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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-dimethylamino-7-methyl-5,7-dihydro-3<i>H</i>-thieno[3,4-<i>d</i>]pyrimidin-4-one 5719-28-8 C9H13N3OS
    2-dimethylamino-7-methyl-5,7-dihydro-3<i>H</i>-thieno[3,4-<i>d</i>]pyrimidin-4-one
    —— 5-Methylsulfanyl-2-oxo-2H-pyridine-1-carboxylic acid methylamide 25764-82-3 C8H10N2O2S
    5-Methylsulfanyl-2-oxo-2H-pyridine-1-carboxylic acid methylamide
    —— 2-Amino-5-cyanomethylthio-pyrrol-3,4-dicarbonitril 170953-52-3 C8H5N5S
    2-Amino-5-cyanomethylthio-pyrrol-3,4-dicarbonitril
    —— S-butyl-S-(1,1-dimethylethyl)sulfoximine 118657-18-4 C8H19NOS
    S-butyl-S-(1,1-dimethylethyl)sulfoximine
    —— 4-(phenylthio)benzohydroxamic acid 77868-25-8 C13H11NO2S
    4-(phenylthio)benzohydroxamic acid
    —— 4-(4-Chloro-phenylsulfanyl)-4-(2-hydroxy-ethyl)-3-isopropylidene-azetidin-2-one 101166-68-1 C14H16ClNO2S
    4-(4-Chloro-phenylsulfanyl)-4-(2-hydroxy-ethyl)-3-isopropylidene-azetidin-2-one
    —— 1-Butanethiol, 2-amino-4-(methylthio)-, (2S)- 139428-86-7 C5H13NS2
    1-Butanethiol, 2-amino-4-(methylthio)-, (2S)-
    —— 2-benzylsulfanyl-4,5,6,7-tetrahydro-benzothiazole 23920-76-5 C14H15NS2
    2-benzylsulfanyl-4,5,6,7-tetrahydro-benzothiazole
    —— 3-(Furan-2-ylsulfanyl)-propan-1-ol 127505-91-3 C7H10O2S
    3-(Furan-2-ylsulfanyl)-propan-1-ol
    —— N'-(1-(2-chlorophenyl)ethylidene)-2-[(1-methyl-1H-tetrazol-5-yl)thio]acetohydrazide 1416371-01-1 C12H13ClN6OS
    N'-(1-(2-chlorophenyl)ethylidene)-2-[(1-methyl-1H-tetrazol-5-yl)thio]acetohydrazide
    —— 1-(3,6-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-yl)-6-(6-methyl-4-oxo-2-thiadecyl-1,2,3,4-tetrahydropyrimidin-5-yl)hexane 1254971-15-7 C27H44N4O3S
    1-(3,6-dimethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-yl)-6-(6-methyl-4-oxo-2-thiadecyl-1,2,3,4-tetrahydropyrimidin-5-yl)hexane
    —— ethyl (5-acetyl-6-methyl-2-[(E)-2-(2-thienyl)vinyl]pyrimidin-4-ylthio)acetate 1094816-69-9 C17H18N2O3S2
    ethyl (5-acetyl-6-methyl-2-[(E)-2-(2-thienyl)vinyl]pyrimidin-4-ylthio)acetate
    —— (S)-(+)-1-adamantylamino-2-[4-(4-chlorophenylthio)phenyl]propan-2-ol 1323142-77-3 C25H30ClNOS
    (S)-(+)-1-adamantylamino-2-[4-(4-chlorophenylthio)phenyl]propan-2-ol
    —— (Z)-3-Ethylsulfanyl-2-methyl-but-2-enenitrile 53700-01-9 C7H11NS
    (Z)-3-Ethylsulfanyl-2-methyl-but-2-enenitrile
    —— 5-(2-Bromo-phenylsulfanyl)-3-methoxy-6-nitro-benzofuran 286377-44-4 C15H10BrNO4S
    5-(2-Bromo-phenylsulfanyl)-3-methoxy-6-nitro-benzofuran
    —— 5-acetoxy-4,6-di-t-butyl-2-iodomethyl-2-methyl-2,3-dihydrobenzothiophene 173662-61-8 C20H29IO2S
    5-acetoxy-4,6-di-t-butyl-2-iodomethyl-2-methyl-2,3-dihydrobenzothiophene
    —— (R)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-cyclopropyl-2-(methoxymethyloxy)phenyl)thio)phenyl}-1-((dimethoxyphosphoryl)oxy)-2-(1-hydroxypropyl)butane 1383617-37-5 C31H45ClNO9PS
    (R)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-cyclopropyl-2-(methoxymethyloxy)phenyl)thio)phenyl}-1-((dimethoxyphosphoryl)oxy)-2-(1-hydroxypropyl)butane
    —— 83135-87-9 C16H23N3O5S
    —— [Et4N][(C6F5)2B(C5H4)ZrMe2] 345910-15-8 C8H20N*C24H14BF10Zr
    [Et4N][(C6F5)2B(C5H4)ZrMe2]
    —— trithiocarbonic acid ; compound with guanidine 54015-07-5 CH2S3*2CH5N3
    trithiocarbonic acid ; compound with guanidine
    —— 3,5,6,3',5',6'-hexachloro-2,2'-butane-1,4-diylbissulfanyl-bis-pyrazine 36041-01-7 C12H8Cl6N4S2
    3,5,6,3',5',6'-hexachloro-2,2'-butane-1,4-diylbissulfanyl-bis-pyrazine
    —— (E)-1,4-di(t-butylthio)-1-hexylthio-1-buten-3-yne 1269800-95-4 C18H32S3
    (E)-1,4-di(t-butylthio)-1-hexylthio-1-buten-3-yne
    —— Dipropyl-dithiocarbamic acid cyclohepta-2,4,6-trienyl ester 39234-15-6 C14H21NS2
    Dipropyl-dithiocarbamic acid cyclohepta-2,4,6-trienyl ester
    —— 1-benzothiazol-2-ylsulfanyl-phthalazine 17323-00-1 C15H9N3S2
    1-benzothiazol-2-ylsulfanyl-phthalazine
    —— 1,3-Dimethoxy-2-(p-methylthiophenylthio)-propan 32195-43-0 C12H18O2S2
    1,3-Dimethoxy-2-(p-methylthiophenylthio)-propan
    —— 3,4,4aβ,5,6,7,8,8aα-octahydro-8α-methyl-1β-(phenylthio)-1H-2-benzopyran 143215-43-4 C16H22OS
    3,4,4aβ,5,6,7,8,8aα-octahydro-8α-methyl-1β-(phenylthio)-1H-2-benzopyran
    —— tert-butylN-{2-[(2-hydroxyethyl)(imino)oxo-lambda6-sulfanyl]ethyl}carbamate 2416234-34-7 C9H20N2O4S
    tert-butylN-{2-[(2-hydroxyethyl)(imino)oxo-lambda6-sulfanyl]ethyl}carbamate
    —— 2,6-Dichloro-3-methylsulfanyl-phenylamine 15945-21-8 C7H7Cl2NS
    2,6-Dichloro-3-methylsulfanyl-phenylamine
    —— 2-o-chlorobenzylthio-N-phenylcytosine 622837-49-4 C17H14ClN3S
    2-o-chlorobenzylthio-N-phenylcytosine
    —— (2S)-1-[(5-bromo-6-ethyl-2-pyridin-3-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)amino]propan-2-ol;2,2,2-trifluoroacetic acid 1275599-08-0 C2HF3O2*C16H18BrN5OS
    (2S)-1-[(5-bromo-6-ethyl-2-pyridin-3-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)amino]propan-2-ol;2,2,2-trifluoroacetic acid
    —— 4-benzyl-3-benzylsulfanyl-5-cyclohex-1-enyl-4H-[1,2,4]triazole 1448538-39-3 C22H23N3S
    4-benzyl-3-benzylsulfanyl-5-cyclohex-1-enyl-4H-[1,2,4]triazole
    —— 2-Chloro-N-[3,5-dichloro-4-(5-cyano-benzothiazol-2-ylsulfanyl)-phenyl]-4-trifluoromethyl-benzenesulfonamide 315225-33-3 C21H9Cl3F3N3O2S3
    2-Chloro-N-[3,5-dichloro-4-(5-cyano-benzothiazol-2-ylsulfanyl)-phenyl]-4-trifluoromethyl-benzenesulfonamide
    —— 3-(2,5-dichlorophenyl)sulfanyl-1H-indole 1448709-50-9 C14H9Cl2NS
    3-(2,5-dichlorophenyl)sulfanyl-1H-indole
    —— 2,6-Bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-3,5-bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethylsulfanyl)-pyran-4-one 75782-17-1 C17F28O2S2
    2,6-Bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-3,5-bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethylsulfanyl)-pyran-4-one
    —— 1-(4-(dimethylamino)phenyl)-4-(phenylthio)but-2-yn-1-ol 1314664-70-4 C18H19NOS
    1-(4-(dimethylamino)phenyl)-4-(phenylthio)but-2-yn-1-ol
    —— α-(5-methyl-6-oxo-1,6-dihydro-pyrimidin-2-ylmercapto)-isobutyric acid 103860-39-5 C9H12N2O3S
    α-(5-methyl-6-oxo-1,6-dihydro-pyrimidin-2-ylmercapto)-isobutyric acid
    —— 1-(2-phenethyl-1,3-dithian-2-yl)hept-6-en-1-ol 1392325-39-1 C19H28OS2
    1-(2-phenethyl-1,3-dithian-2-yl)hept-6-en-1-ol
    —— 4-(thioacetooctadecylamido)-5-methylthio-1,3-dithiol-2-thione 927414-51-5 C24H43NOS5
    4-(thioacetooctadecylamido)-5-methylthio-1,3-dithiol-2-thione
    —— 1,7-bis-phenylsulfanyl-phenoxazin-3-one 34847-50-2 C24H15NO2S2
    1,7-bis-phenylsulfanyl-phenoxazin-3-one
    —— (S)-NH-methyl n-tridecyl sulfoximine 1356395-23-7 C14H31NOS
    (S)-NH-methyl n-tridecyl sulfoximine
    —— (E)-1-(t-butylthio)-1-hexylthio-4-triisopropylsilyl-1-buten-3-yne 1269800-94-3 C23H44S2Si
    (E)-1-(t-butylthio)-1-hexylthio-4-triisopropylsilyl-1-buten-3-yne
    —— 2.6-Di(phenylthio)benzoylchlorid 10568-25-9 C19H13ClOS2
    2.6-Di(phenylthio)benzoylchlorid
    —— pinacol phenyl(phenylthio)methaneboronate 79121-46-3 C19H23BO2S
    pinacol phenyl(phenylthio)methaneboronate
    —— 3-phenylthio-4-thiophene-nitrile 65369-26-8 C11H7NS2
    3-phenylthio-4-thiophene-nitrile
    —— O,S-dimethyl t-butylphosphonothioate 34309-92-7 C6H15O2PS
    O,S-dimethyl t-butylphosphonothioate
    —— 3,3-di[(phenylsulfanyl)methyl]cyclobutanol 938436-20-5 C18H20OS2
    3,3-di[(phenylsulfanyl)methyl]cyclobutanol
    —— (5-methylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-yl)-phosphonothioic acid O,O'-diisopropyl ester 21080-28-4 C9H17N2O3PS3
    (5-methylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-yl)-phosphonothioic acid O,O'-diisopropyl ester
    —— methyl-3 methylthio-6 p-tolyl-5 thiopyrannethione-2 77643-43-7 C14H14S3
    methyl-3 methylthio-6 p-tolyl-5 thiopyrannethione-2
    —— 6-(cyclohexylmethyl)-2-((2-hydroxy-2-(4-hydroxyphenyl)ethyl)thio)-5-methylpyrimidin-4(3H)-one 1428569-10-1 C20H26N2O3S
    6-(cyclohexylmethyl)-2-((2-hydroxy-2-(4-hydroxyphenyl)ethyl)thio)-5-methylpyrimidin-4(3H)-one
    —— 6-(4-chloro-phenylsulfanyl)-2-[3-(4-methyl-piperazin-1-yl)-propyl]-benzo[<i>d</i>]isothiazol-3-one 64324-75-0 C21H24ClN3OS2
    6-(4-chloro-phenylsulfanyl)-2-[3-(4-methyl-piperazin-1-yl)-propyl]-benzo[<i>d</i>]isothiazol-3-one