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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C16H11N5O2S2
    3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-(4-fluorophenyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C16H16FN5O2S
    3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-(4-fluorophenyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— N-cyclopentyl-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide —— C11H14N6O2S
    N-cyclopentyl-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide
    —— 3-[(2-Chlorophenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H11ClN4O2S2
    3-[(2-Chlorophenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2-methylphenyl)sulfanylacetate —— C21H25NO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N-[(4-methylphenyl)methyl]-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide —— C14H14N6O2S
    N-[(4-methylphenyl)methyl]-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide
    —— 3-[(4-Chlorophenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H11ClN4O2S2
    3-[(4-Chlorophenyl)methyl]-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-cycloheptyl-2-[(6-methyl-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide —— C14H20N6O2S
    N-cycloheptyl-2-[(6-methyl-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide
    —— 7-(2-Oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C10H6N4O2S3
    7-(2-Oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C19H25N3O2S
    2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C21H23N3O2S
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 7-(2-Oxopropylsulfanyl)-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C13H10N4O2S2
    7-(2-Oxopropylsulfanyl)-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C21H24N4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C20H20ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-[(1R)-1-phenylbutyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-[(1R)-1-phenylbutyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C21H23N3O2S
    2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— N-cyclopentyl-2-[(4-oxo-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C17H17N5O2S2
    N-cyclopentyl-2-[(4-oxo-3-phenyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— 3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C16H17N5O2S
    3-(3,3-dimethyl-2-oxobutyl)sulfanyl-6-phenyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 6-(4-chlorophenyl)-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C16H10ClN5O2S2
    6-(4-chlorophenyl)-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 6-methyl-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C11H9N5O2S2
    6-methyl-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C21H24ClNO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— 3-tert-butyl-7-[(3,3-dimethyl-2-oxobutyl)sulfanyl]-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C14H20N4O2S2
    3-tert-butyl-7-[(3,3-dimethyl-2-oxobutyl)sulfanyl]-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C14H18N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C13H16N4OS
    2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H15N5OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-2-[(1S)-1-ethoxyethyl]-1,3-thiazole —— C15H23N3OS2
    4-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-2-[(1S)-1-ethoxyethyl]-1,3-thiazole
    —— 4-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-2-[(1R)-1-ethoxyethyl]-1,3-thiazole —— C15H23N3OS2
    4-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-2-[(1R)-1-ethoxyethyl]-1,3-thiazole
    —— methyl 2,4-dimethyl-5-[(2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C14H18N4O3S
    methyl 2,4-dimethyl-5-[(2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H15N5OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H22N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methylpropyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 4-Methyl-2-thiophen-2-ylsulfanylpyrimidine —— C9H8N2S2
    4-Methyl-2-thiophen-2-ylsulfanylpyrimidine
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H17FN4OS
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H15ClN4OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (3R)-N-[2-(dimethylamino)ethyl]-N-(pyridin-4-ylmethyl)-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H23N3OS
    (3R)-N-[2-(dimethylamino)ethyl]-N-(pyridin-4-ylmethyl)-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[4-(2-methyl-6-oxopyridin-1-yl)butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H22N2O2S
    (3S)-N-[4-(2-methyl-6-oxopyridin-1-yl)butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[4-(2-methyl-6-oxopyridin-1-yl)butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H22N2O2S
    (3R)-N-[4-(2-methyl-6-oxopyridin-1-yl)butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-3-(1-tert-butylimidazol-2-yl)sulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one —— C13H18F3N3OS
    (3R)-3-(1-tert-butylimidazol-2-yl)sulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one
    —— (3R)-N-[(R)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C21H18N2OS
    (3R)-N-[(R)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-(2-cyanoethyl)-N-[(1R)-1-cyclopropylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C17H20N2OS
    (3R)-N-(2-cyanoethyl)-N-[(1R)-1-cyclopropylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[2-(dimethylamino)ethyl]-N-(pyridin-4-ylmethyl)-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H23N3OS
    (3S)-N-[2-(dimethylamino)ethyl]-N-(pyridin-4-ylmethyl)-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-3-thiophen-2-ylsulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one —— C10H10F3NOS2
    (3R)-3-thiophen-2-ylsulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one
    —— (3S)-N-(2-cyanoethyl)-N-[(1S)-1-cyclopropylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C17H20N2OS
    (3S)-N-(2-cyanoethyl)-N-[(1S)-1-cyclopropylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H20N2OS
    (3R)-N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[(S)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C21H18N2OS
    (3S)-N-[(S)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[(2-ethyl-1,3-thiazol-4-yl)methyl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C16H18N2OS2
    (3S)-N-[(2-ethyl-1,3-thiazol-4-yl)methyl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-3-thiophen-2-ylsulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one —— C10H10F3NOS2
    (3S)-3-thiophen-2-ylsulfanyl-1-(2,2,2-trifluoroethyl)pyrrolidin-2-one
    —— (3R)-N-[(2-ethyl-1,3-thiazol-4-yl)methyl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C16H18N2OS2
    (3R)-N-[(2-ethyl-1,3-thiazol-4-yl)methyl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H20N2OS
    (3S)-N-[(1S)-2-methyl-1-pyridin-4-ylpropyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[(S)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C21H18N2OS
    (3R)-N-[(S)-phenyl(pyridin-3-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[(1-butyltetrazol-5-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C15H19N5OS
    (3R)-N-[(1-butyltetrazol-5-yl)methyl]-2,3-dihydro-1-benzothiophene-3-carboxamide