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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C26H22N4O4S
    1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— 3-[5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C12H14FN3OS
    3-[5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine
    —— [5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium —— C10H11FN3OS+
    [5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium
    —— 2-Piperidin-4-yl-5-propylsulfanyl-1,3,4-oxadiazole —— C10H17N3OS
    2-Piperidin-4-yl-5-propylsulfanyl-1,3,4-oxadiazole
    —— (5-Ethylsulfanyl-1,3,4-oxadiazol-2-yl)methylazanium —— C5H10N3OS+
    (5-Ethylsulfanyl-1,3,4-oxadiazol-2-yl)methylazanium
    —— 2-[(2-Fluorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole —— C14H16FN3OS
    2-[(2-Fluorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole
    —— (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methylazanium —— C6H12N3OS+
    (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methylazanium
    —— 1,3,4-Oxadiazole-2-propanamine, 5-[[(4-chlorophenyl)methyl]thio]- 928000-65-1 C12H14ClN3OS
    1,3,4-Oxadiazole-2-propanamine, 5-[[(4-chlorophenyl)methyl]thio]-
    —— 3-[5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C12H14ClN3OS
    3-[5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine
    —— 4-(5-{[(2-Chlorophenyl)methyl]sulfanyl}-1,3,4-oxadiazol-2-YL)piperidine —— C14H16ClN3OS
    4-(5-{[(2-Chlorophenyl)methyl]sulfanyl}-1,3,4-oxadiazol-2-YL)piperidine
    —— 3-(5-Methylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium —— C6H12N3OS+
    3-(5-Methylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium
    —— 3-[5-[(2-Methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C13H18N3OS+
    3-[5-[(2-Methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— 3-[5-[(4-Methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C13H17N3OS
    3-[5-[(4-Methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine
    —— [5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine —— C10H10FN3OS
    [5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine
    —— 2-Ethylsulfanyl-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole —— C9H16N3OS+
    2-Ethylsulfanyl-5-piperidin-1-ium-4-yl-1,3,4-oxadiazole
    —— 3-[5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C12H15ClN3OS+
    3-[5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— 3-[5-[(3-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C12H15ClN3OS+
    3-[5-[(3-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— 3-[5-[(3-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine —— C12H14ClN3OS
    3-[5-[(3-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propan-1-amine
    —— [5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium —— C10H11ClN3OS+
    [5-[(2-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium
    —— [(1S,2S)-2-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium —— C10H20N3OS+
    [(1S,2S)-2-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium
    —— 2-[(3-Fluorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole —— C14H16FN3OS
    2-[(3-Fluorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole
    —— 2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C10H16N4O2S2
    2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— (3R)-1-(2,3-dihydropyrido[4,3-b][1,4]thiazin-4-yl)-3-(3,5-dimethyl-1,2-oxazol-4-yl)butan-1-one —— C16H19N3O2S
    (3R)-1-(2,3-dihydropyrido[4,3-b][1,4]thiazin-4-yl)-3-(3,5-dimethyl-1,2-oxazol-4-yl)butan-1-one
    —— 1-[2-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]piperidin-1-ium —— C18H31N4S+
    1-[2-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]piperidin-1-ium
    —— 4-methyl-6-[(2R,3R)-2-methyloxolan-3-yl]sulfanylpyrimidine —— C10H14N2OS
    4-methyl-6-[(2R,3R)-2-methyloxolan-3-yl]sulfanylpyrimidine
    —— 4-methyl-6-[(2S,3S)-2-methyloxolan-3-yl]sulfanylpyrimidine —— C10H14N2OS
    4-methyl-6-[(2S,3S)-2-methyloxolan-3-yl]sulfanylpyrimidine
    —— 4-methyl-6-[(2R,3S)-2-methyloxolan-3-yl]sulfanylpyrimidine —— C10H14N2OS
    4-methyl-6-[(2R,3S)-2-methyloxolan-3-yl]sulfanylpyrimidine
    —— 4-methyl-6-[(2S,3R)-2-methyloxolan-3-yl]sulfanylpyrimidine —— C10H14N2OS
    4-methyl-6-[(2S,3R)-2-methyloxolan-3-yl]sulfanylpyrimidine
    —— 1-[2-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]piperidine —— C18H30N4S
    1-[2-[(5-Cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]piperidine
    —— (1R,2S)-N-(2-chloroprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C10H18ClNO2S
    (1R,2S)-N-(2-chloroprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— (1S,2S)-N-(2-chloroprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C10H18ClNO2S
    (1S,2S)-N-(2-chloroprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— ethyl (Z)-3-[4-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]thiophen-2-yl]-2-cyanoprop-2-enoate —— C13H12N4O2S3
    ethyl (Z)-3-[4-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]thiophen-2-yl]-2-cyanoprop-2-enoate
    —— N-methyl-2-[1-[(2R)-4-phenylsulfanylbutan-2-yl]piperidin-4-yl]acetamide —— C18H28N2OS
    N-methyl-2-[1-[(2R)-4-phenylsulfanylbutan-2-yl]piperidin-4-yl]acetamide
    —— N-methyl-2-[1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-4-yl]acetamide —— C18H28N2OS
    N-methyl-2-[1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-4-yl]acetamide
    —— 1-[2,5-dimethyl-1-(1H-1,2,4-triazol-5-yl)pyrrol-3-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)ethanone —— C17H21N7OS
    1-[2,5-dimethyl-1-(1H-1,2,4-triazol-5-yl)pyrrol-3-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)ethanone
    —— (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C15H19FN4O2S
    (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— (Z)-2-cyano-3-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]prop-2-enethioamide —— C11H10N6S3
    (Z)-2-cyano-3-[4-[(1-methyltetrazol-5-yl)sulfanylmethyl]thiophen-2-yl]prop-2-enethioamide
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(3-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H13ClFNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(3-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— methyl (Z)-3-[4-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]thiophen-2-yl]-2-cyanoprop-2-enoate —— C12H10N4O2S3
    methyl (Z)-3-[4-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanylmethyl]thiophen-2-yl]-2-cyanoprop-2-enoate
    —— (6Z)-6-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C17H11ClN4O2S2
    (6Z)-6-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (5E)-3-benzyl-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H16ClNO2S3
    (5E)-3-benzyl-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (6E)-6-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-ethylsulfanyl-5-imino-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C19H15ClN4O2S3
    (6E)-6-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-ethylsulfanyl-5-imino-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(3,5-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H18ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(3,5-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H17NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 3-[2-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-oxoethyl]sulfanyl-4-amino-6-methyl-1,2,4-triazin-5-one —— C22H22N6O4S
    3-[2-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-oxoethyl]sulfanyl-4-amino-6-methyl-1,2,4-triazin-5-one
    —— (6E)-6-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-ethylsulfanyl-5-imino-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C19H16N4O2S3
    (6E)-6-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-ethylsulfanyl-5-imino-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— (4Z)-4-[[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methylidene]-1-phenylpyrazolidine-3,5-dione —— C21H16N2O4S
    (4Z)-4-[[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methylidene]-1-phenylpyrazolidine-3,5-dione
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2,6-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H18ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2,6-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2,4-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H18ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2,4-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3,5-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H19NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3,5-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one