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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (6R,7R)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C15H13NO6S2
    (6R,7R)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— dimethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C10H9NO5S2
    dimethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— dimethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C10H9NO5S2
    dimethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6S,7R)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C19H22N2O5S2
    (6S,7R)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (6R,7S)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C19H22N2O5S2
    (6R,7S)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C13H9NO4S2
    (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C13H9NO4S2
    (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— diethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C12H13NO5S2
    diethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6R,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C15H13NO6S2
    (6R,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— diethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C12H13NO5S2
    diethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6R,7S)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C17H18N2O5S2
    (6R,7S)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— N-[2-(N-ethyl-3-methylanilino)ethyl]-2-phenylsulfanylacetamide —— C19H24N2OS
    N-[2-(N-ethyl-3-methylanilino)ethyl]-2-phenylsulfanylacetamide
    —— (Z)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-(1,3-thiazol-2-yl)prop-2-enamide —— C15H13N5OS2
    (Z)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-(1,3-thiazol-2-yl)prop-2-enamide
    —— methyl (2Z)-2-[4-oxo-3-(3-pyridin-2-ylsulfanylpropyl)-1,3-thiazolidin-2-ylidene]acetate —— C14H16N2O3S2
    methyl (2Z)-2-[4-oxo-3-(3-pyridin-2-ylsulfanylpropyl)-1,3-thiazolidin-2-ylidene]acetate
    —— [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H15F2NO3S2
    [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C15H19F2NO3S
    [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C15H19F2NO3S
    [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C14H17F2NO4S
    [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H16ClF2NO3S
    [(2S)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H23F2NO3S
    [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H15F2NO3S2
    [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-[(1-cyanocyclohexyl)-methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C19H22F2N2O3S
    [(2R)-1-[(1-cyanocyclohexyl)-methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— (2S)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)propanamide —— C17H30N6O3S
    (2S)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)propanamide
    —— (5S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— (2R)-N-tert-butyl-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H19ClN4OS2
    (2R)-N-tert-butyl-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (5S,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5S,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid —— C13H9F3N2O3S
    (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid
    —— (5R,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5R,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid —— C13H9F3N2O3S
    (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid
    —— (5R,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5R,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— [(2S)-1-oxo-1-(2-oxoimidazolidin-1-yl)propan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate —— C16H20N2O4S
    [(2S)-1-oxo-1-(2-oxoimidazolidin-1-yl)propan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O4S
    [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H21N3O3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H21N3O3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O4S
    [2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— (Z)-1,4-bis(2-methylsulfonylethylsulfanyl)but-2-ene —— C10H20O4S4
    (Z)-1,4-bis(2-methylsulfonylethylsulfanyl)but-2-ene
    —— (Z)-N-[4-(2-chlorophenyl)sulfanylphenyl]-3-pyrazin-2-ylprop-2-enamide —— C19H14ClN3OS
    (Z)-N-[4-(2-chlorophenyl)sulfanylphenyl]-3-pyrazin-2-ylprop-2-enamide
    —— (Z)-3-pyridin-2-yl-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]prop-2-enamide —— C16H12N4OS2
    (Z)-3-pyridin-2-yl-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]prop-2-enamide
    —— 1-propan-2-yl-5-[(Z)-4-(1-propan-2-yltetrazol-5-yl)sulfanylbut-2-enyl]sulfanyltetrazole —— C12H20N8S2
    1-propan-2-yl-5-[(Z)-4-(1-propan-2-yltetrazol-5-yl)sulfanylbut-2-enyl]sulfanyltetrazole
    —— (2Z,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2Z,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— (2E,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2E,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— (2Z,4E)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2Z,4E)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— 3-[(Z)-3-chloroprop-2-enyl]sulfanyl-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine —— C10H14ClN3S
    3-[(Z)-3-chloroprop-2-enyl]sulfanyl-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine
    —— [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate —— C16H20FNO5S2
    [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate
    —— (2R)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C14H17FN4O2S2
    (2R)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— 2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C15H18N4O2S
    2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 3-[5-[2-(Cyclohexylamino)-2-oxoethyl]sulfanyl-4-(2-methylpropyl)-1,2,4-triazol-3-yl]propanamide —— C17H29N5O2S
    3-[5-[2-(Cyclohexylamino)-2-oxoethyl]sulfanyl-4-(2-methylpropyl)-1,2,4-triazol-3-yl]propanamide