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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Tert-butyl-2,3-dihydropyrido[1,2-b][1,4,2]oxathiazin-5-ium —— C11H16NOS+
    2-Tert-butyl-2,3-dihydropyrido[1,2-b][1,4,2]oxathiazin-5-ium
    —— 3-(2-Methoxyethyl)-5-{(E)-1-[4-(methylsulfanyl)phenyl]methylidene}-2-(phenylimino)-1,3-thiazolan-4-one —— C20H20N2O2S2
    3-(2-Methoxyethyl)-5-{(E)-1-[4-(methylsulfanyl)phenyl]methylidene}-2-(phenylimino)-1,3-thiazolan-4-one
    —— 2-methoxyethyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H26N2O4S2
    2-methoxyethyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (Z)-[(3Z)-3-hydrazinylidene-1,4-bis(methylsulfonyl)butan-2-ylidene]hydrazine —— C6H14N4O4S2
    (Z)-[(3Z)-3-hydrazinylidene-1,4-bis(methylsulfonyl)butan-2-ylidene]hydrazine
    —— (Z)-2-[(E)-1-cyano-2-methoxyethenyl]sulfonyl-3-methoxyprop-2-enenitrile —— C8H8N2O4S
    (Z)-2-[(E)-1-cyano-2-methoxyethenyl]sulfonyl-3-methoxyprop-2-enenitrile
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C19H17FN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— 9-methyl-3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C27H29N3O2S3
    9-methyl-3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C22H20N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H17BrN4OS
    N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (5E)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C12H11NOS3
    (5E)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— N-(3-methoxypropyl)-N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanediamide —— C15H21N3O3S
    N-(3-methoxypropyl)-N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanediamide
    —— (4E)-5-methyl-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-phenylpyrazol-3-one —— C22H18N2O2S
    (4E)-5-methyl-4-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-phenylpyrazol-3-one
    —— propan-2-yl (2E)-5-(4-chlorophenyl)-2-[[5-(4,6-dimethylpyrimidin-2-yl)sulfanylfuran-2-yl]methylidene]-7-methyl-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C28H25ClN4O4S2
    propan-2-yl (2E)-5-(4-chlorophenyl)-2-[[5-(4,6-dimethylpyrimidin-2-yl)sulfanylfuran-2-yl]methylidene]-7-methyl-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1-(Propylsulfinyl)-3-(2-propenylsulfinyl)propene —— C9H16O2S2
    1-(Propylsulfinyl)-3-(2-propenylsulfinyl)propene
    —— (5S,7R)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H23ClF2N4OS
    (5S,7R)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— 2-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-1-[(1R,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C21H24F3N3O2S
    2-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-1-[(1R,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— (5S,7S)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H23ClF2N4OS
    (5S,7S)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— Sodium;1-tridecoxypropane-1-sulfonoperoxoic acid —— C16H34NaO5S+
    Sodium;1-tridecoxypropane-1-sulfonoperoxoic acid
    —— (5R,7R)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H23ClF2N4OS
    (5R,7R)-N-[2-(4-chlorophenyl)sulfanylphenyl]-7-(difluoromethyl)-5-(4-methylphenyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— (2E)-2-[[(5-bromopyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one —— C14H9BrN2OS
    (2E)-2-[[(5-bromopyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one
    —— Diaminomethylidene-[(4-methylsulfanylphenyl)methyl]azanium —— C9H14N3S+
    Diaminomethylidene-[(4-methylsulfanylphenyl)methyl]azanium
    —— (4S,8Z)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile —— C25H25N3OS2
    (4S,8Z)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-phenylethylidene]acetohydrazide —— C19H18N4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-phenylethylidene]acetohydrazide
    —— [1-Amino-2-(2-phenylsulfanylphenyl)ethylidene]azanium —— C14H15N2S+
    [1-Amino-2-(2-phenylsulfanylphenyl)ethylidene]azanium
    —— 1-(4-Chloro-phenylsulfanyl)-4-pyridin-4-ylmethyl-phthalazine —— C20H14ClN3S
    1-(4-Chloro-phenylsulfanyl)-4-pyridin-4-ylmethyl-phthalazine
    —— (18R,19R)-hexatriacontane-1,18,19,36-tetrathiol —— C36H74S4
    (18R,19R)-hexatriacontane-1,18,19,36-tetrathiol
    —— 3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(prop-2-en-1-yl)-5H-[1,2,4]triazino[5,6-b]indole —— C18H11N7O2S2
    3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(prop-2-en-1-yl)-5H-[1,2,4]triazino[5,6-b]indole
    —— (10S,11S)-icosane-10,11-dithiol —— C20H42S2
    (10S,11S)-icosane-10,11-dithiol
    —— 3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-propyl-5H-[1,2,4]triazino[5,6-b]indole —— C18H13N7O2S2
    3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-propyl-5H-[1,2,4]triazino[5,6-b]indole
    —— (10R,11R)-icosane-10,11-dithiol —— C20H42S2
    (10R,11R)-icosane-10,11-dithiol
    —— (9S,10S)-octadecane-9,10-dithiol —— C18H38S2
    (9S,10S)-octadecane-9,10-dithiol
    —— (18S,19S)-hexatriacontane-1,18,19,36-tetrathiol —— C36H74S4
    (18S,19S)-hexatriacontane-1,18,19,36-tetrathiol
    —— (9S,10R)-octadecane-9,10-dithiol —— C18H38S2
    (9S,10R)-octadecane-9,10-dithiol
    —— (9R,10R)-octadecane-9,10-dithiol —— C18H38S2
    (9R,10R)-octadecane-9,10-dithiol
    —— (3S)-2-imino-4-oxothiolane-3-carboxylic acid —— C5H5NO3S
    (3S)-2-imino-4-oxothiolane-3-carboxylic acid
    —— (3S,6S)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-1-carboxamide —— C17H28N2OS
    (3S,6S)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-1-carboxamide
    —— (3R,5R)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide —— C16H26N2OS
    (3R,5R)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide
    —— (3S,5S)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide —— C16H26N2OS
    (3S,5S)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide
    —— (1R,8R)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-3-carboxamide —— C17H28N2OS
    (1R,8R)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-3-carboxamide
    —— (5R,7R)-3-chloro-N-methyladamantane-1-carbothioamide —— C12H18ClNS
    (5R,7R)-3-chloro-N-methyladamantane-1-carbothioamide
    —— [(2S)-3,3,4,4,4-pentafluoro-2-[(2S)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene —— C20H16F10S
    [(2S)-3,3,4,4,4-pentafluoro-2-[(2S)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C20H19N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— [(2R)-3,3,4,4,4-pentafluoro-2-[(2R)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene —— C20H16F10S
    [(2R)-3,3,4,4,4-pentafluoro-2-[(2R)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene
    —— 4-(4-Methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylbutan-2-one —— C13H19N3O2S
    4-(4-Methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylbutan-2-one
    —— (1R)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid —— C6H7NO3S
    (1R)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid
    —— 6-[[6-[(3-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine —— C29H20N8O2S2
    6-[[6-[(3-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine
    —— ethyl (2Z)-2-(cyclohex-3-en-1-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H26N2O3S2
    ethyl (2Z)-2-(cyclohex-3-en-1-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (3R,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide —— C18H29NS
    (3R,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide
    —— N-(3-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C27H18N6O5S3
    N-(3-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— 6-[[6-[(4-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine —— C29H20N8O2S2
    6-[[6-[(4-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine