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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-cyclopentyl-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H28N4OS2
    N-cyclopentyl-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— methyl 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C18H25N3O2S2
    methyl 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-cyclopropyl-2-[[5-[(5R)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H24N4OS2
    N-cyclopropyl-2-[[5-[(5R)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C16H22N4OS2
    2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— (2R)-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C16H20N4S2
    (2R)-2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-3-(1,3,5-trimethylpyrazol-4-yl)prop-2-enoate —— C23H23N3O3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-3-(1,3,5-trimethylpyrazol-4-yl)prop-2-enoate
    —— 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide —— C21H30N4OS2
    2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C19H28N4OS2
    2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— ethyl N-[2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]carbamate —— C18H24N4O3S2
    ethyl N-[2-[[5-[(5S)-5-ethyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]carbamate
    —— (5S)-5-[(4-chlorophenyl)sulfanylmethyl]-3-phenyl-1,3-oxazolidin-2-one —— C16H14ClNO2S
    (5S)-5-[(4-chlorophenyl)sulfanylmethyl]-3-phenyl-1,3-oxazolidin-2-one
    —— 2-methylsulfanyl-6-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine —— C19H23N7S
    2-methylsulfanyl-6-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine
    —— 2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C20H29N5O2S
    2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— 1-[2-[[4-Benzyl-5-(piperidin-1-ium-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C21H28N5O2S+
    1-[2-[[4-Benzyl-5-(piperidin-1-ium-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[(1R)-cyclohex-3-en-1-yl]methylideneamino]acetamide —— C15H17ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[(1R)-cyclohex-3-en-1-yl]methylideneamino]acetamide
    —— 2-[[4-benzyl-5-(piperidin-1-ium-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C21H32N5OS+
    2-[[4-benzyl-5-(piperidin-1-ium-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C21H20N2O3S2
    [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C23H19N3O3S
    (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(2,6-Dimethylanilino)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C24H24N2O3S
    [2-(2,6-Dimethylanilino)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— (4-Oxo-1,2,3-benzotriazin-3-yl)methyl 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C21H16N4O3S
    (4-Oxo-1,2,3-benzotriazin-3-yl)methyl 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C21H21N3O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C22H23N3O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C19H22N2O3S
    [2-Oxo-2-(propan-2-ylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— 2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide —— C19H27N5OS
    2-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide
    —— [2-Oxo-2-(2,2,2-trifluoroethylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C18H17F3N2O3S
    [2-Oxo-2-(2,2,2-trifluoroethylamino)ethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— (2-Amino-2-oxoethyl) 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C16H16N2O3S
    (2-Amino-2-oxoethyl) 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C22H23N3O3S
    [2-[[(1S)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— Cyanomethyl 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C16H14N2O2S
    Cyanomethyl 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Dimethylamino)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C18H20N2O3S
    [2-(Dimethylamino)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— (2-Anilino-2-oxoethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C21H18N2O3S
    (2-Anilino-2-oxoethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(2-Cyanoanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H17N3O3S
    [2-(2-Cyanoanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [(3S)-2-oxooxolan-3-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C17H15NO4S
    [(3S)-2-oxooxolan-3-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C22H25N3O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— (2-Oxo-2-pyrrolidin-1-ylethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C19H20N2O3S
    (2-Oxo-2-pyrrolidin-1-ylethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(2-Fluoroanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C21H17FN2O3S
    [2-(2-Fluoroanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-Oxo-2-(2,4,6-trimethylanilino)ethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C24H24N2O3S
    [2-Oxo-2-(2,4,6-trimethylanilino)ethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H23N3O3S
    [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C16H16N2O3S
    [(2S)-1-amino-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— (2S)-2-ethanimidoyl-3-oxo-4-(2,3,5,6-tetramethylphenyl)sulfanylbutanenitrile —— C16H20N2OS
    (2S)-2-ethanimidoyl-3-oxo-4-(2,3,5,6-tetramethylphenyl)sulfanylbutanenitrile
    —— [2-Oxo-2-(2-phenylethylamino)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [2-Oxo-2-(2-phenylethylamino)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— (6S)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-6-hydroxy-1,4-oxazepane-4-carboxamide —— C17H22N4O3S
    (6S)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-6-hydroxy-1,4-oxazepane-4-carboxamide
    —— (6R)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-6-hydroxy-1,4-oxazepane-4-carboxamide —— C17H22N4O3S
    (6R)-N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-6-hydroxy-1,4-oxazepane-4-carboxamide
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C13H16BrNO3S
    [(2R)-1-amino-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-(Cyclopropylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H19NO3S
    [2-(Cyclopropylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C16H20BrNO3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C21H22N2O3S
    [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H27NO3S
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H19NO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(carbamoylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C14H18N2O4S
    [(2S)-1-(carbamoylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate —— C17H16N2O3S2
    (5-Oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl 2-(2,5-dimethylphenyl)sulfanylacetate