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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(3-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole —— C11H12FN3S
    3-[(3-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole
    —— methyl {[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C12H15N3O2S2
    methyl {[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— N-cyclopropyl-2-{[5-cyclopropyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C13H20N4OS
    N-cyclopropyl-2-{[5-cyclopropyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-cyclopentyl-2-[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C10H16N4OS
    N-cyclopentyl-2-[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide —— C16H22N4OS
    2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide
    —— methyl {[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C13H17N3O2S2
    methyl {[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 2-phenyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H9N5OS
    2-phenyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— 3,3-Dimethyl-1-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}butan-2-one —— C9H14N2OS3
    3,3-Dimethyl-1-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}butan-2-one
    —— N-cyclopentyl-2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetamide —— C10H15N3OS3
    N-cyclopentyl-2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetamide
    —— 1-Methyl-4-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]piperazine —— C11H21N5S
    1-Methyl-4-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]piperazine
    —— 2,4-Di(propan-2-yl)-6-prop-1-en-2-yl-1,3,2-dioxaphosphinane-5,5-dithiol —— C12H23O2PS2
    2,4-Di(propan-2-yl)-6-prop-1-en-2-yl-1,3,2-dioxaphosphinane-5,5-dithiol
    —— [(Z)-(2,4,5-trimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate —— C9H16N2O2S2
    [(Z)-(2,4,5-trimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate
    —— Ethyl cis-1-propenyl disulfide —— C5H10S2
    Ethyl cis-1-propenyl disulfide
    —— Methyl pentyl tetrasulfide —— C6H14S4
    Methyl pentyl tetrasulfide
    —— Cyclohexane, 1,2-bis-(methylthio), trans —— C8H16S2
    Cyclohexane, 1,2-bis-(methylthio), trans
    —— 1-(Methylthio)propyl 1-propenyl disulfide —— C7H14S4
    1-(Methylthio)propyl 1-propenyl disulfide
    —— 2,5-Dichloro-4-cyano-6-pentafluoroethylthiopyridine —— C8HCl2F5N2S
    2,5-Dichloro-4-cyano-6-pentafluoroethylthiopyridine
    —— Di(3-chloro-4-methoxyphenyl)sulfide —— C14H12Cl2O2S
    Di(3-chloro-4-methoxyphenyl)sulfide
    —— 3-[(4R)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C15H18N4O2S
    3-[(4R)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— 3-[(4S)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C15H18N4O2S
    3-[(4S)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— 2,4-Dimethyl-6-(methylthio)pyridine —— C8H11NS
    2,4-Dimethyl-6-(methylthio)pyridine
    —— 6,7-Dihydro-2,2-dimethylcyclopenta-1,3-dithian-4(5H)-thione —— C9H12S3
    6,7-Dihydro-2,2-dimethylcyclopenta-1,3-dithian-4(5H)-thione
    —— 3-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide —— C21H22ClN3O3S2
    3-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide
    —— 3-[(3aR,7aR)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide —— C21H22ClN3O3S2
    3-[(3aR,7aR)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide
    —— 2-Chloro-5,5-dimethyl-2-phenylsulfanyl-cyclohexane-1,3-dione —— C14H15ClO2S
    2-Chloro-5,5-dimethyl-2-phenylsulfanyl-cyclohexane-1,3-dione
    —— N-[(E)-2-[(1-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)amino]-2-nitroso-1-phenylethenyl]hydroxylamine —— C12H14N6O2S
    N-[(E)-2-[(1-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)amino]-2-nitroso-1-phenylethenyl]hydroxylamine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-prop-2-enylacetamide —— C22H22N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-prop-2-enylacetamide
    —— 8,11,11-Trimethyl-5-methylsulfanyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C12H17N3S
    8,11,11-Trimethyl-5-methylsulfanyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(oxolan-2-ylmethyl)acetamide —— C22H22N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(oxolan-2-ylmethyl)acetamide
    —— 4-[4-[(5-Ethyl-[1,2,4]triazino[5,6-b]indol-3-yl)sulfanyl]-3-nitrophenyl]sulfonylmorpholine —— C21H20N6O5S2
    4-[4-[(5-Ethyl-[1,2,4]triazino[5,6-b]indol-3-yl)sulfanyl]-3-nitrophenyl]sulfonylmorpholine
    —— 2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylbutanamide —— C24H24F2N4OS
    2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylbutanamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(4-methylcyclohexyl)acetamide —— C24H26N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(4-methylcyclohexyl)acetamide
    —— N-benzyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C25H22N4OS
    N-benzyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]phthalazin-1-amine —— C19H15N7O2S
    N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]phthalazin-1-amine
    —— N-cyclohexyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C24H26N4OS
    N-cyclohexyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— 2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide —— C24H17Cl3N4OS
    2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide
    —— 3-(2,4-dinitrophenyl)sulfanyl-5-N,6-N-diethyl-1,2,4-triazine-5,6-diamine —— C13H15N7O4S
    3-(2,4-dinitrophenyl)sulfanyl-5-N,6-N-diethyl-1,2,4-triazine-5,6-diamine
    —— N-butan-2-yl-N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C25H28N4O3S2
    N-butan-2-yl-N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C20H19N3O3S
    Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-(2-phenylethyl)acetamide —— C27H26N4OS
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-(2-phenylethyl)acetamide
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(4-methylphenyl)methyl]acetamide —— C27H26N4OS
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(4-methylphenyl)methyl]acetamide
    —— 3-((4-Chlorobenzyl)sulfanyl)-6-methyl-5-(2-(((4-methylbenzyl)oxy)amino)vinyl)-1,2,4-triazine —— C21H21ClN4OS
    3-((4-Chlorobenzyl)sulfanyl)-6-methyl-5-(2-(((4-methylbenzyl)oxy)amino)vinyl)-1,2,4-triazine
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-3,5-dimethyl-1,2-oxazole —— C21H18N4OS
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-3,5-dimethyl-1,2-oxazole
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(1,1-dioxothiolan-3-yl)-N-methylacetamide —— C24H26N4O3S2
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(1,1-dioxothiolan-3-yl)-N-methylacetamide
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C24H22N4OS
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— 1-(2,5-Dimethyl-1-prop-2-enylpyrrol-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C26H24N4OS
    1-(2,5-Dimethyl-1-prop-2-enylpyrrol-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C28H28N4O2S
    1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C24H22N4OS2
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— Ethyl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate —— C16H15N3O4S
    Ethyl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate
    —— N-(2-(3-(Allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-methylaniline —— C16H18N4S
    N-(2-(3-(Allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-methylaniline