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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Dithiophosphorsaeure-O.O-dimethyl-S-<2-vinylmercapto-aethyl>-ester 114303-99-0 C6H13O2PS3
    Dithiophosphorsaeure-O.O-dimethyl-S-<2-vinylmercapto-aethyl>-ester
    —— 6-chloro-3-piperidinomethyl-thiochroman-4-one 111588-59-1 C15H18ClNOS
    6-chloro-3-piperidinomethyl-thiochroman-4-one
    —— 5,5-dimethyl-3-phenylthiocyclohexanol 96530-10-8 C14H20OS
    5,5-dimethyl-3-phenylthiocyclohexanol
    —— 2-({6-amino-9-[2-(1-formylpiperidin-4-yl)ethyl]-9H-purin-8-yl}thio)-4-methoxybenzonitrile 1156465-93-8 C21H23N7O2S
    2-({6-amino-9-[2-(1-formylpiperidin-4-yl)ethyl]-9H-purin-8-yl}thio)-4-methoxybenzonitrile
    —— 4-Chlorphenyl-octadecyl-sulfid 115915-51-0 C24H41ClS
    4-Chlorphenyl-octadecyl-sulfid
    —— deca-1,9-diene-2,9-diylbis(phenylsulfane) 121213-53-4 C22H26S2
    deca-1,9-diene-2,9-diylbis(phenylsulfane)
    —— 3-(4-iodophenyl)-1-morpholinoprop-2-yn-1-one 1238626-55-5 C13H12INO2
    3-(4-iodophenyl)-1-morpholinoprop-2-yn-1-one
    —— 3-Ethyl-1-pentanthiol 110502-84-6 C7H16S
    3-Ethyl-1-pentanthiol
    —— 1-Cyclohexyl-3-phenylmercapto-propan 28796-64-7 C15H22S
    1-Cyclohexyl-3-phenylmercapto-propan
    —— (6-Methyl-7-oxo-2-phenylamino-6,7-dihydro-thiazolo[5,4-d]pyrimidin-5-ylsulfanyl)-phenyl-acetic acid 86998-97-2 C20H16N4O3S2
    (6-Methyl-7-oxo-2-phenylamino-6,7-dihydro-thiazolo[5,4-d]pyrimidin-5-ylsulfanyl)-phenyl-acetic acid
    —— 4,6-dichloro-2-(o-tolylthio)pyrimidine 1394124-20-9 C11H8Cl2N2S
    4,6-dichloro-2-(o-tolylthio)pyrimidine
    —— 2-Isopropyl-4-isopropylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 130168-89-7 C11H15N3OS
    2-Isopropyl-4-isopropylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— methyl erythro-5-hydroxy-6-phenyl-6-phenylthiohexanoate 106027-00-3 C19H22O3S
    methyl erythro-5-hydroxy-6-phenyl-6-phenylthiohexanoate
    —— 3-undecylsulfonyl-2-dodecyloxy-1-propanol 1230401-20-3 C26H54O4S
    3-undecylsulfonyl-2-dodecyloxy-1-propanol
    —— 3-Methyl-2-thioxo-butyraldehyde 132604-59-2 C5H8OS
    3-Methyl-2-thioxo-butyraldehyde
    —— 17723-31-8 C10Cl4F4N2S
    —— 2-butyrylamino-3,3-bis-phenylsulfanyl-acrylonitrile 60956-93-6 C19H18N2OS2
    2-butyrylamino-3,3-bis-phenylsulfanyl-acrylonitrile
    —— 5-Phenylsulfanyl-1-(toluene-4-sulfonyl)-1H-indole 512779-61-2 C21H17NO2S2
    5-Phenylsulfanyl-1-(toluene-4-sulfonyl)-1H-indole
    —— 1400993-96-5 C9H18N4O3S
    —— N-methyl-3-chlorohexanesulfonamide 99380-67-3 C7H16ClNO2S
    N-methyl-3-chlorohexanesulfonamide
    —— 1-((1S,2R)-3-Methoxy-4-methyl-2-phenylsulfanyl-cyclohex-3-enyl)-ethanone 77004-04-7 C16H20O2S
    1-((1S,2R)-3-Methoxy-4-methyl-2-phenylsulfanyl-cyclohex-3-enyl)-ethanone
    —— [Mn(cyanodithioformato)2] 412294-68-9 C4MnN2S4
    [Mn(cyanodithioformato)2]
    —— 1-[4-{3-[N-methyl-N-(3,4-dimethoxy-β-phenethyl)amino]propyloxy}phenylthio]-2-isopropylindolizine oxalate 114433-10-2 C2H2O4*C31H38N2O3S
    1-[4-{3-[N-methyl-N-(3,4-dimethoxy-β-phenethyl)amino]propyloxy}phenylthio]-2-isopropylindolizine oxalate
    —— 2,5-Dimethyl-1-propyl-3,4-bis-thiocyanato-1H-pyrrole 18519-28-3 C11H13N3S2
    2,5-Dimethyl-1-propyl-3,4-bis-thiocyanato-1H-pyrrole
    —— (N-adamantyldithiocarbamato)zinc(II) 1313228-58-8 C22H32N2S4Zn
    (N-adamantyldithiocarbamato)zinc(II)
    —— Diethylthio-3,3-tetramethyl-2,2,4,4-cyclobutanon 69131-35-7 C12H22OS2
    Diethylthio-3,3-tetramethyl-2,2,4,4-cyclobutanon
    —— phenyl 4-O-benzyl-1-thio-β-D-xyloside 851189-15-6 C18H20O4S
    phenyl 4-O-benzyl-1-thio-β-D-xyloside
    —— ethyl-phosphonothioic acid <i>O</i>-(4-cyano-5-methylsulfanyl-isothiazol-3-yl) ester <i>O</i>'-ethyl ester 29045-33-8 C9H13N2O2PS3
    ethyl-phosphonothioic acid <i>O</i>-(4-cyano-5-methylsulfanyl-isothiazol-3-yl) ester <i>O</i>'-ethyl ester
    —— methyl-phosphonodithioic acid <i>O</i>-methyl ester <i>S</i>-[(3-methyl-3<i>H</i>-thiazol-2-ylidenecarbamoyl)-methyl] ester 41319-05-5 C8H13N2O2PS3
    methyl-phosphonodithioic acid <i>O</i>-methyl ester <i>S</i>-[(3-methyl-3<i>H</i>-thiazol-2-ylidenecarbamoyl)-methyl] ester
    —— Ethyl-phosphonodithioic acid O-ethyl ester S-[2-(hexyloxycarbonyl-methyl-amino)-2-oxo-ethyl] ester 29163-27-7 C14H28NO4PS2
    Ethyl-phosphonodithioic acid O-ethyl ester S-[2-(hexyloxycarbonyl-methyl-amino)-2-oxo-ethyl] ester
    —— (5-Chloro-2-phenylsulfanyl-phenyl)-(3-iodo-propyl)-amine 180145-04-4 C15H15ClINS
    (5-Chloro-2-phenylsulfanyl-phenyl)-(3-iodo-propyl)-amine
    —— 1,5-bis-[N'-(2-cyano-ethyl)-thioureido]-pentane 131410-13-4 C13H22N6S2
    1,5-bis-[N'-(2-cyano-ethyl)-thioureido]-pentane
    —— 5-cyano-1-(4-methylphenyl)-4-(methylthio)-6-oxo-2-phenyl-1,6-dihydropyrimidine 812692-06-1 C19H15N3OS
    5-cyano-1-(4-methylphenyl)-4-(methylthio)-6-oxo-2-phenyl-1,6-dihydropyrimidine
    —— 3-Methylsulfanyl-selenophene-2-carbonitrile 113123-75-4 C6H5NSSe
    3-Methylsulfanyl-selenophene-2-carbonitrile
    —— methyl (2E)-2-(phenylsulfanylmethylidene)penta-3,4-dienoate 82937-27-7 C13H12O2S
    methyl (2E)-2-(phenylsulfanylmethylidene)penta-3,4-dienoate
    —— 1-(3,3-dimethyl-norborn-5-en-2<i>exo</i>-yl)-ethanethione 73367-89-2 C11H16S
    1-(3,3-dimethyl-norborn-5-en-2<i>exo</i>-yl)-ethanethione
    —— 5-cyano-4-(methylthio)-1-[4-(methylthio)phenyl]-6-oxo-2-pyridin-2-yl-1,6-dihydropyrimidine 812692-13-0 C18H14N4OS2
    5-cyano-4-(methylthio)-1-[4-(methylthio)phenyl]-6-oxo-2-pyridin-2-yl-1,6-dihydropyrimidine
    —— 2-(3-Methoxyphenyl)sulfanylpyridine-3-carboxylic acid 1019453-19-0 C13H11NO3S
    2-(3-Methoxyphenyl)sulfanylpyridine-3-carboxylic acid
    —— methyl 2-(4-methoxy-4-oxo-3-pyridin-2-ylsulfanylbutyl)cyclopentane-1-carboxylate 128756-64-9 C17H23NO4S
    methyl 2-(4-methoxy-4-oxo-3-pyridin-2-ylsulfanylbutyl)cyclopentane-1-carboxylate
    —— 2,4,5-trichloro-6-octylsulfanyl-pyrimidine 27158-56-1 C12H17Cl3N2S
    2,4,5-trichloro-6-octylsulfanyl-pyrimidine
    —— 5-Methoxy-2-phenyl-4-(2-thienylmethylthio)-3-pyridazinon 20142-61-4 C16H14N2O2S2
    5-Methoxy-2-phenyl-4-(2-thienylmethylthio)-3-pyridazinon
    —— 6-(3-Chloro-4-methylsulfanyl-phenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile 803686-93-3 C14H10ClNO2S2
    6-(3-Chloro-4-methylsulfanyl-phenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile
    —— phenyl 2,4,6-tri-O-acetyl-3-deoxy-1-thio-α-D-erythro-hex-2-enopyranozide 1101117-81-0 C18H20O7S
    phenyl 2,4,6-tri-O-acetyl-3-deoxy-1-thio-α-D-erythro-hex-2-enopyranozide
    —— 1-deoxy-1-thiophenyl-2,3-isopropylidene-4-(t-butyl-dimethylsilyloxyl)-L-lyxose 91510-77-9 C20H32O4SSi
    1-deoxy-1-thiophenyl-2,3-isopropylidene-4-(t-butyl-dimethylsilyloxyl)-L-lyxose
    —— 2-[(2-diisopropylaminoethyl)thio]-4-(3-pyridyl)thiazole 137810-50-5 C16H23N3S2
    2-[(2-diisopropylaminoethyl)thio]-4-(3-pyridyl)thiazole
    —— 2-Mercaptomethyl-4-methyl-6-formylhydrazinopyrimidin 72411-22-4 C7H10N4OS
    2-Mercaptomethyl-4-methyl-6-formylhydrazinopyrimidin
    —— N-(4-((2,3,5,6-tetrafluorophenyl)thio)phenyl)acetamide 1372616-49-3 C14H9F4NOS
    N-(4-((2,3,5,6-tetrafluorophenyl)thio)phenyl)acetamide
    —— methyl 2-methyl-4-phenyl-3-(phenylthio)butyrate 104306-39-0 C18H20O2S
    methyl 2-methyl-4-phenyl-3-(phenylthio)butyrate
    —— endo-3-chloro-exo-4-(phenylthio)bicyclo<3.2.1>octan-6-one 109637-62-9 C14H15ClOS
    endo-3-chloro-exo-4-(phenylthio)bicyclo<3.2.1>octan-6-one
    —— 119400-21-4 C20H40IMnO5*I3