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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-methylphenyl)methylsulfanyl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide —— C19H22N2O2S2
    2-[(4-methylphenyl)methylsulfanyl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide
    —— (E)-3-(5-bromothiophen-2-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]prop-2-enehydrazide —— C16H15BrN2O2S2
    (E)-3-(5-bromothiophen-2-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]prop-2-enehydrazide
    —— [1-(2-methylsulfanylpyrimidin-5-yl)cyclopropyl]methanamine —— C9H13N3S
    [1-(2-methylsulfanylpyrimidin-5-yl)cyclopropyl]methanamine
    —— 2-methylsulfanyl-5-[(3S)-pyrrolidin-3-yl]pyrimidine —— C9H13N3S
    2-methylsulfanyl-5-[(3S)-pyrrolidin-3-yl]pyrimidine
    —— [1-(2-methylsulfanylpyrimidin-4-yl)cyclopropyl]methanamine —— C9H13N3S
    [1-(2-methylsulfanylpyrimidin-4-yl)cyclopropyl]methanamine
    —— N-methyl-N-[(1S)-1-(3-methylsulfanylphenyl)ethyl]hydroxylamine —— C10H15NOS
    N-methyl-N-[(1S)-1-(3-methylsulfanylphenyl)ethyl]hydroxylamine
    —— 2-(2,4-dimethylphenyl)sulfanyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C18H19FN2O2S2
    2-(2,4-dimethylphenyl)sulfanyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— 6-Amino-5-[2-(2-chlorophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione —— C13H12ClN3O3S
    6-Amino-5-[2-(2-chlorophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione
    —— 5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C13H13N5OS2
    5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-dimethylpropanamide —— C7H12N4OS2
    (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-dimethylpropanamide
    —— 2-methylsulfanyl-5-[(3R)-pyrrolidin-3-yl]pyrimidine —— C9H13N3S
    2-methylsulfanyl-5-[(3R)-pyrrolidin-3-yl]pyrimidine
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C11H16N4O3S3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— (2E,4E)-N'-[2-(2-fluorophenyl)sulfanylacetyl]hexa-2,4-dienehydrazide —— C14H15FN2O2S
    (2E,4E)-N'-[2-(2-fluorophenyl)sulfanylacetyl]hexa-2,4-dienehydrazide
    —— 3-(4-chlorophenyl)sulfanyl-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide —— C18H19ClN2O2S2
    3-(4-chlorophenyl)sulfanyl-N'-[2-(4-methylphenyl)sulfanylacetyl]propanehydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-(5-phenylfuran-2-yl)propanehydrazide —— C21H19FN2O3S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-(5-phenylfuran-2-yl)propanehydrazide
    —— (E)-N'-[2-(4-methylphenyl)sulfanylacetyl]-3-(3-methylthiophen-2-yl)prop-2-enehydrazide —— C17H18N2O2S2
    (E)-N'-[2-(4-methylphenyl)sulfanylacetyl]-3-(3-methylthiophen-2-yl)prop-2-enehydrazide
    —— (E)-N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-(3-methylthiophen-2-yl)prop-2-enehydrazide —— C16H15FN2O2S2
    (E)-N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-(3-methylthiophen-2-yl)prop-2-enehydrazide
    —— 2-methylsulfanyl-4-[(3S)-pyrrolidin-3-yl]pyrimidine —— C9H13N3S
    2-methylsulfanyl-4-[(3S)-pyrrolidin-3-yl]pyrimidine
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-methylbutanehydrazide —— C13H17FN2O2S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-3-methylbutanehydrazide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C13H20N4O3S3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C13H13N5OS2
    5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 3-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C12H11FN6OS
    3-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— N'-[2-(2,5-dimethylphenyl)sulfanylacetyl]-2-(3,5-dimethylpyrazol-1-yl)acetohydrazide —— C17H22N4O2S
    N'-[2-(2,5-dimethylphenyl)sulfanylacetyl]-2-(3,5-dimethylpyrazol-1-yl)acetohydrazide
    —— (3S)-3-amino-2,3-dihydrothieno[3,2-b]thiophene-5-carbaldehyde —— C7H7NOS2
    (3S)-3-amino-2,3-dihydrothieno[3,2-b]thiophene-5-carbaldehyde
    —— 3-[(1R)-1-[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C13H14N6OS
    3-[(1R)-1-[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— (3S)-3-amino-2,3-dihydrothieno[3,4-b]thiophene-6-carbaldehyde —— C7H7NOS2
    (3S)-3-amino-2,3-dihydrothieno[3,4-b]thiophene-6-carbaldehyde
    —— 2-(3,5-dimethylpyrazol-1-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide —— C16H20N4O2S
    2-(3,5-dimethylpyrazol-1-yl)-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide
    —— 3-[(1S)-1-[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C12H11ClN6OS
    3-[(1S)-1-[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— 5-[(1R)-1-aminoethyl]-4-methylsulfanylthiophen-2-amine —— C7H12N2S2
    5-[(1R)-1-aminoethyl]-4-methylsulfanylthiophen-2-amine
    —— N-[(6-methyl-2-methylsulfanylpyrimidin-4-yl)methyl]hydroxylamine —— C7H11N3OS
    N-[(6-methyl-2-methylsulfanylpyrimidin-4-yl)methyl]hydroxylamine
    —— 1-(5-amino-3-methylsulfanyl-1H-pyrrol-2-yl)-2-hydroxyethanone —— C7H10N2O2S
    1-(5-amino-3-methylsulfanyl-1H-pyrrol-2-yl)-2-hydroxyethanone
    —— 6-Amino-1-methyl-5-(2-phenylsulfanylacetyl)pyrimidine-2,4-dione —— C13H13N3O3S
    6-Amino-1-methyl-5-(2-phenylsulfanylacetyl)pyrimidine-2,4-dione
    —— N-methyl-N-[(2-methylsulfanylpyrimidin-4-yl)methyl]hydroxylamine —— C7H11N3OS
    N-methyl-N-[(2-methylsulfanylpyrimidin-4-yl)methyl]hydroxylamine
    —— 2-amino-1-(1-methyl-5-methylsulfanylpyrrol-2-yl)ethanone —— C8H12N2OS
    2-amino-1-(1-methyl-5-methylsulfanylpyrrol-2-yl)ethanone
    —— 2-amino-1-(5-amino-3-methylsulfanylfuran-2-yl)ethanone —— C7H10N2O2S
    2-amino-1-(5-amino-3-methylsulfanylfuran-2-yl)ethanone
    —— (3R)-3-amino-2,3-dihydrothieno[3,4-b]thiophene-6-carbaldehyde —— C7H7NOS2
    (3R)-3-amino-2,3-dihydrothieno[3,4-b]thiophene-6-carbaldehyde
    —— 5-[(1S)-1-aminoethyl]-4-methylsulfanylthiophen-2-amine —— C7H12N2S2
    5-[(1S)-1-aminoethyl]-4-methylsulfanylthiophen-2-amine
    —— 2-(2,3-dihydrothieno[2,3-b]thiophen-5-yl)ethanamine —— C8H11NS2
    2-(2,3-dihydrothieno[2,3-b]thiophen-5-yl)ethanamine
    —— 1-(5-amino-3-methylsulfanylfuran-2-yl)-2-hydroxyethanone —— C7H9NO3S
    1-(5-amino-3-methylsulfanylfuran-2-yl)-2-hydroxyethanone
    —— N-methyl-N-{[3-(methylsulfanyl)phenyl]methyl}hydroxylamine —— C9H13NOS
    N-methyl-N-{[3-(methylsulfanyl)phenyl]methyl}hydroxylamine
    —— 2-(4-fluorophenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide —— C14H13FN2OS
    2-(4-fluorophenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide
    —— 3-(4-fluorophenyl)sulfanyl-N-(pyridin-2-ylmethyl)propanamide —— C15H15FN2OS
    3-(4-fluorophenyl)sulfanyl-N-(pyridin-2-ylmethyl)propanamide
    —— (3R)-1-amino-5-methylsulfonylpentan-3-ol —— C6H15NO3S
    (3R)-1-amino-5-methylsulfonylpentan-3-ol
    —— (3S)-1-amino-5-methylsulfonylpentan-3-ol —— C6H15NO3S
    (3S)-1-amino-5-methylsulfonylpentan-3-ol
    —— N-[(3S)-2,3-dihydro-1-benzothiophen-3-yl]-N-methylhydroxylamine —— C9H11NOS
    N-[(3S)-2,3-dihydro-1-benzothiophen-3-yl]-N-methylhydroxylamine
    —— N-[(3R)-2,3-dihydro-1-benzothiophen-3-yl]-N-methylhydroxylamine —— C9H11NOS
    N-[(3R)-2,3-dihydro-1-benzothiophen-3-yl]-N-methylhydroxylamine
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] pyridine-3-carboxylate —— C22H20N2O3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] pyridine-3-carboxylate
    —— (2S,3R)-2-amino-2,3-dihydrothieno[3,4-b]thiophen-3-ol —— C6H7NOS2
    (2S,3R)-2-amino-2,3-dihydrothieno[3,4-b]thiophen-3-ol
    —— (2R,3S)-2-amino-2,3-dihydrothieno[3,4-b]thiophen-3-ol —— C6H7NOS2
    (2R,3S)-2-amino-2,3-dihydrothieno[3,4-b]thiophen-3-ol
    —— (2R)-2-hydroxythieno[3,4-b]thiophen-3-one —— C6H4O2S2
    (2R)-2-hydroxythieno[3,4-b]thiophen-3-one