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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(phenylmethoxymethyl)-5H-thiochromeno[2,3-d]pyrimidine-2,4-dione —— C19H16N2O3S
    1-(phenylmethoxymethyl)-5H-thiochromeno[2,3-d]pyrimidine-2,4-dione
    —— 3-[2-[2-(2,3-Dihydroxypropylsulfanyl)ethylsulfonyl]ethylsulfanyl]propane-1,2-diol —— C10H22O6S3
    3-[2-[2-(2,3-Dihydroxypropylsulfanyl)ethylsulfonyl]ethylsulfanyl]propane-1,2-diol
    —— 4-[2-[2-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]ethoxy]ethylsulfanyl]phenol —— C14H17NO2S3
    4-[2-[2-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]ethoxy]ethylsulfanyl]phenol
    —— 5-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine —— C16H16N4S2
    5-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine
    —— 5-Amino-2-(2,3-dichlorophenyl)sulfanylphenol;hydrochloride —— C12H10Cl3NOS
    5-Amino-2-(2,3-dichlorophenyl)sulfanylphenol;hydrochloride
    —— 5-Amino-2-(2,3-dichlorophenyl)sulfanylphenol —— C12H9Cl2NOS
    5-Amino-2-(2,3-dichlorophenyl)sulfanylphenol
    —— 2-(1-Benzyltetrazol-5-yl)sulfanyl-5-nitro-1,3-thiazole —— C11H8N6O2S2
    2-(1-Benzyltetrazol-5-yl)sulfanyl-5-nitro-1,3-thiazole
    —— 3-Chloro-4-[2-chloro-4-(dimethylamino)phenyl]sulfanylaniline —— C14H14Cl2N2S
    3-Chloro-4-[2-chloro-4-(dimethylamino)phenyl]sulfanylaniline
    —— 6,6-Dimethyl-1-(2-methyltetrazol-5-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one —— C13H16N4OS2
    6,6-Dimethyl-1-(2-methyltetrazol-5-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— 3-(4-methyl-anilino)-5-(2-methyl-benzylthio)-1,2,4-triazole 334538-94-2 C17H18N4S
    3-(4-methyl-anilino)-5-(2-methyl-benzylthio)-1,2,4-triazole
    —— N-tert-butyl-1-[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methanimine oxide —— C16H19NO3S
    N-tert-butyl-1-[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methanimine oxide
    —— (3Z)-3-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-9-oxo-1,2-dihydropyrrolo[2,1-b]quinazoline-6-carboxylic acid —— C26H19N3O5S
    (3Z)-3-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-9-oxo-1,2-dihydropyrrolo[2,1-b]quinazoline-6-carboxylic acid
    —— (2Z)-2-cyano-2-[(5Z)-3-(3-methoxypropyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-N-(2-morpholin-4-ylethyl)acetamide —— C24H30N4O4S2
    (2Z)-2-cyano-2-[(5Z)-3-(3-methoxypropyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-N-(2-morpholin-4-ylethyl)acetamide
    —— 8-Benzyl-5-methyl-2,3-dihydropyridazino[4,5-b][1,4]thiazepine-4,9-dione —— C15H15N3O2S
    8-Benzyl-5-methyl-2,3-dihydropyridazino[4,5-b][1,4]thiazepine-4,9-dione
    —— N-(cyanomethyl)-3-(2-methylpropylsulfonyl)-2-(2-methylpropylsulfonylmethyl)propanamide —— C14H26N2O5S2
    N-(cyanomethyl)-3-(2-methylpropylsulfonyl)-2-(2-methylpropylsulfonylmethyl)propanamide
    —— N-[2-[[4-(2-anilinopyrimidin-4-yl)-5-methyl-1,2-oxazol-3-yl]sulfanyl]ethyl]acetamide —— C18H19N5O2S
    N-[2-[[4-(2-anilinopyrimidin-4-yl)-5-methyl-1,2-oxazol-3-yl]sulfanyl]ethyl]acetamide
    —— 3-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-5-(trifluoromethyl)pyridine-2-carbonitrile —— C17H16F3N3OS
    3-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-5-(trifluoromethyl)pyridine-2-carbonitrile
    —— N,N-dimethyl-4-[[3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-yl]methyl]aniline —— C16H18N4S2
    N,N-dimethyl-4-[[3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-yl]methyl]aniline
    —— 5-[(2-methylphenyl)methyl]-3-[(5-methylthiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazole —— C16H17N3S2
    5-[(2-methylphenyl)methyl]-3-[(5-methylthiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazole
    —— Ethyl 2-[4-(4-propan-2-yloxypyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate —— C14H18N4O3S
    Ethyl 2-[4-(4-propan-2-yloxypyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate
    —— 7-(6,6-Dimethyl-7-oxoheptyl)sulfinyl-2,2-dimethylheptanal —— C18H34O3S
    7-(6,6-Dimethyl-7-oxoheptyl)sulfinyl-2,2-dimethylheptanal
    —— 5-fluoro-6-methyl-2-[(1R)-3-(methylamino)-1-phenylpropyl]sulfanylpyridine-3-carbonitrile —— C17H18FN3S
    5-fluoro-6-methyl-2-[(1R)-3-(methylamino)-1-phenylpropyl]sulfanylpyridine-3-carbonitrile
    —— 5-[(4-chlorophenyl)methyl]-3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazole —— C14H12ClN3S2
    5-[(4-chlorophenyl)methyl]-3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazole
    —— Ethyl 2-[4-(4-chloro-3,5-dimethylpyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate —— C13H15ClN4O2S
    Ethyl 2-[4-(4-chloro-3,5-dimethylpyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate
    —— 2-Chloroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate —— C11H11ClN4O2S
    2-Chloroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate
    —— 3-[(4-fluorophenyl)methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole —— C14H12FN3S2
    3-[(4-fluorophenyl)methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole
    —— N-hydroxy-N'-(5-methylsulfanyl-4-propan-2-ylsulfonylthiophen-3-yl)methanimidamide —— C9H14N2O3S3
    N-hydroxy-N'-(5-methylsulfanyl-4-propan-2-ylsulfonylthiophen-3-yl)methanimidamide
    —— 1-[2-(3-methylphenylsulfanyl)phenyl][1,4]-diazepane —— C18H22N2S
    1-[2-(3-methylphenylsulfanyl)phenyl][1,4]-diazepane
    —— (5S,6S)-6-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C13H21N3S2
    (5S,6S)-6-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— exo-6-(3-(2-methoxyethylthio)-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C12H19N3OS2
    exo-6-(3-(2-methoxyethylthio)-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— 4-chloro-6-(2-fluorophenylamino)-2-methylsulfanylpyrimidine-5-carbaldehyde 444605-17-8 C12H9ClFN3OS
    4-chloro-6-(2-fluorophenylamino)-2-methylsulfanylpyrimidine-5-carbaldehyde
    —— 4-Methylsulfanyl-10,11,12,13,14,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,12,14-heptaen-8-one —— C11H6N6OS
    4-Methylsulfanyl-10,11,12,13,14,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,12,14-heptaen-8-one
    —— N-[2-[(5E)-5-benzylidene-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-3-(4-fluorophenyl)sulfanylpropanamide —— C21H19FN2O3S2
    N-[2-[(5E)-5-benzylidene-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-3-(4-fluorophenyl)sulfanylpropanamide
    —— 1-(2-hydroxyethyl)-3-[(1R,3S)-3-methylcyclohexyl]thiourea —— C10H20N2OS
    1-(2-hydroxyethyl)-3-[(1R,3S)-3-methylcyclohexyl]thiourea
    —— (5R,7S)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H21BrF3N5O3S
    (5R,7S)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— 1-Ethylsulfanylethanamine —— C4H11NS
    1-Ethylsulfanylethanamine
    —— (5R,7R)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H21BrF3N5O3S
    (5R,7R)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— (5S,7S)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H21BrF3N5O3S
    (5S,7S)-N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— 4-[(Z)-[3-[(E)-[(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidenehydrazinylidene]methyl]-2-morpholin-4-ylcyclopent-2-en-1-ylidene]methyl]-N,N-diethylaniline —— C33H36F2N4O2S
    4-[(Z)-[3-[(E)-[(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidenehydrazinylidene]methyl]-2-morpholin-4-ylcyclopent-2-en-1-ylidene]methyl]-N,N-diethylaniline
    —— 4-[(Z)-[3-[(Z)-[(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidenehydrazinylidene]methyl]-2-morpholin-4-ylcyclopent-2-en-1-ylidene]methyl]-N,N-diethylaniline —— C33H36F2N4O2S
    4-[(Z)-[3-[(Z)-[(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidenehydrazinylidene]methyl]-2-morpholin-4-ylcyclopent-2-en-1-ylidene]methyl]-N,N-diethylaniline
    —— N-[(Z)-(2,4-dichlorophenyl)methylideneamino]-6-(2-nitrophenyl)sulfanyl-5-phenylthieno[2,3-d]pyrimidin-4-amine —— C25H15Cl2N5O2S2
    N-[(Z)-(2,4-dichlorophenyl)methylideneamino]-6-(2-nitrophenyl)sulfanyl-5-phenylthieno[2,3-d]pyrimidin-4-amine
    —— N-ethyl-6-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-phenylpyridine-3-sulfonamide —— C24H25N5O3S3
    N-ethyl-6-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-phenylpyridine-3-sulfonamide
    —— (2E)-2-cyano-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C25H22N6O5S2
    (2E)-2-cyano-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— [(4S)-4-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]-6-methyl-2-sulfanylidene-3,4-dihydro-1H-pyrimidin-5-yl]-morpholin-4-ylmethanone —— C23H21N5O4S3
    [(4S)-4-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]-6-methyl-2-sulfanylidene-3,4-dihydro-1H-pyrimidin-5-yl]-morpholin-4-ylmethanone
    —— butyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate;dichloromanganese —— C27H45Cl2MnN5O2S
    butyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate;dichloromanganese
    —— N-ethyl-6-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-phenylpyridine-3-sulfonamide —— C24H25N5O3S3
    N-ethyl-6-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-phenylpyridine-3-sulfonamide
    —— (2E)-2-cyano-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C25H22N6O5S2
    (2E)-2-cyano-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— (4R,9R,14R,19R)-24-cyclohexylsulfanyl-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-triene —— C27H45N5S
    (4R,9R,14R,19R)-24-cyclohexylsulfanyl-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-triene
    —— [(4R)-4-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]-6-methyl-2-sulfanylidene-3,4-dihydro-1H-pyrimidin-5-yl]-morpholin-4-ylmethanone —— C23H21N5O4S3
    [(4R)-4-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]-6-methyl-2-sulfanylidene-3,4-dihydro-1H-pyrimidin-5-yl]-morpholin-4-ylmethanone
    —— (2E)-4,4-dimethyl-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-[[(2R)-oxolan-2-yl]methyl]-1,3-thiazolidin-2-ylidene]-3-oxopentanenitrile —— C26H25N5O5S2
    (2E)-4,4-dimethyl-2-[(5E)-5-[(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylidene]-4-oxo-3-[[(2R)-oxolan-2-yl]methyl]-1,3-thiazolidin-2-ylidene]-3-oxopentanenitrile