 4-Hydroxyimino-3-(methylthio)-4,5,6,7-tetrahydrobenzo[c]thiophene-1-carbonitrile —— C10H10N2OS2
    4-Hydroxyimino-3-(methylthio)-4,5,6,7-tetrahydrobenzo[c]thiophene-1-carbonitrile
    —— methyl (2Z)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H19ClN2O3S2
    methyl (2Z)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-butyl-N-ethyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C28H28N6O6S2
    N-butyl-N-ethyl-5-nitro-2-[(2E)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-phenylethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H18N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-phenylethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— N-butyl-N-ethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C28H28N6O6S2
    N-butyl-N-ethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— 2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-methyl-5-nitrobenzenesulfonamide —— C25H24N6O6S3
    2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-methyl-5-nitrobenzenesulfonamide
    —— 2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-ethyl-5-nitrobenzenesulfonamide —— C26H26N6O6S3
    2-[(2Z)-2-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]hydrazinyl]-N-butyl-N-ethyl-5-nitrobenzenesulfonamide
    —— (E)-2-(1H-benzimidazol-2-yl)-3-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enenitrile —— C21H14BrN3OS
    (E)-2-(1H-benzimidazol-2-yl)-3-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]prop-2-enenitrile
    —— (Z)-N-[[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxy]-1-(2,4-dichlorophenyl)methanimine —— C19H13BrCl2F3N3OS
    (Z)-N-[[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxy]-1-(2,4-dichlorophenyl)methanimine
    —— 2-amino-4-(4-methylthiophenyl)-8-[(4-methylthiophenyl)methylene]-6-propyl-5,6, 7-trihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile —— C27H29N3OS2
    2-amino-4-(4-methylthiophenyl)-8-[(4-methylthiophenyl)methylene]-6-propyl-5,6, 7-trihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile
    —— 3-{[4-(2,4-Dichlorostyryl)-2-pyrimidinyl]sulfanyl}-5-(trifluoromethyl)-2-pyridinecarbonitrile —— C19H9Cl2F3N4S
    3-{[4-(2,4-Dichlorostyryl)-2-pyrimidinyl]sulfanyl}-5-(trifluoromethyl)-2-pyridinecarbonitrile
    —— dimethyl (2Z)-5-amino-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarboxylate —— C26H24N2O5S3
    dimethyl (2Z)-5-amino-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarboxylate
    —— [(Z)-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]methylideneamino] 3-methylbutanoate —— C17H17ClN2O2S
    [(Z)-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]methylideneamino] 3-methylbutanoate
    —— (1'R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-dioxolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile —— C16H14N4O2S
    (1'R,5'R,6'R)-2'-amino-6'-(4-methylsulfanylphenyl)spiro[1,3-dioxolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile