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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (3R)-3-(3-bromo-4-fluorophenyl)-3-[6-[(4-chlorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate —— C22H17BrClFO5S
    methyl (3R)-3-(3-bromo-4-fluorophenyl)-3-[6-[(4-chlorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate
    —— N,N-dimethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide —— C24H20N6O6S2
    N,N-dimethyl-5-nitro-2-[(2Z)-2-[(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylidene]hydrazinyl]benzenesulfonamide
    —— (1E,4E)-1,5-bis(dimethylamino)-2,4-bis(phenylsulfanyl)penta-1,4-dien-3-one —— C21H24N2OS2
    (1E,4E)-1,5-bis(dimethylamino)-2,4-bis(phenylsulfanyl)penta-1,4-dien-3-one
    —— methyl (3S)-3-(3-bromo-4-fluorophenyl)-3-[6-[(4-chlorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate —— C22H17BrClFO5S
    methyl (3S)-3-(3-bromo-4-fluorophenyl)-3-[6-[(4-chlorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate
    —— (NZ)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododecylidene]hydroxylamine —— C15H25N3OS2
    (NZ)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododecylidene]hydroxylamine
    —— 2-[(2S)-5-amino-4-cyano-2-methyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile —— C12H12N4OS
    2-[(2S)-5-amino-4-cyano-2-methyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile
    —— 2-[(2R)-5-amino-4-cyano-2-methyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile —— C12H12N4OS
    2-[(2R)-5-amino-4-cyano-2-methyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile
    —— (E)-2-(4-chlorophenylthio)nicotinaldehyde O-3,4-dichlorobenzyl oxime —— C19H13Cl3N2OS
    (E)-2-(4-chlorophenylthio)nicotinaldehyde O-3,4-dichlorobenzyl oxime
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(diethylamino)phenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C23H25N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(diethylamino)phenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[(2R)-5-amino-4-cyano-2-propyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile —— C14H16N4OS
    2-[(2R)-5-amino-4-cyano-2-propyl-2-propylsulfanylfuran-3-ylidene]propanedinitrile
    —— 2-[(Z)-1-chloro-2-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]ethenyl]-3H-quinazolin-4-one —— C23H16ClN3O3S
    2-[(Z)-1-chloro-2-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]ethenyl]-3H-quinazolin-4-one
    —— N'-[(5R)-3-cyano-4-(dicyanomethylidene)-5-phenyl-5-propylsulfanylfuran-2-yl]-N,N-dimethylmethanimidamide —— C20H19N5OS
    N'-[(5R)-3-cyano-4-(dicyanomethylidene)-5-phenyl-5-propylsulfanylfuran-2-yl]-N,N-dimethylmethanimidamide
    —— N'-[(5S)-3-cyano-4-(dicyanomethylidene)-5-phenyl-5-propylsulfanylfuran-2-yl]-N,N-dimethylmethanimidamide —— C20H19N5OS
    N'-[(5S)-3-cyano-4-(dicyanomethylidene)-5-phenyl-5-propylsulfanylfuran-2-yl]-N,N-dimethylmethanimidamide
    —— (E)-2-cyano-3-[2,5-dimethyl-3-[(2-methylphenyl)sulfanylmethyl]phenyl]prop-2-enethioamide —— C20H20N2S2
    (E)-2-cyano-3-[2,5-dimethyl-3-[(2-methylphenyl)sulfanylmethyl]phenyl]prop-2-enethioamide
    —— 2-[(2S)-5-amino-4-cyano-2-ethylsulfanyl-2-phenylfuran-3-ylidene]propanedinitrile —— C16H12N4OS
    2-[(2S)-5-amino-4-cyano-2-ethylsulfanyl-2-phenylfuran-3-ylidene]propanedinitrile
    —— (1S,2R,5R)-2-[4-thiophen-2-yl-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one —— C15H11F3N2O3S2
    (1S,2R,5R)-2-[4-thiophen-2-yl-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one
    —— 3-[(R)-octylsulfinyl]propanamide —— C11H23NO2S
    3-[(R)-octylsulfinyl]propanamide
    —— 2-[(R)-dodecylsulfinyl]propane-1,3-diol —— C15H32O3S
    2-[(R)-dodecylsulfinyl]propane-1,3-diol
    —— 3-[(R)-decylsulfinyl]propanoic acid —— C13H26O3S
    3-[(R)-decylsulfinyl]propanoic acid
    —— 3-[(S)-octylsulfinyl]propanamide —— C11H23NO2S
    3-[(S)-octylsulfinyl]propanamide
    —— 1-[(S)-[(2R)-2,3-dichloropropyl]sulfinyl]dodecane —— C15H30Cl2OS
    1-[(S)-[(2R)-2,3-dichloropropyl]sulfinyl]dodecane
    —— 1-[(R)-[(2R)-2,3-dichloropropyl]sulfinyl]dodecane —— C15H30Cl2OS
    1-[(R)-[(2R)-2,3-dichloropropyl]sulfinyl]dodecane
    —— 1-[(S)-[(2S)-2,3-dichloropropyl]sulfinyl]dodecane —— C15H30Cl2OS
    1-[(S)-[(2S)-2,3-dichloropropyl]sulfinyl]dodecane
    —— 3-[(S)-decylsulfinyl]propanoic acid —— C13H26O3S
    3-[(S)-decylsulfinyl]propanoic acid
    —— 2-[(S)-dodecylsulfinyl]propane-1,3-diol —— C15H32O3S
    2-[(S)-dodecylsulfinyl]propane-1,3-diol
    —— (2S)-2-chloro-3-dodecylsulfonylpropan-1-ol —— C15H31ClO3S
    (2S)-2-chloro-3-dodecylsulfonylpropan-1-ol
    —— 1-[(2R)-2,3-dichloropropyl]sulfonyldecane —— C13H26Cl2O2S
    1-[(2R)-2,3-dichloropropyl]sulfonyldecane
    —— (2R)-2-chloro-3-dodecylsulfonylpropan-1-ol —— C15H31ClO3S
    (2R)-2-chloro-3-dodecylsulfonylpropan-1-ol
    —— 7-[(S)-octylsulfinyl]heptan-1-ol —— C15H32O2S
    7-[(S)-octylsulfinyl]heptan-1-ol
    —— 1-[(2S)-2,3-dichloropropyl]sulfonyldecane —— C13H26Cl2O2S
    1-[(2S)-2,3-dichloropropyl]sulfonyldecane
    —— 7-[(R)-octylsulfinyl]heptan-1-ol —— C15H32O2S
    7-[(R)-octylsulfinyl]heptan-1-ol
    —— (2S)-1-chloro-3-octylsulfonylpropan-2-ol —— C11H23ClO3S
    (2S)-1-chloro-3-octylsulfonylpropan-2-ol
    —— 2-[(E)-(2-oxo-1-benzothiophen-3-ylidene)amino]guanidine —— C9H8N4OS
    2-[(E)-(2-oxo-1-benzothiophen-3-ylidene)amino]guanidine
    —— O-[(5R,7R)-3-methyl-1-adamantyl] methylsulfanylmethanethioate —— C13H20OS2
    O-[(5R,7R)-3-methyl-1-adamantyl] methylsulfanylmethanethioate
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2,4-dichlorobenzamide —— C18H10BrCl3N2O2S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2,4-dichlorobenzamide
    —— 1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1R,2R)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea —— C22H32N4S2
    1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1R,2R)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea
    —— 1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1R,2S)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea —— C22H32N4S2
    1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1R,2S)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea
    —— 3-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-1,1-bis(2-cyanoethyl)thiourea —— C14H18N4S
    3-[(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]-1,1-bis(2-cyanoethyl)thiourea
    —— 1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1S,2S)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea —— C22H32N4S2
    1-[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]-3-[[(1S,2S)-2-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]carbamothioylamino]cyclopentyl]methyl]thiourea
    —— 3-[(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]-1,1-bis(2-cyanoethyl)thiourea —— C14H18N4S
    3-[(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]-1,1-bis(2-cyanoethyl)thiourea
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-1-pyridin-2-ylethylideneamino]triazole-4-carboxamide —— C16H16N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-1-pyridin-2-ylethylideneamino]triazole-4-carboxamide
    —— 3-[(Z)-(3-butyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-9-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C23H21N3O2S3
    3-[(Z)-(3-butyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-9-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— 1-[(2S)-2,3-dibromopropyl]sulfonyloctane —— C11H22Br2O2S
    1-[(2S)-2,3-dibromopropyl]sulfonyloctane
    —— 1-[(2R)-2,3-dibromopropyl]sulfonyloctane —— C11H22Br2O2S
    1-[(2R)-2,3-dibromopropyl]sulfonyloctane
    —— [(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]thiourea —— C8H12N2S
    [(1S,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]thiourea
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-naphthalen-1-ylacetamide —— C24H18N4O2S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-naphthalen-1-ylacetamide
    —— (2S)-1,2-dichloro-3-ethylsulfonylpropane —— C5H10Cl2O2S
    (2S)-1,2-dichloro-3-ethylsulfonylpropane
    —— [(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]thiourea —— C8H12N2S
    [(1S,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]thiourea
    —— (Z)-4-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylanilino]-2-methyl-4-oxobut-2-enoic acid —— C17H17N3O3S
    (Z)-4-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylanilino]-2-methyl-4-oxobut-2-enoic acid
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]heptanamide —— C15H22N2OS
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]heptanamide