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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-cyclohexyl-4-[(Z)-(2,4-dimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C19H23N4O2S-
    2-[[5-cyclohexyl-4-[(Z)-(2,4-dimethylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-[(Z)-benzylideneamino]-5-cyclohexyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H19N4O2S-
    2-[[4-[(Z)-benzylideneamino]-5-cyclohexyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[5-cyclohexyl-4-[(Z)-(4-methylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C18H21N4O2S-
    2-[[5-cyclohexyl-4-[(Z)-(4-methylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N,N-diethyl-4-[(6R)-3-methylsulfanyl-5,6-dihydro-[1,2,4]triazino[5,6-d][1,3]benzoxazepin-6-yl]aniline —— C21H23N5OS
    N,N-diethyl-4-[(6R)-3-methylsulfanyl-5,6-dihydro-[1,2,4]triazino[5,6-d][1,3]benzoxazepin-6-yl]aniline
    —— methyl (2Z,7R)-5-amino-6-cyano-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate —— C25H21N3O3S3
    methyl (2Z,7R)-5-amino-6-cyano-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate
    —— methyl (2Z,7S)-5-amino-6-cyano-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate —— C25H21N3O3S3
    methyl (2Z,7S)-5-amino-6-cyano-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate
    —— N,N-diethyl-4-[(6S)-3-methylsulfanyl-5,6-dihydro-[1,2,4]triazino[5,6-d][1,3]benzoxazepin-6-yl]aniline —— C21H23N5OS
    N,N-diethyl-4-[(6S)-3-methylsulfanyl-5,6-dihydro-[1,2,4]triazino[5,6-d][1,3]benzoxazepin-6-yl]aniline
    —— tert-butyl (5S)-5-hydroxy-5-(3-methyl-2-phenylsulfanylimidazol-4-yl)-3-oxopentanoate —— C19H24N2O4S
    tert-butyl (5S)-5-hydroxy-5-(3-methyl-2-phenylsulfanylimidazol-4-yl)-3-oxopentanoate
    —— (3R,3aS,7Z)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine —— C23H27N3S2
    (3R,3aS,7Z)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine
    —— N-[(S)-(4-bromophenyl)-(1-methyltetrazol-5-yl)sulfanylmethyl]-5-chloropyridin-2-amine —— C14H12BrClN6S
    N-[(S)-(4-bromophenyl)-(1-methyltetrazol-5-yl)sulfanylmethyl]-5-chloropyridin-2-amine
    —— N-[(R)-(4-bromophenyl)-(1-methyltetrazol-5-yl)sulfanylmethyl]-5-chloropyridin-2-amine —— C14H12BrClN6S
    N-[(R)-(4-bromophenyl)-(1-methyltetrazol-5-yl)sulfanylmethyl]-5-chloropyridin-2-amine
    —— (3R,3aR,7Z)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine —— C23H27N3S2
    (3R,3aR,7Z)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine
    —— (2R)-1-(4-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2R)-1-(4-methylsulfanylphenyl)butan-2-ol
    —— (2R)-1-(2-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2R)-1-(2-methylsulfanylphenyl)butan-2-ol
    —— N-[2-[(5E)-2,4-dioxo-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-3-yl]ethyl]-4-phenylsulfanylbutanamide —— C21H21N3O3S2
    N-[2-[(5E)-2,4-dioxo-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-3-yl]ethyl]-4-phenylsulfanylbutanamide
    —— (2R)-1-(3-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2R)-1-(3-methylsulfanylphenyl)butan-2-ol
    —— (2S)-1-(4-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2S)-1-(4-methylsulfanylphenyl)butan-2-ol
    —— (2S)-1-(4-ethylsulfanylphenyl)butan-2-ol —— C12H18OS
    (2S)-1-(4-ethylsulfanylphenyl)butan-2-ol
    —— (2S)-1-(2-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2S)-1-(2-methylsulfanylphenyl)butan-2-ol
    —— (2S)-1-(3-methylsulfanylphenyl)butan-2-ol —— C11H16OS
    (2S)-1-(3-methylsulfanylphenyl)butan-2-ol
    —— (1S)-1-cyclopropyl-1-(4-ethylsulfanylphenyl)ethanol —— C13H18OS
    (1S)-1-cyclopropyl-1-(4-ethylsulfanylphenyl)ethanol
    —— (1R)-1-cyclopropyl-1-(3-methylsulfanylphenyl)ethanol —— C12H16OS
    (1R)-1-cyclopropyl-1-(3-methylsulfanylphenyl)ethanol
    —— (1R)-1-cyclopropyl-1-(2-methylsulfanylphenyl)ethanol —— C12H16OS
    (1R)-1-cyclopropyl-1-(2-methylsulfanylphenyl)ethanol
    —— (1S)-1-cyclopropyl-1-(2-methylsulfanylphenyl)ethanol —— C12H16OS
    (1S)-1-cyclopropyl-1-(2-methylsulfanylphenyl)ethanol
    —— (1S)-1-cyclopropyl-1-(4-methylsulfanylphenyl)ethanol —— C12H16OS
    (1S)-1-cyclopropyl-1-(4-methylsulfanylphenyl)ethanol
    —— (1R)-1-cyclopropyl-1-(4-methylsulfanylphenyl)ethanol —— C12H16OS
    (1R)-1-cyclopropyl-1-(4-methylsulfanylphenyl)ethanol
    —— (1R)-1-cyclopropyl-1-(4-ethylsulfanylphenyl)ethanol —— C13H18OS
    (1R)-1-cyclopropyl-1-(4-ethylsulfanylphenyl)ethanol
    —— (Z)-N-methyl-3-(5-methylfuran-2-yl)-N-[(4-methylsulfanylphenyl)methyl]prop-2-enamide —— C17H19NO2S
    (Z)-N-methyl-3-(5-methylfuran-2-yl)-N-[(4-methylsulfanylphenyl)methyl]prop-2-enamide
    —— (Z)-N-[5-chloro-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-thiophen-2-ylprop-2-enamide —— C16H13ClN4OS2
    (Z)-N-[5-chloro-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-thiophen-2-ylprop-2-enamide
    —— [(1S,2R,4R)-2-methyl-4-methylsulfonylcyclopentyl]methanamine —— C8H17NO2S
    [(1S,2R,4R)-2-methyl-4-methylsulfonylcyclopentyl]methanamine
    —— (1R,4S)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid —— C9H14O4S
    (1R,4S)-4-ethylsulfonyl-2-methylidenecyclopentane-1-carboxylic acid
    —— (1R,2S,4R)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile —— C10H17NO3S
    (1R,2S,4R)-1-ethylsulfonyl-4-(hydroxymethyl)-2-methylcyclopentane-1-carbonitrile
    —— ethyl (1S,2S,4R)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate —— C11H17NO4S
    ethyl (1S,2S,4R)-1-cyano-2-methyl-4-methylsulfonylcyclopentane-1-carboxylate
    —— (3S)-3-ethylsulfonyl-2,2-dimethyloxirane —— C6H12O3S
    (3S)-3-ethylsulfonyl-2,2-dimethyloxirane
    —— (1S,2R,4S)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H14O4S
    (1S,2R,4S)-2-methyl-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— (1R,4S)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H12O4S
    (1R,4S)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— [(1S,3R,4R)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine —— C9H20N2O2S
    [(1S,3R,4R)-3-(aminomethyl)-4-methyl-3-methylsulfonylcyclopentyl]methanamine
    —— (1R,2S,4S)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid —— C9H16O4S
    (1R,2S,4S)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid
    —— [1-(Ethylsulfonylmethyl)cyclobutyl]methanamine —— C8H17NO2S
    [1-(Ethylsulfonylmethyl)cyclobutyl]methanamine
    —— (1R,2R,4R)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid —— C9H16O4S
    (1R,2R,4R)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid
    —— (3S)-2,2-dimethyl-3-methylsulfonyloxirane —— C5H10O3S
    (3S)-2,2-dimethyl-3-methylsulfonyloxirane
    —— (3R)-2,2-dimethyl-3-methylsulfonyloxirane —— C5H10O3S
    (3R)-2,2-dimethyl-3-methylsulfonyloxirane
    —— (1S,2S,4S)-1-(methoxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile —— C10H17NO3S
    (1S,2S,4S)-1-(methoxymethyl)-2-methyl-4-methylsulfonylcyclopentane-1-carbonitrile
    —— (1S,4S)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H12O4S
    (1S,4S)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— (1R,4R)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid —— C8H12O4S
    (1R,4R)-2-methylidene-4-methylsulfonylcyclopentane-1-carboxylic acid
    —— [(1S,2S,4S)-2-methyl-4-methylsulfonylcyclopentyl]methanamine —— C8H17NO2S
    [(1S,2S,4S)-2-methyl-4-methylsulfonylcyclopentyl]methanamine
    —— ethyl (1R,2S,4S)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate —— C12H19NO4S
    ethyl (1R,2S,4S)-1-cyano-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylate
    —— [(1S,3S,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine —— C10H22N2O2S
    [(1S,3S,4S)-3-(aminomethyl)-3-ethylsulfonyl-4-methylcyclopentyl]methanamine
    —— (1R,2R,4S)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid —— C9H16O4S
    (1R,2R,4S)-4-ethylsulfonyl-2-methylcyclopentane-1-carboxylic acid
    —— [(1S,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine —— C11H23NO3S
    [(1S,2S,4R)-1-ethylsulfonyl-4-(methoxymethyl)-2-methylcyclopentyl]methanamine