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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R,3S)-1-cyano-3-methylcyclohexyl]-2-propylsulfonylacetamide —— C13H22N2O3S
    N-[(1R,3S)-1-cyano-3-methylcyclohexyl]-2-propylsulfonylacetamide
    —— N-[(1S,3R)-1-cyano-3-methylcyclohexyl]-2-propylsulfonylacetamide —— C13H22N2O3S
    N-[(1S,3R)-1-cyano-3-methylcyclohexyl]-2-propylsulfonylacetamide
    —— 2-cyclopentylsulfonyl-N-[(3S)-1-(dimethylamino)-4,4-dimethylpentan-3-yl]acetamide —— C16H32N2O3S
    2-cyclopentylsulfonyl-N-[(3S)-1-(dimethylamino)-4,4-dimethylpentan-3-yl]acetamide
    —— 2-cyclopentylsulfonyl-N-[(3R)-1-(dimethylamino)-4,4-dimethylpentan-3-yl]acetamide —— C16H32N2O3S
    2-cyclopentylsulfonyl-N-[(3R)-1-(dimethylamino)-4,4-dimethylpentan-3-yl]acetamide
    —— 5-[(4-chlorophenyl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole —— C13H15ClN2O2S
    5-[(4-chlorophenyl)sulfanylmethyl]-3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— 1-ethyl-3-(6-ethylsulfanylpyridin-3-yl)-1-[(1R)-1-pyridin-3-ylethyl]urea —— C17H22N4OS
    1-ethyl-3-(6-ethylsulfanylpyridin-3-yl)-1-[(1R)-1-pyridin-3-ylethyl]urea
    —— 5-[(4-chlorophenyl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole —— C13H15ClN2O2S
    5-[(4-chlorophenyl)sulfanylmethyl]-3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazole
    —— ethyl (3S)-3-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanoate —— C11H13F3N2O2S
    ethyl (3S)-3-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanoate
    —— ethyl (3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutanoate —— C10H13BrN2O2S
    ethyl (3R)-3-(5-bromopyrimidin-2-yl)sulfanylbutanoate
    —— 1-ethyl-3-(6-ethylsulfanylpyridin-3-yl)-1-[(1S)-1-pyridin-3-ylethyl]urea —— C17H22N4OS
    1-ethyl-3-(6-ethylsulfanylpyridin-3-yl)-1-[(1S)-1-pyridin-3-ylethyl]urea
    —— ethyl (3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutanoate —— C10H13BrN2O2S
    ethyl (3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutanoate
    —— ethyl (3R)-3-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanoate —— C11H13F3N2O2S
    ethyl (3R)-3-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylbutanoate
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C13H15F2NO3S2
    2-(2,4-difluorophenyl)sulfanyl-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C17H17F2NOS2
    2-(2,4-difluorophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-(2-phenylsulfanylethyl)acetamide —— C16H15F2NOS2
    2-(2,4-difluorophenyl)sulfanyl-N-(2-phenylsulfanylethyl)acetamide
    —— N-[(3R,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C12H12ClF2NO3S2
    N-[(3R,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]acetamide —— C16H15F2NOS
    2-(2,5-difluorophenyl)sulfanyl-N-[(4-methylphenyl)methyl]acetamide
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C16H14BrF2NOS
    N-[(1R)-1-(2-bromophenyl)ethyl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[2-[(2-fluorophenyl)methylsulfanyl]ethyl]acetamide —— C17H16F3NOS2
    2-(2,4-difluorophenyl)sulfanyl-N-[2-[(2-fluorophenyl)methylsulfanyl]ethyl]acetamide
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C16H14BrF2NOS
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C12H12ClF2NO3S2
    N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— 2-[(2,4-Difluorophenyl)sulfanylmethyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole —— C15H12F2N2O2S
    2-[(2,4-Difluorophenyl)sulfanylmethyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole
    —— N-(1-adamantylmethyl)-2-(2,4-difluorophenyl)sulfanylacetamide —— C19H23F2NOS
    N-(1-adamantylmethyl)-2-(2,4-difluorophenyl)sulfanylacetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide —— C18H19F2NOS
    2-(2,4-difluorophenyl)sulfanyl-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(2,4-difluorophenyl)sulfanylethanone —— C16H15F2NO2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(2,4-difluorophenyl)sulfanylethanone
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C14H16F2N2OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C15H19F2NOS
    2-(2,4-difluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-2-(2,4-difluorophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]propanamide —— C16H21F2NOS
    (2R)-2-(2,4-difluorophenyl)sulfanyl-N-[(1S,2S)-2-methylcyclohexyl]propanamide
    —— (2S)-N-(1-adamantyl)-2-(2,4-difluorophenyl)sulfanylpropanamide —— C19H23F2NOS
    (2S)-N-(1-adamantyl)-2-(2,4-difluorophenyl)sulfanylpropanamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide —— C18H19F2NOS
    2-(2,4-difluorophenyl)sulfanyl-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide
    —— N-(1-cyanocyclohexyl)-2-(2,4-difluorophenyl)sulfanyl-N-methylacetamide —— C16H18F2N2OS
    N-(1-cyanocyclohexyl)-2-(2,4-difluorophenyl)sulfanyl-N-methylacetamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]acetamide —— C16H14F3NOS
    2-(2,4-difluorophenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— (2R)-2-(2,4-difluorophenyl)sulfanylpropanamide —— C9H9F2NOS
    (2R)-2-(2,4-difluorophenyl)sulfanylpropanamide
    —— N-[(2-chlorophenyl)methyl]-2-(2,4-difluorophenyl)sulfanylacetamide —— C15H12ClF2NOS
    N-[(2-chlorophenyl)methyl]-2-(2,4-difluorophenyl)sulfanylacetamide
    —— (2R)-2-(2,4-difluorophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclohexyl]propanamide —— C16H21F2NOS
    (2R)-2-(2,4-difluorophenyl)sulfanyl-N-[(1S,2R)-2-methylcyclohexyl]propanamide
    —— (2R)-N-cyclohexyl-2-(2,4-difluorophenyl)sulfanylpropanamide —— C15H19F2NOS
    (2R)-N-cyclohexyl-2-(2,4-difluorophenyl)sulfanylpropanamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-(furan-2-ylmethyl)acetamide —— C13H11F2NO2S
    2-(2,4-difluorophenyl)sulfanyl-N-(furan-2-ylmethyl)acetamide
    —— N-[(4-chlorophenyl)methyl]-3-(3,4-difluorophenyl)sulfanylpropanamide —— C16H14ClF2NOS
    N-[(4-chlorophenyl)methyl]-3-(3,4-difluorophenyl)sulfanylpropanamide
    —— (2S)-N-cyclohexyl-2-cyclopentylsulfonyl-N-methylpropanamide —— C15H27NO3S
    (2S)-N-cyclohexyl-2-cyclopentylsulfonyl-N-methylpropanamide
    —— (2R)-N-cyclohexyl-2-cyclopentylsulfonyl-N-methylpropanamide —— C15H27NO3S
    (2R)-N-cyclohexyl-2-cyclopentylsulfonyl-N-methylpropanamide
    —— 2-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole —— C17H15ClN2O2S
    2-[(Z)-1-chloro-2-(4-methylsulfanylphenyl)ethenyl]-5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazole
    —— 2-[3-[(Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-enyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazol-4-yl]acetamide —— C20H28N4O2S2
    2-[3-[(Z)-2-tert-butyl-5,5-dimethyl-4-oxohex-2-enyl]sulfanyl-5-thiophen-2-yl-1,2,4-triazol-4-yl]acetamide
    —— (Z)-3-(5-bromothiophen-2-yl)-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]prop-2-enamide —— C17H14BrN3OS2
    (Z)-3-(5-bromothiophen-2-yl)-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]prop-2-enamide
    —— 2-[[5-cyclohexyl-4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C21H29N5O2S
    2-[[5-cyclohexyl-4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (Z)-3-pyridin-2-yl-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)prop-2-enamide —— C18H14N4OS
    (Z)-3-pyridin-2-yl-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)prop-2-enamide
    —— (Z)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-3-(1-methylpyrazol-4-yl)prop-2-enamide —— C19H19N5OS
    (Z)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-3-(1-methylpyrazol-4-yl)prop-2-enamide
    —— (Z)-N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-(1-methylpyrazol-4-yl)prop-2-enamide —— C18H26N6OS
    (Z)-N-[3-(4-cyclopentyl-5-methylsulfanyl-1,2,4-triazol-3-yl)propyl]-3-(1-methylpyrazol-4-yl)prop-2-enamide
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(2-fluorophenyl)sulfanylacetamide —— C18H20FNOS
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[6-amino-1-(2-methylpropyl)-2,4-dioxopyrimidin-5-yl]-N-butyl-2-(2-fluorophenyl)sulfanylacetamide —— C20H27FN4O3S
    N-[6-amino-1-(2-methylpropyl)-2,4-dioxopyrimidin-5-yl]-N-butyl-2-(2-fluorophenyl)sulfanylacetamide
    —— (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate —— C16H10FN2O3S2-
    (E)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-(3-methylthiophen-2-yl)prop-2-enoate