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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-[2-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C15H15N3O3S3
    ethyl 2-[2-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— 3-[(1-Butyltetrazol-5-yl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C12H16N8S2
    3-[(1-Butyltetrazol-5-yl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C13H17N5OS
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone —— C18H18N6O2S
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C12H21N5O3S2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C10H11ClN4S
    3-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— 2-[(5-amino-4H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide —— C7H13N5OS
    2-[(5-amino-4H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide
    —— (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C9H15N5OS
    (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)acetamide —— C12H21N5O3S2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)acetamide
    —— 3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C10H11ClN4S
    3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methylpropyl)acetamide —— C8H15N5OS
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methylpropyl)acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C10H17N5O3S2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide —— C8H15N5OS
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-butan-2-yl]acetamide
    —— (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C8H12N4OS
    (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 7-{[(5-Amino-4H-1,2,4-triazol-3-YL)sulfanyl]methyl}-3-methyl-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one —— C10H10N6OS2
    7-{[(5-Amino-4H-1,2,4-triazol-3-YL)sulfanyl]methyl}-3-methyl-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one
    —— [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C18H23NO5S2
    [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— 3-phenyl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazole-2-thione —— C16H12N4OS4
    3-phenyl-5-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-thiadiazole-2-thione
    —— (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C8H12N4OS
    (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 3-[(1-Butyltetrazol-5-yl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C21H21N7S
    3-[(1-Butyltetrazol-5-yl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 2-(3,4-difluorophenyl)sulfanyl-1-[(2S)-2-(4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]ethanone —— C15H16F2N4OS
    2-(3,4-difluorophenyl)sulfanyl-1-[(2S)-2-(4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]ethanone
    —— 6-Amino-5-[2-(4-bromophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione —— C13H12BrN3O3S
    6-Amino-5-[2-(4-bromophenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione
    —— 2-(3,4-difluorophenyl)sulfanyl-1-[(2R)-2-(4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]ethanone —— C15H16F2N4OS
    2-(3,4-difluorophenyl)sulfanyl-1-[(2R)-2-(4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]ethanone
    —— 2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C15H18BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-5-nitro-N-[(1S)-1-(1,2-oxazol-3-yl)ethyl]benzamide —— C18H14FN3O4S
    2-(2-fluorophenyl)sulfanyl-5-nitro-N-[(1S)-1-(1,2-oxazol-3-yl)ethyl]benzamide
    —— (Z)-N-(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)-1-(2-methylphenyl)methanimine —— C19H20N4S
    (Z)-N-(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)-1-(2-methylphenyl)methanimine
    —— 2-[(1S)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C10H10N6OS2
    2-[(1S)-1-(1-methyltetrazol-5-yl)sulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-(2-fluorophenyl)sulfanyl-5-nitro-N-[(1R)-1-(1,2-oxazol-3-yl)ethyl]benzamide —— C18H14FN3O4S
    2-(2-fluorophenyl)sulfanyl-5-nitro-N-[(1R)-1-(1,2-oxazol-3-yl)ethyl]benzamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-tert-butylsulfonylacetamide —— C18H31NO3S
    N-[(1R)-1-(1-adamantyl)ethyl]-2-tert-butylsulfonylacetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-tert-butylsulfonylacetamide —— C18H31NO3S
    N-[(1S)-1-(1-adamantyl)ethyl]-2-tert-butylsulfonylacetamide
    —— 3-[(1-butyltetrazol-5-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C8H14N8S
    3-[(1-butyltetrazol-5-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C15H18ClNO3S2
    2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(3-bromophenyl)sulfanyl-N-[(3R)-3-methyloxolan-3-yl]acetamide —— C13H16BrNO2S
    2-(3-bromophenyl)sulfanyl-N-[(3R)-3-methyloxolan-3-yl]acetamide
    —— 2-(3-bromophenyl)sulfanyl-N-[(3S)-3-methyloxolan-3-yl]acetamide —— C13H16BrNO2S
    2-(3-bromophenyl)sulfanyl-N-[(3S)-3-methyloxolan-3-yl]acetamide
    —— (1S,2R)-N-methyl-2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide —— C13H24N2O4S
    (1S,2R)-N-methyl-2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide
    —— (1S,2S)-N-methyl-2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide —— C13H24N2O4S
    (1S,2S)-N-methyl-2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide
    —— (1S,2R)-N-methyl-2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide —— C13H24N2O4S
    (1S,2R)-N-methyl-2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide
    —— (1S,2S)-N-methyl-2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide —— C13H24N2O4S
    (1S,2S)-N-methyl-2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]cyclopentane-1-carboxamide
    —— (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[(1-methylpyrazol-3-yl)methyl]propanamide —— C15H18FN3OS
    (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[(1-methylpyrazol-3-yl)methyl]propanamide
    —— (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[(1-methylpyrazol-3-yl)methyl]propanamide —— C15H18FN3OS
    (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[(1-methylpyrazol-3-yl)methyl]propanamide
    —— (2S)-N-(2-oxopropyl)-2-pyridin-2-ylsulfanylpropanamide —— C11H14N2O2S
    (2S)-N-(2-oxopropyl)-2-pyridin-2-ylsulfanylpropanamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-1-[(3R)-3-(2-hydroxyethyl)morpholin-4-yl]ethanone —— C15H20BrNO3S
    2-(4-bromo-2-methylphenyl)sulfanyl-1-[(3R)-3-(2-hydroxyethyl)morpholin-4-yl]ethanone
    —— (2R)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H17N3OS3
    (2R)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H20N4OS3
    (2R)-N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C15H18FN3OS3
    (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-1-[(3S)-3-(2-hydroxyethyl)morpholin-4-yl]ethanone —— C15H20BrNO3S
    2-(4-bromo-2-methylphenyl)sulfanyl-1-[(3S)-3-(2-hydroxyethyl)morpholin-4-yl]ethanone
    —— (2R)-N-(2-oxopropyl)-2-pyridin-2-ylsulfanylpropanamide —— C11H14N2O2S
    (2R)-N-(2-oxopropyl)-2-pyridin-2-ylsulfanylpropanamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C11H19N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C7H11N3OS3
    (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H17N3OS3
    (2S)-N-benzyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C15H18FN3OS3
    (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide