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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-[2-[2-[[(1S,2S,3S)-2,3-dimethylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C17H26N2O3S2
    ethyl 2-[2-[2-[[(1S,2S,3S)-2,3-dimethylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H18N4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H18N4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-methyltetrazol-5-yl)sulfanylpropan-1-one —— C11H19N5O2S
    (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(1-methyltetrazol-5-yl)sulfanylpropan-1-one
    —— N-benzyl-2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C19H18ClF3N2O3S2
    N-benzyl-2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C16H20BrNO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— (2S)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2R)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C22H28N8O4S3
    (2S)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2R)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2S)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C22H28N8O4S3
    (2S)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2S)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[(S)-octylsulfinyl]-3-[(R)-octylsulfinyl]propan-1-ol —— C19H40O3S2
    (2S)-2-[(S)-octylsulfinyl]-3-[(R)-octylsulfinyl]propan-1-ol
    —— (2R)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2R)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C22H28N8O4S3
    (2R)-N-[(Z)-[5-(dimethylamino)furan-2-yl]methylideneamino]-2-[[5-[(2R)-1-[(2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[(S)-octylsulfinyl]-3-[(R)-octylsulfinyl]propan-1-ol —— C19H40O3S2
    (2R)-2-[(S)-octylsulfinyl]-3-[(R)-octylsulfinyl]propan-1-ol
    —— 2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C16H18ClN3O3S4
    2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C16H18BrN3O4S2
    2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 1,3-bis[(S)-octylsulfinyl]propan-2-ol —— C19H40O3S2
    1,3-bis[(S)-octylsulfinyl]propan-2-ol
    —— 1,3-bis[(R)-octylsulfinyl]propan-2-ol —— C19H40O3S2
    1,3-bis[(R)-octylsulfinyl]propan-2-ol
    —— (2R)-2,3-bis[(S)-octylsulfinyl]propan-1-ol —— C19H40O3S2
    (2R)-2,3-bis[(S)-octylsulfinyl]propan-1-ol
    —— 1-[(R)-octylsulfinyl]-3-[(S)-octylsulfinyl]propan-2-ol —— C19H40O3S2
    1-[(R)-octylsulfinyl]-3-[(S)-octylsulfinyl]propan-2-ol
    —— (NZ)-N-[(2S)-2-decylsulfonylcyclooctylidene]hydroxylamine —— C18H35NO3S
    (NZ)-N-[(2S)-2-decylsulfonylcyclooctylidene]hydroxylamine
    —— (4R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide —— C12H12N4O2S
    (4R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide
    —— (4S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide —— C12H12N4O2S
    (4S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C15H23N3O2S
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (NZ)-N-[(2R)-2-decylsulfonylcyclooctylidene]hydroxylamine —— C18H35NO3S
    (NZ)-N-[(2R)-2-decylsulfonylcyclooctylidene]hydroxylamine
    —— N-[(2R)-2,3-dihydro-1-benzothiophen-2-yl]-4-[(1S,4R)-2-thia-5-azabicyclo[2.2.1]heptan-5-yl]butanamide —— C17H22N2OS2
    N-[(2R)-2,3-dihydro-1-benzothiophen-2-yl]-4-[(1S,4R)-2-thia-5-azabicyclo[2.2.1]heptan-5-yl]butanamide
    —— (NE)-N-[(6S)-6-methyl-6-phenylsulfanylcyclohex-3-en-1-ylidene]hydroxylamine —— C13H15NOS
    (NE)-N-[(6S)-6-methyl-6-phenylsulfanylcyclohex-3-en-1-ylidene]hydroxylamine
    —— N-[(2S)-2,3-dihydro-1-benzothiophen-2-yl]-4-[(1S,4R)-2-thia-5-azabicyclo[2.2.1]heptan-5-yl]butanamide —— C17H22N2OS2
    N-[(2S)-2,3-dihydro-1-benzothiophen-2-yl]-4-[(1S,4R)-2-thia-5-azabicyclo[2.2.1]heptan-5-yl]butanamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H26N4O2S
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [(1S)-1-[5-[2-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium —— C14H25N4O4S2+
    [(1S)-1-[5-[2-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium
    —— (NE)-N-[(2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine —— C11H18N4OS
    (NE)-N-[(2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine
    —— (NE)-N-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooctylidene]hydroxylamine —— C10H16N4OS
    (NE)-N-[(2S)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooctylidene]hydroxylamine
    —— (NE)-N-[(2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine —— C11H18N4OS
    (NE)-N-[(2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine
    —— (NE)-N-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooctylidene]hydroxylamine —— C10H16N4OS
    (NE)-N-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooctylidene]hydroxylamine
    —— (4S,8Z)-2-amino-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-6-propyl-4,5,6,7-tetrahydropyrano[3,2-c]pyridin-6-ium-3-carbonitrile —— C27H30N3OS2+
    (4S,8Z)-2-amino-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-6-propyl-4,5,6,7-tetrahydropyrano[3,2-c]pyridin-6-ium-3-carbonitrile
    —— (NE)-N-[(2R)-2-phenylsulfanylcyclooctylidene]hydroxylamine —— C14H19NOS
    (NE)-N-[(2R)-2-phenylsulfanylcyclooctylidene]hydroxylamine
    —— (NE)-N-[(2S)-2-phenylsulfanylcyclooctylidene]hydroxylamine —— C14H19NOS
    (NE)-N-[(2S)-2-phenylsulfanylcyclooctylidene]hydroxylamine
    —— (3S,5R)-3-hexyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)oxolan-2-one —— C13H21N3O2S
    (3S,5R)-3-hexyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)oxolan-2-one
    —— ethyl (2R)-4-[(4-cyclopropyl-5-piperidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanoate —— C20H27N5O3S2
    ethyl (2R)-4-[(4-cyclopropyl-5-piperidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanoate
    —— ethyl (2S)-4-[(4-cyclopropyl-5-piperidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanoate —— C20H27N5O3S2
    ethyl (2S)-4-[(4-cyclopropyl-5-piperidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanoate
    —— (2S)-2-(4-chloro-2-methylphenoxy)-N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]propanamide —— C23H17ClN4O6S2
    (2S)-2-(4-chloro-2-methylphenoxy)-N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]propanamide
    —— (2R)-2-(4-chloro-2-methylphenoxy)-N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]propanamide —— C23H17ClN4O6S2
    (2R)-2-(4-chloro-2-methylphenoxy)-N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]propanamide
    —— dimethyl (3R,4S,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C25H21FN2O5S
    dimethyl (3R,4S,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3R,4S,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C26H24N2O5S
    dimethyl (3R,4S,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3S,4R,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C25H21FN2O5S
    dimethyl (3S,4R,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3S,4R,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C26H24N2O5S
    dimethyl (3S,4R,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3R,4S,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate —— C24H21N3O5S
    dimethyl (3R,4S,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate
    —— dimethyl (3R,4R,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C26H24N2O5S
    dimethyl (3R,4R,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3S,4S,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C26H24N2O5S
    dimethyl (3S,4S,6R)-5,5-dicyano-2-hydroxy-4-(4-methylphenyl)-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3R,4R,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate —— C24H21N3O5S
    dimethyl (3R,4R,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate
    —— dimethyl (3R,4R,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate —— C25H21FN2O5S
    dimethyl (3R,4R,6S)-5,5-dicyano-4-(4-fluorophenyl)-2-hydroxy-6-(4-methylsulfanylphenyl)cyclohexene-1,3-dicarboxylate
    —— dimethyl (3S,4S,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate —— C24H21N3O5S
    dimethyl (3S,4S,6S)-5,5-dicyano-2-hydroxy-6-(4-methylsulfanylphenyl)-4-pyridin-4-ylcyclohexene-1,3-dicarboxylate