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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate —— C15H19N4O4S-
    (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate
    —— ethyl (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C16H22N4O4S
    ethyl (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— 7-ethyl-1,3-dimethyl-5-[(1S)-1-phenylethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O2S
    7-ethyl-1,3-dimethyl-5-[(1S)-1-phenylethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N,N-bis(prop-2-enyl)acetamide —— C18H22N4O2S
    2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N,N-bis(prop-2-enyl)acetamide
    —— ethyl (2S)-2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-oxobutanoate —— C16H20N4O5S
    ethyl (2S)-2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-oxobutanoate
    —— 5-[(2R)-butan-2-yl]sulfanyl-7-ethyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C14H20N4O2S
    5-[(2R)-butan-2-yl]sulfanyl-7-ethyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 3-[2-(4-acetylpiperazin-1-yl)-2-oxoethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C18H23N5O3S
    3-[2-(4-acetylpiperazin-1-yl)-2-oxoethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 3-[(2-chlorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C17H16ClN3OS
    3-[(2-chlorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— N-[(2S)-butan-2-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H22N4O2S
    N-[(2S)-butan-2-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2S)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C17H23FN4O2S
    (2S)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 4-(2-phenylethyl)-3-(2-phenylethylsulfanyl)-1H-1,2,4-triazol-5-one —— C18H19N3OS
    4-(2-phenylethyl)-3-(2-phenylethylsulfanyl)-1H-1,2,4-triazol-5-one
    —— methyl (2S)-2-(1,3,7-trimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C13H16N4O4S
    methyl (2S)-2-(1,3,7-trimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— 5-[(2-Chlorophenyl)methylsulfanyl]-7-ethyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H17ClN4O2S
    5-[(2-Chlorophenyl)methylsulfanyl]-7-ethyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-Ethyl-1,3-dimethyl-5-propan-2-ylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C13H18N4O2S
    7-Ethyl-1,3-dimethyl-5-propan-2-ylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21FN4O2S
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 7-Ethyl-5-ethylsulfanyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C12H16N4O2S
    7-Ethyl-5-ethylsulfanyl-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1,3-Dimethyl-5-propan-2-ylsulfanyl-7-propylpyrimido[4,5-d]pyrimidine-2,4-dione —— C14H20N4O2S
    1,3-Dimethyl-5-propan-2-ylsulfanyl-7-propylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 3-(4-oxo-4-thiophen-2-ylbutyl)sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C18H19N3O2S2
    3-(4-oxo-4-thiophen-2-ylbutyl)sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C21H24N4O2S
    2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— 3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C16H20N4O3S
    3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 3-[(2-fluorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C17H16FN3OS
    3-[(2-fluorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 4-(2-phenylethyl)-3-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C20H18N4OS2
    4-(2-phenylethyl)-3-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— butyl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H21N3O3S
    butyl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 5-(ethylthio)-1,3-dimethyl-7-propylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C13H18N4O2S
    5-(ethylthio)-1,3-dimethyl-7-propylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— N-(2-cyanoethyl)-N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H19N5O2S
    N-(2-cyanoethyl)-N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C16H22N4O2S
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-(2-morpholin-4-ylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one —— C13H21N3O2S
    2-(2-morpholin-4-ylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one
    —— 3-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-butyl-1H-1,2,4-triazol-5-one —— C15H16BrN5O2S
    3-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-butyl-1H-1,2,4-triazol-5-one
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate —— C12H12N3O2S2-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate
    —— N-[[4-ethyl-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazol-3-yl]methyl]adamantane-1-carboxamide —— C24H32N4OS
    N-[[4-ethyl-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazol-3-yl]methyl]adamantane-1-carboxamide
    —— (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid —— C11H11N3O2S2
    (E)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-thiophen-2-ylprop-2-enoic acid
    —— 4-ethyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one —— C12H20N3O2S+
    4-ethyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one
    —— 7-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C13H15N5O2S2
    7-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 4-amino-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one —— C10H17N4O2S+
    4-amino-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-3-ylprop-2-enoate —— C12H11N4O2S-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-pyridin-3-ylprop-2-enoate
    —— (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C13H14BrN4O3S-
    (Z)-3-[4-bromo-5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-(5-bromothiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C12H12BrN3O2S2
    (E)-3-(5-bromothiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate —— C14H17N4O2S-
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(1,2,5-trimethylpyrrol-3-yl)prop-2-enoate
    —— 3-[(4-bromophenyl)methylsulfanyl]-4-butyl-1H-1,2,4-triazol-5-one —— C13H16BrN3OS
    3-[(4-bromophenyl)methylsulfanyl]-4-butyl-1H-1,2,4-triazol-5-one
    —— (Z)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid —— C13H15N3O4S
    (Z)-3-[5-(dimethylamino)furan-2-yl]-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]prop-2-enoic acid
    —— 2-(2-morpholin-4-ium-4-ylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one —— C13H22N3O2S+
    2-(2-morpholin-4-ium-4-ylethylsulfanyl)-4-propyl-1H-pyrimidin-6-one
    —— 4-butyl-3-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C13H15ClFN3OS
    4-butyl-3-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C16H22N4O3S
    (E)-3-[5-(diethylamino)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— 2-(2,4-dinitrophenyl)sulfanyl-4,5-dimethyl-1H-pyrimidin-6-one —— C12H10N4O5S
    2-(2,4-dinitrophenyl)sulfanyl-4,5-dimethyl-1H-pyrimidin-6-one
    —— 6-Isopropyl-2-(methylthio)pyrimidin-4-ol —— C8H12N2OS
    6-Isopropyl-2-(methylthio)pyrimidin-4-ol
    —— 2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C22H23N3O2S
    2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C17H14ClN3O3S2
    (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(5-piperidin-1-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C17H21N4O3S-
    (E)-3-(5-piperidin-1-ylfuran-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C17H14ClN3O3S
    (E)-3-[5-(3-chlorophenyl)furan-2-yl]-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— 2-[2-(4-ethylpiperazin-1-yl)-2-oxoethyl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one —— C15H24N4O2S
    2-[2-(4-ethylpiperazin-1-yl)-2-oxoethyl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one