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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-(2-Bromo-3-phenyl-2-propenylidene)-2-((4-(2-(2-(2-bromo-3-phenyl-2-propenylidene)hydrazino)-2-oxoethoxy)-6-methyl-2-pyrimidinyl)thio)acetohydrazide —— C27H24Br2N6O3S
    N'-(2-Bromo-3-phenyl-2-propenylidene)-2-((4-(2-(2-(2-bromo-3-phenyl-2-propenylidene)hydrazino)-2-oxoethoxy)-6-methyl-2-pyrimidinyl)thio)acetohydrazide
    —— (2E)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone —— C19H21N3OS
    (2E)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone
    —— N-[1-[4-[4-[(E)-N-(2,4-dinitroanilino)-C-methylcarbonimidoyl]phenyl]sulfanylphenyl]ethylideneamino]-2,4-dinitroaniline —— C28H22N8O8S
    N-[1-[4-[4-[(E)-N-(2,4-dinitroanilino)-C-methylcarbonimidoyl]phenyl]sulfanylphenyl]ethylideneamino]-2,4-dinitroaniline
    —— 2-[[5-[(2E)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C15H19BrN6OS
    2-[[5-[(2E)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethanone —— C20H23N5O2S2
    2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethanone
    —— N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H12ClN5OS
    N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 4,10-dihydroimidazo[5,1-c][1,4]benzothiazepine-3-carboxylic acid —— C12H10N2O2S
    4,10-dihydroimidazo[5,1-c][1,4]benzothiazepine-3-carboxylic acid
    —— 3-ethyl-5-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-1,2,4-oxadiazole —— C13H13N5OS2
    3-ethyl-5-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-1,2,4-oxadiazole
    —— 5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-3-(2-methylprop-2-enylsulfanyl)-1H-1,2,4-triazole —— C13H15N3OS
    5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-3-(2-methylprop-2-enylsulfanyl)-1H-1,2,4-triazole
    —— N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-[(3-ethyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide —— C14H16ClN5OS
    N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-[(3-ethyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide
    —— N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H12ClN5OS
    N-[(E)-1-(4-chlorophenyl)ethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-[(3-ethyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide —— C14H16ClN5OS
    N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-[(3-ethyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide
    —— (3-Benzylsulfanyl-(1,2,4)triazol-4-YL)-(4-bromo-benzylidene)-amine —— C16H13BrN4S
    (3-Benzylsulfanyl-(1,2,4)triazol-4-YL)-(4-bromo-benzylidene)-amine
    —— 2-(4-chlorophenyl)sulfanyl-3-[(E)-(phenylhydrazinylidene)methyl]pyrido[1,2-a]pyrimidin-4-one —— C21H15ClN4OS
    2-(4-chlorophenyl)sulfanyl-3-[(E)-(phenylhydrazinylidene)methyl]pyrido[1,2-a]pyrimidin-4-one
    —— 2-[(4,6-dimethyl-2-pyrimidinyl)thio]-N'-(2-thienylmethylene)propanohydrazide —— C14H16N4OS2
    2-[(4,6-dimethyl-2-pyrimidinyl)thio]-N'-(2-thienylmethylene)propanohydrazide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]ethanamine —— C20H19FN2S
    2-(2-fluorophenyl)sulfanyl-N-[(S)-phenyl(pyridin-2-yl)methyl]ethanamine
    —— 4-Oxo-2-(2-pyridinylsulfanyl)-4H-pyrido[1,2-A]pyrimidine-3-carbaldehyde thiosemicarbazone —— C15H12N6OS2
    4-Oxo-2-(2-pyridinylsulfanyl)-4H-pyrido[1,2-A]pyrimidine-3-carbaldehyde thiosemicarbazone
    —— 2-(2-fluorophenyl)sulfanyl-N-[(R)-phenyl(pyridin-2-yl)methyl]ethanamine —— C20H19FN2S
    2-(2-fluorophenyl)sulfanyl-N-[(R)-phenyl(pyridin-2-yl)methyl]ethanamine
    —— 4-cyano-2-fluoro-N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}benzohydrazide —— C19H12FN3O2S
    4-cyano-2-fluoro-N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}benzohydrazide
    —— 3-[(3-bromobenzyl)sulfanyl]-N-[(E)-(4-fluorophenyl)methylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C17H12BrFN6S
    3-[(3-bromobenzyl)sulfanyl]-N-[(E)-(4-fluorophenyl)methylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide —— C17H12N4O3S
    N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide
    —— N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-methoxyacetohydrazide —— C15H13N3O3S2
    N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-methoxyacetohydrazide
    —— N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-cyanoacetohydrazide —— C15H10N4O2S2
    N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-cyanoacetohydrazide
    —— 4-Methoxy-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide —— C22H17N3O3S
    4-Methoxy-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide
    —— 5-bromo-4-oxo-2,3-dihydrothieno[3,4-b]thiopyran-7-carbaldehyde —— C8H5BrO2S2
    5-bromo-4-oxo-2,3-dihydrothieno[3,4-b]thiopyran-7-carbaldehyde
    —— N'-[(E)-(3-Bromophenyl)methylidene]-2-[(4-chlorophenyl)sulfanyl]acetohydrazide —— C15H12BrClN2OS
    N'-[(E)-(3-Bromophenyl)methylidene]-2-[(4-chlorophenyl)sulfanyl]acetohydrazide
    —— N-[(E)-benzylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H13ClN2OS
    N-[(E)-benzylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— N-[(E)-(3-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C13H13N3O2S
    N-[(E)-(3-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— 5-[[2-(2-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C18H21N5OS3
    5-[[2-(2-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]pyridine-4-carboxamide —— C16H12N4O2S
    N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]pyridine-4-carboxamide
    —— 5-[[2-(2-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C18H21N5OS3
    5-[[2-(2-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 1-[(Z)-nonylideneamino]-3-(nonylideneamino)thiourea —— C19H38N4S
    1-[(Z)-nonylideneamino]-3-(nonylideneamino)thiourea
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C18H20N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-(4-chlorophenyl)sulfanyl-3-[(E)-hydroxyiminomethyl]pyrido[1,2-a]pyrimidin-4-one —— C15H10ClN3O2S
    2-(4-chlorophenyl)sulfanyl-3-[(E)-hydroxyiminomethyl]pyrido[1,2-a]pyrimidin-4-one
    —— 6-{[3-(Trifluoromethyl)phenyl]sulfanyl}imidazo[2,1-b][1,3]thiazole-5-carbaldehyde oxime —— C13H8F3N3OS2
    6-{[3-(Trifluoromethyl)phenyl]sulfanyl}imidazo[2,1-b][1,3]thiazole-5-carbaldehyde oxime
    —— 6-[(4-Methylphenyl)sulfanyl]nicotinaldehyde oxime —— C13H12N2OS
    6-[(4-Methylphenyl)sulfanyl]nicotinaldehyde oxime
    —— 1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde oxime —— C12H10F3N3OS
    1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde oxime
    —— N'-[(E)-(2-chloro-6-fluorophenyl)methylidene]-2-[(4,6-dimethyl-2-pyrimidinyl)thio]acetohydrazide —— C15H14ClFN4OS
    N'-[(E)-(2-chloro-6-fluorophenyl)methylidene]-2-[(4,6-dimethyl-2-pyrimidinyl)thio]acetohydrazide
    —— N-(benzoyloxy)-N-{[1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylene}amine —— C19H14F3N3O2S
    N-(benzoyloxy)-N-{[1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylene}amine
    —— 6-[(3-Chlorobenzyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde oxime —— C13H10ClN3OS2
    6-[(3-Chlorobenzyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde oxime
    —— (E)-{[1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylidene}amino 2-chloroacetate —— C14H11ClF3N3O2S
    (E)-{[1-methyl-5-(phenylsulfanyl)-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylidene}amino 2-chloroacetate
    —— N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4-cyano-2-fluorobenzohydrazide —— C20H12FN5O2S
    N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-4-cyano-2-fluorobenzohydrazide
    —— N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}acetohydrazide —— C13H12N2O2S
    N'-{(E)-[5-(phenylsulfanyl)furan-2-yl]methylidene}acetohydrazide
    —— N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]furan-2-carbohydrazide —— C24H17N5O3S
    N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]furan-2-carbohydrazide
    —— (2E)-N-methyl-2-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]hydrazinecarbothioamide —— C14H13N5O2S2
    (2E)-N-methyl-2-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]hydrazinecarbothioamide
    —— (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(furan-2-yl)methanimine —— C15H14N4OS
    (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(furan-2-yl)methanimine
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine —— C16H13ClN4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine
    —— N'-[(E)-(3-fluorophenyl)methylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide —— C14H12FN3OS
    N'-[(E)-(3-fluorophenyl)methylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide
    —— 2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-(4-ethylphenyl)methylidene]acetohydrazide —— C17H20N4OS
    2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-(4-ethylphenyl)methylidene]acetohydrazide
    —— 3-(4-bromophenyl)-4-methylsulfanyl-1,2,5-thiadiazole —— C9H7BrN2S2
    3-(4-bromophenyl)-4-methylsulfanyl-1,2,5-thiadiazole