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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2E)-1-(2,4-dinitrophenyl)-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)hydrazine —— C18H14N4O5S
    (2E)-1-(2,4-dinitrophenyl)-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)hydrazine
    —— 4-chloro-2-(methylsulfanyl)-6-[(E)-2-(phenylmethylidene)hydrazin-1-yl]pyrimidine —— C12H11ClN4S
    4-chloro-2-(methylsulfanyl)-6-[(E)-2-(phenylmethylidene)hydrazin-1-yl]pyrimidine
    —— 2-({4-allyl-5-[(4-chloroanilino)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-(3-pyridinylmethylene)propanohydrazide —— C21H22ClN7OS
    2-({4-allyl-5-[(4-chloroanilino)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-(3-pyridinylmethylene)propanohydrazide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(4-hydroxyphenyl)methylideneamino]acetamide —— C18H15ClN4O2S3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(4-hydroxyphenyl)methylideneamino]acetamide
    —— N-[(E)-(2-bromophenyl)methylideneamino]-2-[[5-[1-[(2E)-2-[(2-bromophenyl)methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C22H20Br2N6O2S3
    N-[(E)-(2-bromophenyl)methylideneamino]-2-[[5-[1-[(2E)-2-[(2-bromophenyl)methylidene]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide —— C12H12N4O2S
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-5-oxo-1,4-dihydropyrazole-4-carboxamide
    —— 1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde O-(2,4-dichlorobenzyl)oxime —— C19H14Cl2F3N3OS
    1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde O-(2,4-dichlorobenzyl)oxime
    —— (2E)-N'-[(E)-(2-chlorophenyl)methylidene]-2-cyano-3-(5-{4-[(difluoromethyl)sulfanyl]phenyl}furan-2-yl)prop-2-enehydrazide —— C22H14ClF2N3O2S
    (2E)-N'-[(E)-(2-chlorophenyl)methylidene]-2-cyano-3-(5-{4-[(difluoromethyl)sulfanyl]phenyl}furan-2-yl)prop-2-enehydrazide
    —— N-[(E)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-hydroxybenzamide —— C18H12BrClN2O3S
    N-[(E)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-hydroxybenzamide
    —— 2-[(1R)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one —— C12H14N4O2S
    2-[(1R)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one
    —— 2-[(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one —— C12H14N4O2S
    2-[(1S)-1-(5-methyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-pyridin-4-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C18H14ClN9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-pyridin-4-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]thiophene-2-carbohydrazide —— C16H10BrClN2O2S2
    N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]thiophene-2-carbohydrazide
    —— 2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(thiophen-2-yl)ethylidene]acetohydrazide —— C17H15ClN4OS4
    2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(thiophen-2-yl)ethylidene]acetohydrazide
    —— 2-naphthalen-1-yl-N-[(E)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]acetamide —— C31H22N4O3S
    2-naphthalen-1-yl-N-[(E)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]acetamide
    —— 2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide
    —— N-(4-Bromo-benzylidene)-N'-(4-(4-methylsulfanyl-phenyl)-thiazol-2-YL)-hydrazine —— C17H14BrN3S2
    N-(4-Bromo-benzylidene)-N'-(4-(4-methylsulfanyl-phenyl)-thiazol-2-YL)-hydrazine
    —— 3-(3-methyl-5-oxo-4,5-dihydro-1H-pyrazol-4-yl)-N'-{(E)-[4-(methylthio)phenyl]methylidene}propanohydrazide —— C15H18N4O2S
    3-(3-methyl-5-oxo-4,5-dihydro-1H-pyrazol-4-yl)-N'-{(E)-[4-(methylthio)phenyl]methylidene}propanohydrazide
    —— 2-({5-[(3-chloroanilino)methyl]-4-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[(5-methyl-2-furyl)methylene]propanohydrazide —— C19H21ClN6O2S
    2-({5-[(3-chloroanilino)methyl]-4-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[(5-methyl-2-furyl)methylene]propanohydrazide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(3,4-difluorophenyl)ethyl]-N-methylacetamide —— C19H16ClF2N3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(3,4-difluorophenyl)ethyl]-N-methylacetamide
    —— N-[(1S)-1-(3,4-difluorophenyl)ethyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H17F2N3O2S
    N-[(1S)-1-(3,4-difluorophenyl)ethyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-difluorophenyl)ethyl]-N-methylacetamide —— C19H16ClF2N3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-difluorophenyl)ethyl]-N-methylacetamide
    —— N-[(1R)-1-(3,4-difluorophenyl)ethyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H17F2N3O2S
    N-[(1R)-1-(3,4-difluorophenyl)ethyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 6-[(4-chlorophenyl)sulfanyl]nicotinaldehyde O-(3-fluorobenzyl)oxime —— C19H14ClFN2OS
    6-[(4-chlorophenyl)sulfanyl]nicotinaldehyde O-(3-fluorobenzyl)oxime
    —— 3-(4-chlorophenyl)sulfanyl-N-[(E)-(3-methylphenyl)methylideneamino]propanamide —— C17H17ClN2OS
    3-(4-chlorophenyl)sulfanyl-N-[(E)-(3-methylphenyl)methylideneamino]propanamide
    —— 2-(2-amino-1,3-thiazol-4-yl)-N-[(E)-[4-[(E)-[[2-(2-amino-1,3-thiazol-4-yl)acetyl]hydrazinylidene]methyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylideneamino]acetamide —— C18H20N8O2S5
    2-(2-amino-1,3-thiazol-4-yl)-N-[(E)-[4-[(E)-[[2-(2-amino-1,3-thiazol-4-yl)acetyl]hydrazinylidene]methyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylideneamino]acetamide
    —— 2-[(4-chlorophenyl)sulfanyl]-N'-{[4-(methylsulfanyl)phenyl]methylene}acetohydrazide —— C16H15ClN2OS2
    2-[(4-chlorophenyl)sulfanyl]-N'-{[4-(methylsulfanyl)phenyl]methylene}acetohydrazide
    —— (3R)-4-methyl-1-[[(1R,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol —— C12H25NO3S
    (3R)-4-methyl-1-[[(1R,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol
    —— (3R)-4-methyl-1-[[(1S,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol —— C12H25NO3S
    (3R)-4-methyl-1-[[(1S,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol
    —— (3S)-4-methyl-1-[[(1R,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol —— C12H25NO3S
    (3S)-4-methyl-1-[[(1R,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol
    —— (3S)-4-methyl-1-[[(1S,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol —— C12H25NO3S
    (3S)-4-methyl-1-[[(1S,2S)-2-methylsulfonylcyclopentyl]amino]pentan-3-ol
    —— 2-Dimethylamino-6,7-dihydro-4H-triazolo[3,2-a]-1,3,5-triazin-2-one Acetylhydrazone —— C9H14N6OS
    2-Dimethylamino-6,7-dihydro-4H-triazolo[3,2-a]-1,3,5-triazin-2-one Acetylhydrazone
    —— Benzaldehyde 4-methyl-6-methylthio-2-pyrimidinylhydrazone —— C13H14N4S
    Benzaldehyde 4-methyl-6-methylthio-2-pyrimidinylhydrazone
    —— (3R)-3-(2,4-difluorophenyl)sulfanyl-1-[(3-methyltriazol-4-yl)methyl]piperidine —— C15H18F2N4S
    (3R)-3-(2,4-difluorophenyl)sulfanyl-1-[(3-methyltriazol-4-yl)methyl]piperidine
    —— [Chloro(methylthio)methylenimino]sulfur pentafluoride —— C2H3ClF5NS2
    [Chloro(methylthio)methylenimino]sulfur pentafluoride
    —— (3S)-3-(2,4-difluorophenyl)sulfanyl-1-[(3-methyltriazol-4-yl)methyl]piperidine —— C15H18F2N4S
    (3S)-3-(2,4-difluorophenyl)sulfanyl-1-[(3-methyltriazol-4-yl)methyl]piperidine
    —— Thiophene-2-carboxaldehyde, 3-(3-thienylthio)-, phenylhydrazone —— C15H12N2S3
    Thiophene-2-carboxaldehyde, 3-(3-thienylthio)-, phenylhydrazone
    —— 2-(5-Pyridin-4-yl-[1,3,4]oxadiazol-2-ylsulfanyl)-propionic acid (1-methyl-3-oxo-butylidene)-hydrazide —— C15H17N5O3S
    2-(5-Pyridin-4-yl-[1,3,4]oxadiazol-2-ylsulfanyl)-propionic acid (1-methyl-3-oxo-butylidene)-hydrazide
    —— (Z)-1-[4-bromo-2,5-bis(methylsulfanyl)thiophen-3-yl]-N-hydroxymethanimine —— C7H8BrNOS3
    (Z)-1-[4-bromo-2,5-bis(methylsulfanyl)thiophen-3-yl]-N-hydroxymethanimine
    —— (Z)-N-hydroxy-1-[2-methoxy-5-(methylsulfanyl)thiophen-3-yl]methanimine —— C7H9NO2S2
    (Z)-N-hydroxy-1-[2-methoxy-5-(methylsulfanyl)thiophen-3-yl]methanimine
    —— (2E)-2-[(4-{[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]methyl}thiophen-2-yl)methylidene]hydrazinecarboxamide —— C9H10N6OS3
    (2E)-2-[(4-{[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]methyl}thiophen-2-yl)methylidene]hydrazinecarboxamide
    —— 1-methyl-4-[(R)-methylsulfinyl]cyclohexane —— C8H16OS
    1-methyl-4-[(R)-methylsulfinyl]cyclohexane
    —— N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-2-nitrobenzohydrazide —— C21H16N4O5S2
    N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-2-nitrobenzohydrazide
    —— N-[(4Z)-2-{[4-(Difluoromethyl)-6-methylpyrimidin-2-YL]sulfanyl}-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine —— C12H13F2N3O3S
    N-[(4Z)-2-{[4-(Difluoromethyl)-6-methylpyrimidin-2-YL]sulfanyl}-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine
    —— N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]-2-hydroxybenzohydrazide —— C26H19N5O3S
    N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]-2-hydroxybenzohydrazide
    —— N'-[(E)-cyclohex-3-en-1-ylmethylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide —— C14H17N3OS
    N'-[(E)-cyclohex-3-en-1-ylmethylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide
    —— N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-3-nitrobenzohydrazide —— C21H16N4O5S2
    N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-3-nitrobenzohydrazide
    —— N-[(E)-furan-2-ylmethylidene]-3-(propylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C11H12N6OS
    N-[(E)-furan-2-ylmethylidene]-3-(propylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4-methoxybenzohydrazide —— C20H16N4O3S
    N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4-methoxybenzohydrazide
    —— 3-(propylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C11H12N6S2
    3-(propylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine