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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5E)-1-methyl-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-2-thioxodihydropyrimidine-4,6(1H,5H)-dione —— C16H12N2O3S2
    (5E)-1-methyl-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-2-thioxodihydropyrimidine-4,6(1H,5H)-dione
    —— Azepan-1-yl[4-(methylsulfanyl)phenyl]methanethione —— C14H19NS2
    Azepan-1-yl[4-(methylsulfanyl)phenyl]methanethione
    —— 1,3-diethyl-5-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione —— C20H20N2O3S2
    1,3-diethyl-5-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione
    —— ethyl (6R,7R)-3-methyl-6-(4-methylphenyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C15H18N4O2S
    ethyl (6R,7R)-3-methyl-6-(4-methylphenyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— ethyl (6R,7S)-3-methyl-6-(4-methylphenyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C15H18N4O2S
    ethyl (6R,7S)-3-methyl-6-(4-methylphenyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— (4R)-4-methyl-11-(2-phenylethyl)-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one —— C17H21N4OS+
    (4R)-4-methyl-11-(2-phenylethyl)-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one
    —— ethyl (6S,7S)-6-(4-hydroxyphenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H16N4O3S
    ethyl (6S,7S)-6-(4-hydroxyphenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— 2-[(3-Chlorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C20H18ClFN2OS
    2-[(3-Chlorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— 5-[(2-Fluorophenyl)methyl]-3,6-dimethyl-2-prop-2-enylsulfanylpyrimidin-4-one —— C16H17FN2OS
    5-[(2-Fluorophenyl)methyl]-3,6-dimethyl-2-prop-2-enylsulfanylpyrimidin-4-one
    —— (2R)-N,N-dibenzyl-2-(4-methylphenyl)sulfanylpropanamide —— C24H25NOS
    (2R)-N,N-dibenzyl-2-(4-methylphenyl)sulfanylpropanamide
    —— (5Z)-2-Amino-4,6-dimethyl-5-({5-[(4-methylphenyl)sulfanyl]furan-2-YL}methylidene)cyclopenta[B]pyridine-3,7-dicarbonitrile —— C24H18N4OS
    (5Z)-2-Amino-4,6-dimethyl-5-({5-[(4-methylphenyl)sulfanyl]furan-2-YL}methylidene)cyclopenta[B]pyridine-3,7-dicarbonitrile
    —— (2S)-N,N-dibenzyl-2-(4-methylphenyl)sulfanylpropanamide —— C24H25NOS
    (2S)-N,N-dibenzyl-2-(4-methylphenyl)sulfanylpropanamide
    —— 2-[[4-methyl-5-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C18H24N4O2S
    2-[[4-methyl-5-(2-phenylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 1-[(1S)-1-(1-adamantyl)ethyl]-3-cyclopentylthiourea —— C18H30N2S
    1-[(1S)-1-(1-adamantyl)ethyl]-3-cyclopentylthiourea
    —— (2Z,5Z)-3-ethyl-2-(ethylimino)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidin-4-one —— C18H18N2O2S2
    (2Z,5Z)-3-ethyl-2-(ethylimino)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidin-4-one
    —— 1-[(1R)-1-(1-adamantyl)ethyl]-3-cyclopentylthiourea —— C18H30N2S
    1-[(1R)-1-(1-adamantyl)ethyl]-3-cyclopentylthiourea
    —— [(5E)-5-{[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-2,4-dioxo-1,3-thiazolidin-3-yl]acetic acid —— C17H11N3O5S2
    [(5E)-5-{[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-2,4-dioxo-1,3-thiazolidin-3-yl]acetic acid
    —— N-[(3R)-3-cyano-3,3a,4,5,6,7-hexahydro-1-benzothiophen-2-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C17H20N4OS2
    N-[(3R)-3-cyano-3,3a,4,5,6,7-hexahydro-1-benzothiophen-2-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-Phenyl-6-(1-pyrrolidinyl)-4-pyrimidinyl propyl sulfide —— C17H21N3S
    2-Phenyl-6-(1-pyrrolidinyl)-4-pyrimidinyl propyl sulfide
    —— Dimethyl-[[5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-2-sulfanylidene-1,3,4-oxadiazol-3-yl]methyl]azanium —— C16H25N6OS2+
    Dimethyl-[[5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-2-sulfanylidene-1,3,4-oxadiazol-3-yl]methyl]azanium
    —— 2,5-Dimethylphenyl 2-[3-(4-fluorobenzyl)[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-6-yl]ethyl sulfide —— C20H19FN4S2
    2,5-Dimethylphenyl 2-[3-(4-fluorobenzyl)[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-6-yl]ethyl sulfide
    —— 2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C15H17N3O3S
    2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— ethyl (4R)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4,6,7,8-tetrahydro-3H-quinoline-3-carboxylate —— C20H25NO4S
    ethyl (4R)-4-(5-ethylsulfanyl-2-methylfuran-3-yl)-2-methyl-5-oxo-4,6,7,8-tetrahydro-3H-quinoline-3-carboxylate
    —— 2-[(phenylsulfanyl)acetyl]-N-(prop-2-en-1-yl)hydrazinecarbothioamide —— C12H15N3OS2
    2-[(phenylsulfanyl)acetyl]-N-(prop-2-en-1-yl)hydrazinecarbothioamide
    —— Cambridge id 7201961 —— C15H13N3O2S2
    Cambridge id 7201961
    —— ethyl (3S,3aR,7aS)-2-imino-3a,4,5,6,7,7a-hexahydro-3H-1-benzothiophene-3-carboxylate —— C11H17NO2S
    ethyl (3S,3aR,7aS)-2-imino-3a,4,5,6,7,7a-hexahydro-3H-1-benzothiophene-3-carboxylate
    —— 2-[(3,4-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C20H17F3N2OS
    2-[(3,4-Difluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— 2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-butan-2-yl]acetamide —— C12H17N5OS2
    2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-butan-2-yl]acetamide
    —— Methyl 3-[3-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate —— C20H20FN3O4S
    Methyl 3-[3-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate
    —— N-[(2R)-butan-2-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H16FN3O2S
    N-[(2R)-butan-2-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C15H18FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— 3-[(2-Bromophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C13H11BrN4S2
    3-[(2-Bromophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C20H27N5OS2
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-amino-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C13H17N5O2S
    (2R)-2-[[4-amino-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H17F2N3O2S
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H15F2N3O2S
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-(cyclohexylmethyl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H20FN3O2S
    N-(cyclohexylmethyl)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-diethylacetamide —— C19H25N3O2S
    2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanyl-N,N-diethylacetamide
    —— (2S,6S)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine —— C16H25NOS
    (2S,6S)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine
    —— (3R)-3-methyl-1-(2-phenylsulfanylethyl)piperidin-1-ium —— C14H22NS+
    (3R)-3-methyl-1-(2-phenylsulfanylethyl)piperidin-1-ium
    —— (3R,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium —— C17H28NOS+
    (3R,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium
    —— (3R)-3-methyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium —— C16H26NOS+
    (3R)-3-methyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidin-1-ium
    —— (3R,5S)-3,5-dimethyl-1-(3-phenylsulfanylpropyl)piperidin-1-ium —— C16H26NS+
    (3R,5S)-3,5-dimethyl-1-(3-phenylsulfanylpropyl)piperidin-1-ium
    —— (3R,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine —— C17H27NOS
    (3R,5R)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine
    —— (3S)-3-methyl-1-(2-phenylsulfanylethyl)piperidin-1-ium —— C14H22NS+
    (3S)-3-methyl-1-(2-phenylsulfanylethyl)piperidin-1-ium
    —— N-(2-cyanoethyl)-2-(4-fluorophenyl)sulfanylacetamide —— C11H11FN2OS
    N-(2-cyanoethyl)-2-(4-fluorophenyl)sulfanylacetamide
    —— 6-Amino-5-[2-(4-fluorophenyl)sulfanylacetyl]-3-methyl-1-(2-methylpropyl)pyrimidine-2,4-dione —— C17H20FN3O3S
    6-Amino-5-[2-(4-fluorophenyl)sulfanylacetyl]-3-methyl-1-(2-methylpropyl)pyrimidine-2,4-dione
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C16H15ClFNOS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— N-(1-adamantylmethyl)-2-(4-fluorophenyl)sulfanylacetamide —— C19H24FNOS
    N-(1-adamantylmethyl)-2-(4-fluorophenyl)sulfanylacetamide
    —— (2S,6S)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholin-4-ium —— C17H28NO2S+
    (2S,6S)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholin-4-ium