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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H19FN4O2S2
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 1-[2-[[5-[(2-Methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C13H14N4O3S2
    1-[2-[[5-[(2-Methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— (2S)-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C10H12N4O2S2
    (2S)-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazole —— C18H16N4OS3
    2-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazole
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazole —— C14H12ClN3OS2
    2-[(4-Chlorophenyl)methylsulfanyl]-5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazole
    —— (2R)-N-cyclopropyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C13H16N4O2S2
    (2R)-N-cyclopropyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide —— C12H16N4O2S2
    2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C17H18N4O2S2
    2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-[[5-[(2-Methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-morpholin-4-ylethanone —— C13H16N4O3S2
    2-[[5-[(2-Methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-morpholin-4-ylethanone
    —— N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H22N4O2S2
    N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4,6-diamino-1,3,5-triazin-2-yl)sulfanyl]-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C19H20N6OS2
    2-[(4,6-diamino-1,3,5-triazin-2-yl)sulfanyl]-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— [(1R)-1-[5-[2-(1-adamantylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium —— C19H31N4O2S+
    [(1R)-1-[5-[2-(1-adamantylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium
    —— (2R)-2-phenylsulfanyl-N-(thiophen-2-ylmethyl)propanamide —— C14H15NOS2
    (2R)-2-phenylsulfanyl-N-(thiophen-2-ylmethyl)propanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C13H15N3O5S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H17BrN4OS
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H17BrN4OS
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C19H21N3O3S
    (2S)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— Methyl 3-[3-[2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate —— C18H19N3O5S
    Methyl 3-[3-[2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2,5-dimethylpyrrol-1-yl]propanoate
    —— 3-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C9H7N3O2S
    3-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— [2-[(4-chlorophenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C18H18ClNO3S
    [2-[(4-chlorophenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-(2-cyanoethylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C14H16N2O3S
    [2-(2-cyanoethylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[(1-cyanocyclopentyl)amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C17H20N2O3S
    [2-[(1-cyanocyclopentyl)amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C18H25NO3S
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— methyl 2,4-dimethyl-5-[(2R)-2-[(2S)-2-phenylsulfanylpropanoyl]oxypropanoyl]-1H-pyrrole-3-carboxylate —— C20H23NO5S
    methyl 2,4-dimethyl-5-[(2R)-2-[(2S)-2-phenylsulfanylpropanoyl]oxypropanoyl]-1H-pyrrole-3-carboxylate
    —— [2-(2-acetylhydrazinyl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C13H16N2O4S
    [2-(2-acetylhydrazinyl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C15H19NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] (2R)-2-phenylsulfanylpropanoate —— C20H20N2O3S
    [2-oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-oxo-2-(propan-2-ylcarbamoylamino)ethyl] (2S)-2-phenylsulfanylpropanoate —— C15H20N2O4S
    [2-oxo-2-(propan-2-ylcarbamoylamino)ethyl] (2S)-2-phenylsulfanylpropanoate
    —— 1-(5-Bromothiophen-2-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C16H13BrN2O2S2
    1-(5-Bromothiophen-2-yl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C18H18N2OS3
    2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C18H23N3O3S
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— methyl (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C14H16N2O3S
    methyl (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 2-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C18H17ClN2OS
    2-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C15H19NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C17H21N3O3S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]-N-methylacetamide —— C20H20FN3O2S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]-N-methylacetamide
    —— (2S)-N-cyclopentyl-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanamide —— C18H22N2OS2
    (2S)-N-cyclopentyl-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]propanamide
    —— 2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C20H20N2OS2
    2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C18H21N3OS2
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— 2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C20H20N2OS2
    2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— [(1R)-1-[4-benzyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C19H26N5S2+
    [(1R)-1-[4-benzyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H28N4OS
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C16H15N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C18H20N4O2S
    1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-[(1S)-1-phenylethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H18N4OS
    N-[(1S)-1-phenylethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (3S)-3-[3-(2-methoxyethyl)-5-(pyridin-4-ylsulfanylmethyl)-1,2,4-triazol-1-yl]thiolane 1,1-dioxide —— C15H20N4O3S2
    (3S)-3-[3-(2-methoxyethyl)-5-(pyridin-4-ylsulfanylmethyl)-1,2,4-triazol-1-yl]thiolane 1,1-dioxide
    —— (3R)-3-[3-(2-methoxyethyl)-5-(pyridin-4-ylsulfanylmethyl)-1,2,4-triazol-1-yl]thiolane 1,1-dioxide —— C15H20N4O3S2
    (3R)-3-[3-(2-methoxyethyl)-5-(pyridin-4-ylsulfanylmethyl)-1,2,4-triazol-1-yl]thiolane 1,1-dioxide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C19H25N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C19H25N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— 2-(3,5-Dimethylphenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazole —— C17H15FN2OS
    2-(3,5-Dimethylphenyl)-5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazole