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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3-bromophenyl)-4-methylsulfanyl-1,2,5-thiadiazole —— C9H7BrN2S2
    3-(3-bromophenyl)-4-methylsulfanyl-1,2,5-thiadiazole
    —— 5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-2-[[methyl-[(4-methylsulfanylphenyl)methyl]amino]methyl]-1H-1,2,4-triazole-3-thione —— C19H22N4OS2
    5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-2-[[methyl-[(4-methylsulfanylphenyl)methyl]amino]methyl]-1H-1,2,4-triazole-3-thione
    —— (2S)-2-phenyl-2-[4-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]piperazin-1-yl]acetonitrile —— C20H19F3N4OS
    (2S)-2-phenyl-2-[4-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]piperazin-1-yl]acetonitrile
    —— 4-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-3-(naphthalen-1-ylmethyl)-1H-1,2,4-triazole-5-thione —— C23H18N8O2S2
    4-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-3-(naphthalen-1-ylmethyl)-1H-1,2,4-triazole-5-thione
    —— (2S)-2-phenyl-2-[4-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]piperazin-1-yl]acetonitrile —— C22H21N5O2S
    (2S)-2-phenyl-2-[4-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]piperazin-1-yl]acetonitrile
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-fluorophenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C19H15FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-fluorophenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[2-[4-[(S)-cyano(phenyl)methyl]piperazin-1-yl]-2-oxoethyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C22H23N5OS
    2-[2-[4-[(S)-cyano(phenyl)methyl]piperazin-1-yl]-2-oxoethyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— (2R)-2-phenyl-2-[4-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]piperazin-1-yl]acetonitrile —— C22H21N5O2S
    (2R)-2-phenyl-2-[4-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]piperazin-1-yl]acetonitrile
    —— (2R)-2-phenyl-2-[4-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]piperazin-1-yl]acetonitrile —— C20H19F3N4OS
    (2R)-2-phenyl-2-[4-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]piperazin-1-yl]acetonitrile
    —— 3-Methoxy-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide —— C22H17N3O3S
    3-Methoxy-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide
    —— 3-methoxy-N'-{(E)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide —— C18H15N3O3S
    3-methoxy-N'-{(E)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide
    —— 2-methyl-3-({(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}amino)quinazolin-4(3H)-one —— C23H16N4O2S
    2-methyl-3-({(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}amino)quinazolin-4(3H)-one
    —— 2-hydroxy-N'-[(E)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]benzohydrazide —— C18H15N5O4S
    2-hydroxy-N'-[(E)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]benzohydrazide
    —— (3S)-N-butyl-N-[2-(2-fluorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine —— C16H24FNO2S2
    (3S)-N-butyl-N-[2-(2-fluorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine
    —— (3R)-N-butyl-N-[2-(2-fluorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine —— C16H24FNO2S2
    (3R)-N-butyl-N-[2-(2-fluorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine
    —— 1-(2,6-Dimethylmorpholin-4-yl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]ethanone —— C17H20N2O2S2
    1-(2,6-Dimethylmorpholin-4-yl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]ethanone
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(propylcarbamoyl)acetamide —— C17H27N5O2S
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(propylcarbamoyl)acetamide
    —— N-(1-cyano-1,2-dimethyl-propyl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]thio]acetamide —— C12H16F3N5OS
    N-(1-cyano-1,2-dimethyl-propyl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]thio]acetamide
    —— {(S)-2-Methyl-1-[5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-ylmethylsulfanyl)-[1,3,4]oxadiazol-2-yl]-butyl}-carbamic acid tert-butyl ester —— C18H27N5O5S
    {(S)-2-Methyl-1-[5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-ylmethylsulfanyl)-[1,3,4]oxadiazol-2-yl]-butyl}-carbamic acid tert-butyl ester
    —— 1-(2,6-Dimethylmorpholin-4-yl)-2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone —— C17H19FN2O2S2
    1-(2,6-Dimethylmorpholin-4-yl)-2-[[4-(4-fluorophenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone
    —— (E)-3-amino-2-[2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C15H15N5OS2
    (E)-3-amino-2-[2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 1-[(7E)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C20H19N5O3S
    1-[(7E)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 2-benzylsulfanyl-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride —— C13H16ClN3OS
    2-benzylsulfanyl-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride
    —— N-carbamoyl-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C8H10F3N5O2S
    N-carbamoyl-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 4-{2-[(4-Fluorophenyl)sulfanyl]ethyl}pyridine hydrochloride —— C13H13ClFNS
    4-{2-[(4-Fluorophenyl)sulfanyl]ethyl}pyridine hydrochloride
    —— 6-Amino-5-cyano-2-(3-cyano-4,6-dimethyl-pyridin-2-ylsulfanylmethyl)-4-phenyl-4H-pyran-3-carboxylic acid ethyl ester —— C27H29N5O4S
    6-Amino-5-cyano-2-(3-cyano-4,6-dimethyl-pyridin-2-ylsulfanylmethyl)-4-phenyl-4H-pyran-3-carboxylic acid ethyl ester
    —— (6E)-2-ethyl-6-[[5-(2-furanylmethylthio)-2-furanyl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C17H14N4O3S2
    (6E)-2-ethyl-6-[[5-(2-furanylmethylthio)-2-furanyl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 1-(Acetylamino)-2,2,2-trichloroethyl sec-butyl(isobutyl)dithiocarbamate —— C13H23Cl3N2OS2
    1-(Acetylamino)-2,2,2-trichloroethyl sec-butyl(isobutyl)dithiocarbamate
    —— 6-Amino-3-{[(4-cyano-3,6-dimethyl-2-pyridinyl)sulfanyl]methyl}-4-phenyl-1,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile —— C22H18N6OS
    6-Amino-3-{[(4-cyano-3,6-dimethyl-2-pyridinyl)sulfanyl]methyl}-4-phenyl-1,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile
    —— 2,3-Bis[amino-(2-aminophenyl)sulfanylmethyl]butanedinitrile —— C18H20N6S2
    2,3-Bis[amino-(2-aminophenyl)sulfanylmethyl]butanedinitrile
    —— ({5-[(4-Fluoroanilino)methyl]-1,3,4-oxadiazol-2-yl}sulfanyl)acetonitrile —— C11H9FN4OS
    ({5-[(4-Fluoroanilino)methyl]-1,3,4-oxadiazol-2-yl}sulfanyl)acetonitrile
    —— 5-(4-Fluorophenyl)-2,3-dihydro-[1,3]thiazolo[2,3-b][1,3]thiazol-4-ium;bromide —— C11H9BrFNS2
    5-(4-Fluorophenyl)-2,3-dihydro-[1,3]thiazolo[2,3-b][1,3]thiazol-4-ium;bromide
    —— tetrathiocyanatomercurate(II) —— C4HgN4S4
    tetrathiocyanatomercurate(II)
    —— (2R)-2-(4-methoxyphenyl)-2-[4-(2-phenylsulfanylpyridine-3-carbonyl)piperazin-1-yl]acetonitrile —— C25H24N4O2S
    (2R)-2-(4-methoxyphenyl)-2-[4-(2-phenylsulfanylpyridine-3-carbonyl)piperazin-1-yl]acetonitrile
    —— 5-butylsulfanyl-1-[[(2R)-oxolan-2-yl]methyl]tetrazole —— C10H18N4OS
    5-butylsulfanyl-1-[[(2R)-oxolan-2-yl]methyl]tetrazole
    —— 5-butylsulfanyl-1-[[(2S)-oxolan-2-yl]methyl]tetrazole —— C10H18N4OS
    5-butylsulfanyl-1-[[(2S)-oxolan-2-yl]methyl]tetrazole
    —— (2S)-N-[(4-chlorophenyl)methyl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H21ClN4O2S
    (2S)-N-[(4-chlorophenyl)methyl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine —— C18H21N5O2S3
    4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine
    —— 4-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine —— C18H21N5O2S3
    4-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine
    —— (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylpropanamide —— C12H22N4O2S
    (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylpropanamide
    —— (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C17H24N4O2S
    (2R)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C17H24N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— 4-[[5-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine —— C19H23N5O2S3
    4-[[5-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine
    —— 4-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine —— C18H20N4O3S3
    4-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine
    —— (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylpropanamide —— C12H22N4O2S
    (2S)-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylpropanamide
    —— 4-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine —— C19H23N5O2S3
    4-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-N-(2-methylphenyl)-1,3-thiazol-2-amine
    —— (2R)-N-[(4-chlorophenyl)methyl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H21ClN4O2S
    (2R)-N-[(4-chlorophenyl)methyl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 3-(Prop-2-ene-1-sulfinyl)-propene-1-thiol —— C6H10OS2
    3-(Prop-2-ene-1-sulfinyl)-propene-1-thiol
    —— N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]-2,5-dichlorobenzenesulfonamide —— C19H12Cl2N2O3S3
    N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]-2,5-dichlorobenzenesulfonamide
    —— N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]-4-ethylbenzenesulfonamide —— C21H18N2O3S3
    N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]-4-ethylbenzenesulfonamide