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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-ethanimidoyl-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C16H15N3OS2
    (2R)-2-ethanimidoyl-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— (4R,6S)-6-methyl-N-[(6-pyrrolidin-1-ylpyridin-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C18H23N3S2
    (4R,6S)-6-methyl-N-[(6-pyrrolidin-1-ylpyridin-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— N-benzyl-2-((1-(2-(dimethylamino)ethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide —— C20H26N4O2S
    N-benzyl-2-((1-(2-(dimethylamino)ethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide
    —— 1-[2-(dimethylamino)ethyl]-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]piperidin-4-amine —— C17H29N3S2
    1-[2-(dimethylamino)ethyl]-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]piperidin-4-amine
    —— (4S,6S)-6-methyl-N-[(6-pyrrolidin-1-ylpyridin-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C18H23N3S2
    (4S,6S)-6-methyl-N-[(6-pyrrolidin-1-ylpyridin-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— N-benzyl-2-((1-(2-(diethylamino)ethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide —— C22H30N4O2S
    N-benzyl-2-((1-(2-(diethylamino)ethyl)-2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide
    —— (1R)-1-[4-(difluoromethylsulfanyl)phenyl]-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)ethanamine —— C15H18F2N4S
    (1R)-1-[4-(difluoromethylsulfanyl)phenyl]-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)ethanamine
    —— (4R,6S)-N-[2-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-yl)ethyl]-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C15H20N4S2
    (4R,6S)-N-[2-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-yl)ethyl]-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (1S)-1-[4-(difluoromethylsulfanyl)phenyl]-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)ethanamine —— C15H18F2N4S
    (1S)-1-[4-(difluoromethylsulfanyl)phenyl]-N-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)ethanamine
    —— (4S,6S)-N-[2-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-yl)ethyl]-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C15H20N4S2
    (4S,6S)-N-[2-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-yl)ethyl]-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (1R)-2-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol —— C15H17F2NO2S
    (1R)-2-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol
    —— (1S)-2-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol —— C15H17F2NO2S
    (1S)-2-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol
    —— (1R)-2-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol —— C15H17F2NO2S
    (1R)-2-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-(furan-2-yl)ethanol
    —— (3R)-N-[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine —— C13H17F2NO2S2
    (3R)-N-[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine
    —— (3S)-N-[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine —— C13H17F2NO2S2
    (3S)-N-[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine
    —— (3R)-N-[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine —— C13H17F2NO2S2
    (3R)-N-[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine
    —— 3-[(R)-2-methylsulfonylethylsulfinyl]propylcyclopentane —— C11H22O3S2
    3-[(R)-2-methylsulfonylethylsulfinyl]propylcyclopentane
    —— (3S)-N-[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine —— C13H17F2NO2S2
    (3S)-N-[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]-1,1-dioxothiolan-3-amine
    —— (1S)-N-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-pyrazin-2-ylethanamine —— C16H21N3S
    (1S)-N-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-pyrazin-2-ylethanamine
    —— 3-[(S)-2-methylsulfonylethylsulfinyl]propylcyclopentane —— C11H22O3S2
    3-[(S)-2-methylsulfonylethylsulfinyl]propylcyclopentane
    —— (1R)-N-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-pyrazin-2-ylethanamine —— C16H21N3S
    (1R)-N-[2-(3,4-dimethylphenyl)sulfanylethyl]-1-pyrazin-2-ylethanamine
    —— N-[4-(Diethylamino)phenyl]-N-{(Z)-1-[5-(8-quinolylsulfanyl)-2-furyl]methylidene}amine —— C24H23N3OS
    N-[4-(Diethylamino)phenyl]-N-{(Z)-1-[5-(8-quinolylsulfanyl)-2-furyl]methylidene}amine
    —— 1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-(3-methylpentan-3-yl)urea —— C12H26N2O3S
    1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-(3-methylpentan-3-yl)urea
    —— 1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-(3-methylpentan-3-yl)urea —— C12H26N2O3S
    1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-(3-methylpentan-3-yl)urea
    —— 6-(4-fluorophenyl)-3-thiophen-2-yl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C14H9FN4S2
    6-(4-fluorophenyl)-3-thiophen-2-yl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— [(1R,3S)-3-methylcyclohexyl] 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C16H21N3O3S
    [(1R,3S)-3-methylcyclohexyl] 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— [(2S)-butan-2-yl] (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C14H19N3O3S
    [(2S)-butan-2-yl] (2R)-2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— 2-[(5-cyano-4-ethyl-6-oxo-1,6-dihydro-2-pyrimidinyl)sulfanyl]-N,N-diethylacetamide —— C13H18N4O2S
    2-[(5-cyano-4-ethyl-6-oxo-1,6-dihydro-2-pyrimidinyl)sulfanyl]-N,N-diethylacetamide
    —— 2-(cyanomethylsulfanyl)-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile —— C9H8N4OS
    2-(cyanomethylsulfanyl)-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 6-ethyl-4-oxo-2-propylsulfanyl-1H-pyrimidine-5-carbonitrile —— C10H13N3OS
    6-ethyl-4-oxo-2-propylsulfanyl-1H-pyrimidine-5-carbonitrile
    —— cyclopentyl 2-[(5-cyano-6-ethyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C14H17N3O3S
    cyclopentyl 2-[(5-cyano-6-ethyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— 4-ethyl-2-[(3-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile —— C15H15N3OS
    4-ethyl-2-[(3-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 4-ethyl-2-[(4-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile —— C15H15N3OS
    4-ethyl-2-[(4-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C9H10N4O2S
    2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 5-[(1R)-1-[(5-tert-butyl-1,3-oxazol-2-yl)sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole —— C13H19N3O2S
    5-[(1R)-1-[(5-tert-butyl-1,3-oxazol-2-yl)sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole
    —— 4-ethyl-2-[(2-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile —— C15H15N3OS
    4-ethyl-2-[(2-methylphenyl)methylsulfanyl]-6-oxo-1H-pyrimidine-5-carbonitrile
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-3-ylmethanimine —— C15H12ClN5S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-3-ylmethanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine —— C17H15ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine
    —— 2-[(5-cyano-6-ethyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide —— C13H18N4O2S
    2-[(5-cyano-6-ethyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide
    —— 5-chloro-2-[(5-ethyl-1H-imidazol-2-yl)sulfanyl]pyrimidine —— C9H9ClN4S
    5-chloro-2-[(5-ethyl-1H-imidazol-2-yl)sulfanyl]pyrimidine
    —— 4-Ethyl-6-oxo-2-(pentylsulfanyl)-1,6-dihydro-5-pyrimidinecarbonitrile —— C12H17N3OS
    4-Ethyl-6-oxo-2-(pentylsulfanyl)-1,6-dihydro-5-pyrimidinecarbonitrile
    —— 5-[(1S)-1-[(5-tert-butyl-1,3-oxazol-2-yl)sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole —— C13H19N3O2S
    5-[(1S)-1-[(5-tert-butyl-1,3-oxazol-2-yl)sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole
    —— methyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C10H11N3O3S
    methyl 2-[(5-cyano-4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— (Z)-1-(2-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12BrClN4S
    (Z)-1-(2-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(4-bromophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12BrClN4S
    (Z)-1-(4-bromophenyl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 4-[(Z)-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline —— C18H18ClN5S
    4-[(Z)-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline
    —— (2S)-3-(2,5,6-trimethylpyrimidin-4-yl)sulfanylpropane-1,2-diol —— C10H16N2O2S
    (2S)-3-(2,5,6-trimethylpyrimidin-4-yl)sulfanylpropane-1,2-diol
    —— (Z)-1-(4-chlorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12Cl2N4S
    (Z)-1-(4-chlorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 4-[(Z)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline —— C18H18ClN5S
    4-[(Z)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline
    —— 3-[(Z)-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol —— C16H13ClN4OS
    3-[(Z)-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol