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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]dodecanamide —— C20H32N2OS
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]dodecanamide
    —— 1-[(E)-[2-(4-methylphenyl)sulfanyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]-3-phenylthiourea —— C23H19N5OS2
    1-[(E)-[2-(4-methylphenyl)sulfanyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]-3-phenylthiourea
    —— 2-{[4-allyl-5-(4-toluidinomethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N'-(4-chlorobenzylidene)propanohydrazide —— C23H25ClN6OS
    2-{[4-allyl-5-(4-toluidinomethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N'-(4-chlorobenzylidene)propanohydrazide
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(pyridin-4-yl)ethylidene]acetohydrazide —— C18H17N5OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(pyridin-4-yl)ethylidene]acetohydrazide
    —— 3-(tert-butylsulfanyl)-6-methyl-4-{[(E)-(4-methylphenyl)methylidene]amino}-1,2,4-triazin-5(4H)-one —— C16H20N4OS
    3-(tert-butylsulfanyl)-6-methyl-4-{[(E)-(4-methylphenyl)methylidene]amino}-1,2,4-triazin-5(4H)-one
    —— 2-naphthalen-1-yl-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide —— C22H17N3O2S
    2-naphthalen-1-yl-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— N'-[(E)-2-(1H-1,2,3-benzotriazol-1-yl)-1-methylethylidene]-2-[(4-chlorophenyl)thio]-5-nitrobenzohydrazide —— C22H17ClN6O3S
    N'-[(E)-2-(1H-1,2,3-benzotriazol-1-yl)-1-methylethylidene]-2-[(4-chlorophenyl)thio]-5-nitrobenzohydrazide
    —— N'-[(1E)-1-(3-hydroxyphenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C20H20N4O2S3
    N'-[(1E)-1-(3-hydroxyphenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 2-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole —— C15H17N5O2S
    2-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole
    —— 3-butyl-5-[(1S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H23N5O2S
    3-butyl-5-[(1S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 2-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole —— C15H17N5O2S
    2-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole
    —— 3-butyl-5-[(1R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H23N5O2S
    3-butyl-5-[(1R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— N-(4-methylphenyl)-4-[[4-(oxolan-2-ylmethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazol-2-amine —— C22H23N5OS3
    N-(4-methylphenyl)-4-[[4-(oxolan-2-ylmethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazol-2-amine
    —— N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C14H22N4OS
    N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (1R)-2-(4-chlorophenyl)sulfanyl-1-(2,4-difluorophenyl)ethanol —— C14H11ClF2OS
    (1R)-2-(4-chlorophenyl)sulfanyl-1-(2,4-difluorophenyl)ethanol
    —— (1S)-2-(4-chlorophenyl)sulfanyl-1-(2,4-difluorophenyl)ethanol —— C14H11ClF2OS
    (1S)-2-(4-chlorophenyl)sulfanyl-1-(2,4-difluorophenyl)ethanol
    —— N'-{(E)-[4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide —— C22H16N4O2S
    N'-{(E)-[4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide
    —— 4-nitro-N'-{(E)-[4-oxo-2-(2-pyridinylthio)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide —— C21H14N6O4S
    4-nitro-N'-{(E)-[4-oxo-2-(2-pyridinylthio)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide
    —— [(4-{[(E)-(4-bromophenyl)methylidene]amino}-5-propyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetic acid —— C14H15BrN4O2S
    [(4-{[(E)-(4-bromophenyl)methylidene]amino}-5-propyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetic acid
    —— 1-[(E)-(4-oxo-2-pyridin-2-ylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-phenylthiourea —— C21H16N6OS2
    1-[(E)-(4-oxo-2-pyridin-2-ylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-phenylthiourea
    —— 3-[(4-Chlorophenyl)sulfanyl]-N'-[(E)-1-methyl-2-(5-nitro-2H-tetraazol-2-YL)ethylidene]-5-nitrobenzohydrazide —— C17H13ClN8O5S
    3-[(4-Chlorophenyl)sulfanyl]-N'-[(E)-1-methyl-2-(5-nitro-2H-tetraazol-2-YL)ethylidene]-5-nitrobenzohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-furan-3-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C17H13ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-furan-3-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 4-Oxo-2-(phenylthio)-4H-pyrido(1,2-A)pyrimidine-3-carbaldehyde phenylhydrazone —— C21H16N4OS
    4-Oxo-2-(phenylthio)-4H-pyrido(1,2-A)pyrimidine-3-carbaldehyde phenylhydrazone
    —— N-[(E)-(2-chlorophenyl)methylideneamino]-2-[2-[2-[(2E)-2-[(2-chlorophenyl)methylidene]hydrazinyl]-2-oxoethyl]sulfanyl-6-methylpyrimidin-4-yl]oxyacetamide —— C23H20Cl2N6O3S
    N-[(E)-(2-chlorophenyl)methylideneamino]-2-[2-[2-[(2E)-2-[(2-chlorophenyl)methylidene]hydrazinyl]-2-oxoethyl]sulfanyl-6-methylpyrimidin-4-yl]oxyacetamide
    —— N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H24N4O2S
    N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanamide —— C17H18N4OS2
    (2S)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanamide
    —— N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H24N4O2S
    N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanamide —— C17H18N4OS2
    (2R)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-phenylpropanamide
    —— N-[2-[(1R,2R)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H24N4O2S
    N-[2-[(1R,2R)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-ethyl-5-[(1R)-1-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C9H13N5OS
    3-ethyl-5-[(1R)-1-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-7-methoxy-1-benzofuran-2-carbohydrazide —— C21H15ClN2O4S
    N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-7-methoxy-1-benzofuran-2-carbohydrazide
    —— N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H24N4O2S
    N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-(3,5-dimethyl-1H-pyrazol-4-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}propanohydrazide —— C16H20N4OS
    3-(3,5-dimethyl-1H-pyrazol-4-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}propanohydrazide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H15N5OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-ethyl-5-[(1S)-1-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C9H13N5OS
    3-ethyl-5-[(1S)-1-[(2-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-ethylphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C21H20N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-ethylphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— (2R)-3-(2-ethylsulfanylpyridin-4-yl)-3-oxo-2-pyridin-2-ylpropanenitrile —— C15H13N3OS
    (2R)-3-(2-ethylsulfanylpyridin-4-yl)-3-oxo-2-pyridin-2-ylpropanenitrile
    —— (2S)-3-(2-ethylsulfanylpyridin-4-yl)-3-oxo-2-pyridin-2-ylpropanenitrile —— C15H13N3OS
    (2S)-3-(2-ethylsulfanylpyridin-4-yl)-3-oxo-2-pyridin-2-ylpropanenitrile
    —— 2-methyl-3-[(E)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one —— C23H18N4O3S
    2-methyl-3-[(E)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one
    —— (Z)-3-(2-methyl-1,3-thiazol-4-yl)-1-[4-(2-phenylsulfanylethyl)piperazin-1-yl]prop-2-en-1-one —— C19H23N3OS2
    (Z)-3-(2-methyl-1,3-thiazol-4-yl)-1-[4-(2-phenylsulfanylethyl)piperazin-1-yl]prop-2-en-1-one
    —— 3-tert-butyl-5-[(1R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H23N5O2S
    3-tert-butyl-5-[(1R)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 3-tert-butyl-5-[(1S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H23N5O2S
    3-tert-butyl-5-[(1S)-1-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1E)-1-(thiophen-2-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C19H18N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1E)-1-(thiophen-2-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— N-benzyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]butanediamide —— C19H21N3O2S
    N-benzyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]butanediamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C18H15ClN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— N-[(E)-[(Z)-2-bromo-3-phenylprop-2-enylidene]amino]-2-(5-ethyl-4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide —— C19H21BrN4O2S
    N-[(E)-[(Z)-2-bromo-3-phenylprop-2-enylidene]amino]-2-(5-ethyl-4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide
    —— 2-cyano-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide —— C13H10N4O2S
    2-cyano-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— N'-[(E)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylidene]-3-bromobenzohydrazide —— C19H12BrN3O2S2
    N'-[(E)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylidene]-3-bromobenzohydrazide
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(2-methylphenyl)methylidene]acetohydrazide —— C19H17ClN4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(2-methylphenyl)methylidene]acetohydrazide
    —— N-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine —— C14H10N6OS
    N-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine