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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R,3R)-3-ethoxy-N-methyl-N-(2-methylsulfonylethyl)spiro[3.4]octan-1-amine —— C14H27NO3S
    (1R,3R)-3-ethoxy-N-methyl-N-(2-methylsulfonylethyl)spiro[3.4]octan-1-amine
    —— (1R,3S)-3-ethoxy-N-methyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]spiro[3.4]octan-1-amine —— C15H25N3OS2
    (1R,3S)-3-ethoxy-N-methyl-N-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)methyl]spiro[3.4]octan-1-amine
    —— (1R,3S)-3-ethoxy-N-methyl-N-(2-methylsulfonylethyl)spiro[3.4]octan-1-amine —— C14H27NO3S
    (1R,3S)-3-ethoxy-N-methyl-N-(2-methylsulfonylethyl)spiro[3.4]octan-1-amine
    —— 2-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]pyridine-4-carbonitrile —— C14H15N3OS2
    2-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]pyridine-4-carbonitrile
    —— 2-[(1R)-1-ethoxyethyl]-4-(1,3-thiazol-2-ylsulfanylmethyl)-1,3-thiazole —— C11H14N2OS3
    2-[(1R)-1-ethoxyethyl]-4-(1,3-thiazol-2-ylsulfanylmethyl)-1,3-thiazole
    —— 4-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-2,6-dimethylpyrimidine-5-carbonitrile —— C15H18N4OS2
    4-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-2,6-dimethylpyrimidine-5-carbonitrile
    —— 1-[[(2R)-oxolan-2-yl]methyl]-5-[3-(1H-pyrazol-4-yl)propylsulfanyl]tetrazole —— C12H18N6OS
    1-[[(2R)-oxolan-2-yl]methyl]-5-[3-(1H-pyrazol-4-yl)propylsulfanyl]tetrazole
    —— 4-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-2,6-dimethylpyrimidine-5-carbonitrile —— C15H18N4OS2
    4-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-2,6-dimethylpyrimidine-5-carbonitrile
    —— 2-[(1S)-1-ethoxyethyl]-4-(1,3-thiazol-2-ylsulfanylmethyl)-1,3-thiazole —— C11H14N2OS3
    2-[(1S)-1-ethoxyethyl]-4-(1,3-thiazol-2-ylsulfanylmethyl)-1,3-thiazole
    —— 2-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]pyridine-4-carbonitrile —— C14H15N3OS2
    2-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]pyridine-4-carbonitrile
    —— 1-[2-(4-fluorophenyl)sulfanylethyl]-3-[(2S)-2-hydroxy-2-thiophen-3-ylethyl]urea —— C15H17FN2O2S2
    1-[2-(4-fluorophenyl)sulfanylethyl]-3-[(2S)-2-hydroxy-2-thiophen-3-ylethyl]urea
    —— 1-[(2S)-1-(3,5-dimethyl-1,2-oxazol-4-yl)propan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea —— C16H22N4O2S
    1-[(2S)-1-(3,5-dimethyl-1,2-oxazol-4-yl)propan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea
    —— 1-[(2R)-1-(3,5-dimethyl-1,2-oxazol-4-yl)propan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea —— C16H22N4O2S
    1-[(2R)-1-(3,5-dimethyl-1,2-oxazol-4-yl)propan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 2-[(1R)-cyclopent-2-en-1-yl]acetate —— C21H21NO3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 2-[(1R)-cyclopent-2-en-1-yl]acetate
    —— (2R)-N-cycloheptyl-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H28N4O2S2
    (2R)-N-cycloheptyl-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (2S)-2-(4-methylphenyl)sulfanylpropanoate —— C18H18N2O3S2
    [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (2S)-2-(4-methylphenyl)sulfanylpropanoate
    —— methyl N-[(2S)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C13H18N4O4S2
    methyl N-[(2S)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C18H21FN4O2S2
    (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (2R)-2-(4-methylphenyl)sulfanylpropanoate —— C18H18N2O3S2
    [(3S)-3-cyano-3-(4-methyl-1,3-thiazol-2-yl)-2-oxopropyl] (2R)-2-(4-methylphenyl)sulfanylpropanoate
    —— (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C19H24N4O2S2
    (2R)-2-[[5-[cyclopropyl(propanoyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— 2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C19H20FN5OS2
    2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 3-[(4-Fluorophenyl)methyl]-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C14H14FN5OS
    3-[(4-Fluorophenyl)methyl]-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (2S)-N-cycloheptyl-2-(2,5-difluorophenyl)sulfanylpropanamide —— C16H21F2NOS
    (2S)-N-cycloheptyl-2-(2,5-difluorophenyl)sulfanylpropanamide
    —— 2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C16H15ClN4OS3
    2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C17H18FN5OS2
    2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— (2R)-N-cycloheptyl-2-(2,5-difluorophenyl)sulfanylpropanamide —— C16H21F2NOS
    (2R)-N-cycloheptyl-2-(2,5-difluorophenyl)sulfanylpropanamide
    —— 2-[(1S)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C13H13N5OS
    2-[(1S)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— (2R)-2-(2,5-difluorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide —— C17H17F2NOS
    (2R)-2-(2,5-difluorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-2-(4-methyl-1,3-thiazol-2-yl)-4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-oxobutanenitrile —— C11H11N5OS2
    (2R)-2-(4-methyl-1,3-thiazol-2-yl)-4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-oxobutanenitrile
    —— (2S)-2-(2,5-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C13H15F2NO3S2
    (2S)-2-(2,5-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— [(2R)-1-amino-1-oxopropan-2-yl] (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C15H23NO3S2
    [(2R)-1-amino-1-oxopropan-2-yl] (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— (2S)-4-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile —— C13H13N5OS3
    (2S)-4-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile
    —— 2-[(1R)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C13H13N5OS
    2-[(1R)-1-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— [2-(cyclopropylamino)-2-oxoethyl] (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C17H25NO3S2
    [2-(cyclopropylamino)-2-oxoethyl] (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— N-(3-fluorophenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H14FN5OS2
    N-(3-fluorophenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-[(2,4-dimethylphenyl)methyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C20H21FN4OS2
    N-[(2,4-dimethylphenyl)methyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-1-(5-methylthiophen-2-yl)propan-2-yl]acetamide —— C16H21N3OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-1-(5-methylthiophen-2-yl)propan-2-yl]acetamide
    —— (2S)-1-[(2S)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H24N4O2S
    (2S)-1-[(2S)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2R)-1-[(2S)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H24N4O2S
    (2R)-1-[(2S)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— N-(3-fluorophenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C18H14FN5OS2
    N-(3-fluorophenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2R)-1-[(2R)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H24N4O2S
    (2R)-1-[(2R)-2-(5-methylfuran-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-1-(5-methylthiophen-2-yl)propan-2-yl]acetamide —— C16H21N3OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-1-(5-methylthiophen-2-yl)propan-2-yl]acetamide
    —— (2-amino-2-oxoethyl) (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C14H21NO3S2
    (2-amino-2-oxoethyl) (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-3-thiophen-2-ylprop-2-enoate —— C17H17NO3S2
    [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-3-thiophen-2-ylprop-2-enoate
    —— [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 2-(4-hydroxyphenyl)acetate —— C23H21NO4S
    [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 2-(4-hydroxyphenyl)acetate
    —— [2-[2-(4-chlorophenyl)sulfanylethylamino]-2-oxoethyl] (E)-3-thiophen-2-ylprop-2-enoate —— C17H16ClNO3S2
    [2-[2-(4-chlorophenyl)sulfanylethylamino]-2-oxoethyl] (E)-3-thiophen-2-ylprop-2-enoate
    —— 2-[(1R)-1-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C20H17N3OS2
    2-[(1R)-1-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C18H18N2OS3
    2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— N-[1-[[(3R)-oxolan-3-yl]methyl]piperidin-4-yl]-2-phenylsulfanylacetamide —— C18H26N2O2S
    N-[1-[[(3R)-oxolan-3-yl]methyl]piperidin-4-yl]-2-phenylsulfanylacetamide
    —— N-[1-[[(3S)-oxolan-3-yl]methyl]piperidin-4-yl]-2-phenylsulfanylacetamide —— C18H26N2O2S
    N-[1-[[(3S)-oxolan-3-yl]methyl]piperidin-4-yl]-2-phenylsulfanylacetamide