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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl (2R)-2-phenylsulfanylpropanoate —— C18H27NO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl (2R)-2-phenylsulfanylpropanoate
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(4-nitrobenzyl)oxime —— C20H14ClN3O5S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(4-nitrobenzyl)oxime
    —— 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C21H16Cl2N2O3S
    4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 2-methoxyethyl (2R)-2-phenylsulfanylpropanoate —— C12H16O3S
    2-methoxyethyl (2R)-2-phenylsulfanylpropanoate
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate —— C18H27NO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— N-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide —— C19H13ClF3N3O2S2
    N-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide
    —— 1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(E)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide —— C20H17Cl2N5O2S
    1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(E)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide
    —— N,N-dimethyl-N'-(5-octadecylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide —— C23H44N4S2
    N,N-dimethyl-N'-(5-octadecylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide
    —— 1-(4-chlorophenyl)-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C20H13Cl2F3N4S2
    1-(4-chlorophenyl)-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— 1-(4-chlorophenyl)-3-[(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea —— C19H13Cl2N5S3
    1-(4-chlorophenyl)-3-[(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea
    —— [(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea —— C13H10ClN5S3
    [(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea
    —— 2-(Methylthio)thiophene-3-carbaldehyde oxime —— C6H7NOS2
    2-(Methylthio)thiophene-3-carbaldehyde oxime
    —— N'-[(E)-[5-(Phenylsulfanyl)furan-2-YL]methylidene]pyridine-4-carbohydrazide —— C17H13N3O2S
    N'-[(E)-[5-(Phenylsulfanyl)furan-2-YL]methylidene]pyridine-4-carbohydrazide
    —— (1S)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine —— C21H19FN6O2S
    (1S)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine
    —— (1R)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine —— C21H19FN6O2S
    (1R)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine
    —— 2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide —— C16H15ClN2OS
    2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide
    —— N-[(E)-(4-fluorophenyl)methylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C11H9FN6S
    N-[(E)-(4-fluorophenyl)methylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— N-[(E)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide —— C16H19N5OS
    N-[(E)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide
    —— S-methyl (2Z)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate; S-methyl (2Z)-5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate —— C27H28N6O4S7
    S-methyl (2Z)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate; S-methyl (2Z)-5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-(4-chloro-phenyl)-4-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C24H17ClN6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-(4-chloro-phenyl)-4-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-chloro-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C24H17ClN6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-chloro-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-phenyl-3-p-tolyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C25H20N6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-phenyl-3-p-tolyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— N-[(E)-[3-(3-bromophenyl)-4-phenyl-thiazol-2-ylidene]amino]-2-[[5-(2-pyridyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C24H17BrN6OS3
    N-[(E)-[3-(3-bromophenyl)-4-phenyl-thiazol-2-ylidene]amino]-2-[[5-(2-pyridyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-phenyl-4-p-tolyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C25H20N6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-phenyl-4-p-tolyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-bromo-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C24H17BrN6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-bromo-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— [(5-pyridin-2-yl)-1,3,4-thiadiazol-2-ylthio]acetic acid (3,4-diphenyl-3H-thiazol-2-ylidene)hydrazide —— C24H18N6OS3
    [(5-pyridin-2-yl)-1,3,4-thiadiazol-2-ylthio]acetic acid (3,4-diphenyl-3H-thiazol-2-ylidene)hydrazide
    —— 1-[(E)-1-(1-adamantyl)ethylideneamino]-3-amino-thiourea —— C13H22N4S
    1-[(E)-1-(1-adamantyl)ethylideneamino]-3-amino-thiourea
    —— (2E,4Z)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide —— C18H16N2O3S
    (2E,4Z)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide
    —— (2Z,4Z)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide —— C18H16N2O3S
    (2Z,4Z)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide
    —— (3Z)-3-[[2-[2-[(2Z)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid —— C26H18N4O6S
    (3Z)-3-[[2-[2-[(2Z)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid
    —— (Z)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]-3-pyridin-3-ylprop-2-enamide —— C17H18N2OS
    (Z)-N-methyl-N-[(4-methylsulfanylphenyl)methyl]-3-pyridin-3-ylprop-2-enamide
    —— 1-[3-nitro-4-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]phenyl]sulfonylpiperidine —— C19H19N5O4S3
    1-[3-nitro-4-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]phenyl]sulfonylpiperidine
    —— (2Z,4E)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide —— C18H16N2O3S
    (2Z,4E)-N-[4-(4-nitrophenyl)sulfanylphenyl]hexa-2,4-dienamide
    —— 2-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]pyridine-3-carbonitrile —— C14H9N5S2
    2-[[5-[(Z)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]pyridine-3-carbonitrile
    —— disodium;(3E)-3-[[4-[4-[(2E)-2-(3-carboxylato-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylate —— C26H16N4Na2O6S
    disodium;(3E)-3-[[4-[4-[(2E)-2-(3-carboxylato-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylate
    —— (3E)-3-[[4-[4-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid —— C26H18N4O6S
    (3E)-3-[[4-[4-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid
    —— (2R)-2-[[(E)-3-[(S)-methylsulfinyl]prop-2-enyl]disulfanyl]butane —— C8H16OS3
    (2R)-2-[[(E)-3-[(S)-methylsulfinyl]prop-2-enyl]disulfanyl]butane
    —— 1-(amino-lambda4-sulfanylidyne)-N-[(E)-1-(4-chloro-2,5-dimethylphenyl)sulfanylpropan-2-ylideneamino]methanamine —— C12H16ClN3S2
    1-(amino-lambda4-sulfanylidyne)-N-[(E)-1-(4-chloro-2,5-dimethylphenyl)sulfanylpropan-2-ylideneamino]methanamine
    —— 1-[(4R)-4-amino-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophen-1-yl]ethanone —— C11H15NOS2
    1-[(4R)-4-amino-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophen-1-yl]ethanone
    —— 1-[(4S)-4-amino-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophen-1-yl]ethanone —— C11H15NOS2
    1-[(4S)-4-amino-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophen-1-yl]ethanone
    —— (6E)-4-amino-3-[(2,5-dichlorophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid —— C34H23Cl2N7O8S3
    (6E)-4-amino-3-[(2,5-dichlorophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid
    —— methyl N'-[(E)-[(1E)-1-[(Z)-[amino(methylsulfanyl)methylidene]hydrazinylidene]propan-2-ylidene]amino]carbamimidothioate —— C7H14N6S2
    methyl N'-[(E)-[(1E)-1-[(Z)-[amino(methylsulfanyl)methylidene]hydrazinylidene]propan-2-ylidene]amino]carbamimidothioate
    —— 2-(5-methyl-7-methylsulfanylimidazo[5,1-b][1,3]thiazol-2-yl)acetic acid —— C9H10N2O2S2
    2-(5-methyl-7-methylsulfanylimidazo[5,1-b][1,3]thiazol-2-yl)acetic acid
    —— N'-{3-nitro-4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]benzylidene}octanohydrazide —— C19H25N5O3S
    N'-{3-nitro-4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]benzylidene}octanohydrazide
    —— (E)-1-(furan-2-yl)-N-(5-phenylsulfanyl-1H-indol-2-yl)methanimine —— C19H14N2OS
    (E)-1-(furan-2-yl)-N-(5-phenylsulfanyl-1H-indol-2-yl)methanimine
    —— N'-[(E)-furan-2-ylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C11H10N4O2S
    N'-[(E)-furan-2-ylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 1-[(E)-(6-chloro-2,3-dihydroimidazo[2,1-b]thiazol-5-yl)methyleneamino]guanidine —— C7H9ClN6S
    1-[(E)-(6-chloro-2,3-dihydroimidazo[2,1-b]thiazol-5-yl)methyleneamino]guanidine