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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <2-Thienylmethyl>-2-imidazolyl-sulfid 89977-43-5 C8H8N2S2
    <2-Thienylmethyl>-2-imidazolyl-sulfid
    —— 2-(4-methoxyphenylthio)-5-methylphenol 1254831-66-7 C14H14O2S
    2-(4-methoxyphenylthio)-5-methylphenol
    —— Zn(thz)2Cl2 115380-83-1 C6H14Cl2N2S2Zn
    Zn(thz)2Cl2
    —— 2-Carboxy-4-methyl-2'-nitrodiphenylsulfid 58755-65-0 C14H11NO4S
    2-Carboxy-4-methyl-2'-nitrodiphenylsulfid
    —— 2-(1-hydroxy-cyclohexyl)-2-methyl-oxazolidine-3-carbothioic acid cyclohexylamide 31824-78-9 C17H30N2O2S
    2-(1-hydroxy-cyclohexyl)-2-methyl-oxazolidine-3-carbothioic acid cyclohexylamide
    —— [Ru(dimethylsulfoxide)6](2+) 82580-42-5 C12H36O6RuS6
    [Ru(dimethylsulfoxide)6](2+)
    —— 3-[3-chloro-4-(chloro-difluoro-methylsulfanyl)-phenyl]-6,7-dihydro-5<i>H</i>-cyclopenta[<i>e</i>][1,3]oxazine-2,4-dione 43066-67-7 C14H9Cl2F2NO3S
    3-[3-chloro-4-(chloro-difluoro-methylsulfanyl)-phenyl]-6,7-dihydro-5<i>H</i>-cyclopenta[<i>e</i>][1,3]oxazine-2,4-dione
    —— 2,5-Dimethyl-2-trifluoromethyl-4-acetyl-1,3-oxathiol 139571-78-1 C8H9F3O2S
    2,5-Dimethyl-2-trifluoromethyl-4-acetyl-1,3-oxathiol
    —— 1-(2-Methoxyethyl)-2-isopropylidene-1-methylcyclobutane 136296-88-3 C11H20O
    1-(2-Methoxyethyl)-2-isopropylidene-1-methylcyclobutane
    —— 1-(4-chlorophenylthio)-2,3,5,6-tetramethyl-4-oxocyclohexa-2,5-dienyl 2-chloroacetate 335642-18-7 C18H18Cl2O3S
    1-(4-chlorophenylthio)-2,3,5,6-tetramethyl-4-oxocyclohexa-2,5-dienyl 2-chloroacetate
    —— bromotellurium dithiobutyrate 97346-39-9 C4H7BrS2Te
    bromotellurium dithiobutyrate
    —— 2-Methyl-3-phenylmercapto-acrylsaeure-chlorid 1078-67-7 C10H9ClOS
    2-Methyl-3-phenylmercapto-acrylsaeure-chlorid
    —— 2-methyl-2-phenyl-4-oxo-2,3-dihydro-1,3-benzothiazine 93301-30-5 C15H13NOS
    2-methyl-2-phenyl-4-oxo-2,3-dihydro-1,3-benzothiazine
    —— 1-[6-[6-(6-Acetylpyrimidin-4-yl)-4-propylsulfanylpyridin-2-yl]pyrimidin-4-yl]ethanone 257957-61-2 C20H19N5O2S
    1-[6-[6-(6-Acetylpyrimidin-4-yl)-4-propylsulfanylpyridin-2-yl]pyrimidin-4-yl]ethanone
    —— 3-Chlor-1-thiocyanato-5,5-dimethyl-hexen-(2) 4003-62-7 C9H14ClNS
    3-Chlor-1-thiocyanato-5,5-dimethyl-hexen-(2)
    —— 2-(4-methylphenylthio)-5-nitrobenzenesulfonamide 91955-99-6 C13H12N2O4S2
    2-(4-methylphenylthio)-5-nitrobenzenesulfonamide
    —— 6-methyl-2-methylsulfanyl-5-pentyl-3<i>H</i>-pyrimidin-4-one 91120-08-0 C11H18N2OS
    6-methyl-2-methylsulfanyl-5-pentyl-3<i>H</i>-pyrimidin-4-one
    —— 8,11,20,23-Tetrathia-hexaspiro-<3.1.0.4.0.1.3.1.0.4.0.1>-tetracosan 425-00-3 C20H28S4
    8,11,20,23-Tetrathia-hexaspiro-<3.1.0.4.0.1.3.1.0.4.0.1>-tetracosan
    —— 21243-38-9 C18H24S8
    —— N-(2,5-Dichloro-4-phenylsulfanyl-phenyl)-C,C,C-trifluoro-methanesulfonamide 62676-97-5 C13H8Cl2F3NO2S2
    N-(2,5-Dichloro-4-phenylsulfanyl-phenyl)-C,C,C-trifluoro-methanesulfonamide
    —— 2-(3-ethyl-4-nitrophenylsulfide)benzoic acid 868157-67-9 C15H13NO4S
    2-(3-ethyl-4-nitrophenylsulfide)benzoic acid
    —— (Butylthio)diaethylsilan 59384-18-8 C8H20SSi
    (Butylthio)diaethylsilan
    —— 4-(4-chlorophenylsulfanyl)-2-p-tolylquinazoline 1382529-53-4 C21H15ClN2S
    4-(4-chlorophenylsulfanyl)-2-p-tolylquinazoline
    —— 1-Chloro-2,4-dinitro-5-m-tolylsulfanyl-benzene 14723-64-9 C13H9ClN2O4S
    1-Chloro-2,4-dinitro-5-m-tolylsulfanyl-benzene
    —— 2-Aethylmercapto-5-(2-brom-aethyl)-thiophen 90002-71-4 C8H11BrS2
    2-Aethylmercapto-5-(2-brom-aethyl)-thiophen
    —— 4-Brom-2-methyl-phenyl-β,β-dimethoxyethylsulfid 19075-65-1 C11H15BrO2S
    4-Brom-2-methyl-phenyl-β,β-dimethoxyethylsulfid
    —— 4,5-Bis-<2-acetylaminophenylmercapto>-2H-pyridazinon-(3) 20552-36-7 C20H18N4O3S2
    4,5-Bis-<2-acetylaminophenylmercapto>-2H-pyridazinon-(3)
    —— 5-Phenylthio-2-methyl-4-brom-3(2H)-pyridazinon 22687-68-9 C11H9BrN2OS
    5-Phenylthio-2-methyl-4-brom-3(2H)-pyridazinon
    —— 4-(Chloromethylsulfanyl)-5-methylsulfanyl-1,3-dithiole-2-thione 1344677-89-9 C5H5ClS5
    4-(Chloromethylsulfanyl)-5-methylsulfanyl-1,3-dithiole-2-thione
    —— 2-(2,4-difluorophenyl)-1-(4-(((5-(4-pentylphenyl)-1,3,4-oxadiazol-2-yl)thio)methyl)-1H-1,2,3-triazol-1-yl)-3-(1H-1,2,4-triazol-1-yl)propan-2-ol 1452784-02-9 C27H28F2N8O2S
    2-(2,4-difluorophenyl)-1-(4-(((5-(4-pentylphenyl)-1,3,4-oxadiazol-2-yl)thio)methyl)-1H-1,2,3-triazol-1-yl)-3-(1H-1,2,4-triazol-1-yl)propan-2-ol
    —— Phenylsulfanyl-acetic acid (E)-7-chloro-1-methyl-hept-5-enyl ester 69008-89-5 C16H21ClO2S
    Phenylsulfanyl-acetic acid (E)-7-chloro-1-methyl-hept-5-enyl ester
    —— Tris-(o-tolylmercapto)-methan 34636-78-7 C22H22S3
    Tris-(o-tolylmercapto)-methan
    —— 1-(4-Methylsulfanyl-phenyl)-cyclobutanol 29480-07-7 C11H14OS
    1-(4-Methylsulfanyl-phenyl)-cyclobutanol
    —— Tert-butyl-dimethyl-(1-pyridin-2-ylsulfanylbut-1-enoxy)silane 152899-68-8 C15H25NOSSi
    Tert-butyl-dimethyl-(1-pyridin-2-ylsulfanylbut-1-enoxy)silane
    —— 5,6:11,12:17,18-tribenzo-2,3-bis(hydroxyimino)-7,16-dithia-10,13-dioxa-1,4-diaza-cyclooctadecane 350794-81-9 C24H24N4O4S2
    5,6:11,12:17,18-tribenzo-2,3-bis(hydroxyimino)-7,16-dithia-10,13-dioxa-1,4-diaza-cyclooctadecane
    —— 2-isobutanoyl-3-(phenylthio)-1,3-butadiene 125628-82-2 C14H16OS
    2-isobutanoyl-3-(phenylthio)-1,3-butadiene
    —— 1240038-50-9 C19H16Br2N2S2
    —— tert-butyl (6-(5-thiocyanatothiazol-2-ylamino)pyridin-3-yl)methylcarbamate 1034919-84-0 C15H17N5O2S2
    tert-butyl (6-(5-thiocyanatothiazol-2-ylamino)pyridin-3-yl)methylcarbamate
    —— 1,1-bis(2-methylphenylthio)-3,4,4-trichloro-2-nitro-1,3-butadiene 1393474-43-5 C18H14Cl3NO2S2
    1,1-bis(2-methylphenylthio)-3,4,4-trichloro-2-nitro-1,3-butadiene
    —— 1240038-32-7 C18H13BrCl2N2S2
    —— <1,2,2-Trichlor-vinyl>-<4-brom-phenyl>-sulfid 14703-97-0 C8H4BrCl3S
    <1,2,2-Trichlor-vinyl>-<4-brom-phenyl>-sulfid
    —— (Z)-1-Bromo-2-phenylsulfanyl-cyclooctene 85895-16-5 C14H17BrS
    (Z)-1-Bromo-2-phenylsulfanyl-cyclooctene
    —— (Z)-2-Butylsulfanyl-oct-2-ene 133878-67-8 C12H24S
    (Z)-2-Butylsulfanyl-oct-2-ene
    —— 4-(3-chlorophenyl)sulfanyl-5,6,7,8-tetrahydro-2H-isoquinolin-1-one 1357188-69-2 C15H14ClNOS
    4-(3-chlorophenyl)sulfanyl-5,6,7,8-tetrahydro-2H-isoquinolin-1-one
    —— (2R,3S)-2-Ethyl-3-((S)-1-phenyl-ethylamino)-5-trimethylsilanyl-pent-4-ynethioic acid S-phenyl ester 109279-70-1 C24H31NOSSi
    (2R,3S)-2-Ethyl-3-((S)-1-phenyl-ethylamino)-5-trimethylsilanyl-pent-4-ynethioic acid S-phenyl ester
    —— ethyl 3-[4-(3-methoxyphenyl)sulfanylphenyl]propanoate 509088-85-1 C18H20O3S
    ethyl 3-[4-(3-methoxyphenyl)sulfanylphenyl]propanoate
    —— S-(2-octen-1-yl) O-ethyl dithiocarbonate 73872-30-7 C11H20OS2
    S-(2-octen-1-yl) O-ethyl dithiocarbonate
    —— μ-N2H2{Fe(PEt2Ph)(1,2-bis(2-mercaptophenylthio)ethane(2-))}2 867059-52-7 C48H56Fe2N2P2S8
    μ-N2H2{Fe(PEt2Ph)(1,2-bis(2-mercaptophenylthio)ethane(2-))}2
    —— 2-(2-chloro-4-fluorophenyl-sulfanyl)-1-(4-cyclohexyl-piperazin-1-yl)ethanone 485796-23-4 C18H24ClFN2OS
    2-(2-chloro-4-fluorophenyl-sulfanyl)-1-(4-cyclohexyl-piperazin-1-yl)ethanone
    —— 2-Methyl-2-(methylsulfinyl)non-3-yne 136022-22-5 C11H20OS
    2-Methyl-2-(methylsulfinyl)non-3-yne